Patent US4198243A successfully refreshed from Google Patents.
US4198243A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Coating composition containing a liquid glycol
Assignee: Individual
•
Filing: 1978-01-19
•
Granted: 1980-04-15
•
Expires: 1998-01-19
Abstract
Abstract A composition for marking the contact points on the occlusal surface of a dental restorative or a natural tooth and for use in evaluating the mode of contact between occluding teeth.
Inventors
- 👤 Asami Tanaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 12:11
CPC Classifications
C; C09; C09D; C09D5/00; A; A61; A61K; A61K6/00; A61K6/90
Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
934 words
A coating composition, comprising: a liquid glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) a --H where a is 3 to 20 and a glycol having the formula HO--(C 3 H 6 O) b --H where b is 2 to 15, said liquid glycol at a concentration of from about 50 weight percent to about 90 weight percent of said coating composition; a coloring agent at a concentration in said composition of from about 0.05 weight percent to about 3 weight percent, such that, when said composition is applied as a thin coating to the occlusal surface of one tooth of a pair of occluding teeth and then the coated tooth and the uncoated tooth of said pair are brought into occluding relationship so that a portion of said coating is transferred to the occlusal surface of said uncoated tooth as a thin marking at each contact point between said teeth, said marking has sufficient color intensity to permit visual location of each contact point on the occlusal surface of said uncoated tooth; and a thickening agent at a concentration in said composition of from about 10 weight percent to about 50 weight percent which comprises a material selected from the group consisting of: A--a member selected from the group consisting of a solid glycol ester and a solid ethoxylated ester formed therefrom, said solid glycol ester having at least one free hydroxyl group and being an ester of a fatty acid containing from 12 to 22 carbon atoms and of a glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) d --H where d is 3 to 27 and a glycol having the formula HO--(C 3 H 6 O) g --H where g is 2 to 20, said ethoxylated ester being a reaction product of 2-30 moles of ethylene oxide and one mole of said solid glycol ester; B--a mixture of (1) a component at a concentration of from about 3 weight percent to about 50 weight percent of said coating composition and selected from the group consisting of a glycol ester and an ethoxylated ester formed therefrom, said glycol ester having at least one free hydroxyl group and being an ester of a fatty acid containing from 12 to 22 carbon atoms and of a glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) x --H where x is 3 to 27 and a glycol having the formula HO--(C 3 H 6 O) y --H where y is 2 to 20, and of (2) a component selected from the group consisting of a fatty acid at a concentration of from about 1 weight percent to about 30 weight percent of said coating composition and containing from 12 to 22 carbon atoms, a fatty acid ester of a fatty acid containing 10 to 22 carbon atoms and of an aliphatic monohydroxyl alcohol containing from 1 to 4 carbon atoms, said fatty acid ester at a concentration of from about 1 weight percent to about 5 weight percent of said coating composition; a fatty alcohol at a concentration of from about 0.1 weight percent of about 5 weight percent of said coating composition and containing from 10 to 30 carbon atoms, an ethoxylated fatty alcohol at a concentration of from about 0.3 weight percent to about 2 weight percent of said coating composition and which is a reaction product of one mole of fatty alcohol containing from 10 to 30 carbon atoms and 2 to 30 moles of ethylene oxide, an aliphatic hydrocarbon oil at a concentration of from about 1 weight percent to about 10 weight percent of said coating composition, and an alkanolamine which is at a concentration of from about 1 percent to about 10 weight percent of said coating composition and which is a secondary or tertiary amine containing from 4 to b 9 carbon atoms, with each alkanol moiety thereof containing 2 to 3 carbon atoms; and C--a mixture of a solid fatty acid at a concentration of from about 7 weight percent to about 40 weight percent of said coating composition and containing 12 to 22 carbon atoms and an alkanolamine which is at a concentration which is about 0.1 to 1.0 of that needed to exactly neutralize said fatty acid in said mixture C and which is a secondary or tertiary amine containing from 4 to 9 carbon atoms, with each alkanol moiety thereof containing 2 to 3 carbon atoms; said composition being in the form of a readily deformable paste which is capable of being smeared as a thin, immobile coating on the occlusal surface of said coated tooth, a portion of said coating capable of being transferred to the occlusal surface of said uncoated tooth when said pair of occluding teeth is brought into occluding relationship, as a thin marking at each contact point between said teeth, said coating being sufficiently thin to permit said occluding teeth to enter into a substantially unimpaired occluding relationship, the mixture of said liquid glycol and said thickening agent serving as a carrier for said coloring agent and being removable from said teeth by a water rinse.
Claim 2
Dependent Claim
934 words
A coating composition, comprising: a liquid glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) a --H where a is 3 to 20 and a glycol having the formula HO--(C 3 H 6 O) b --H where b is 2 to 15, said liquid glycol at a concentration of from about 50 weight percent to about 90 weight percent of said coating composition; a coloring agent at a concentration in said composition of from about 0.05 weight percent to about 3 weight percent, such that, when said composition is applied as a thin coating to the occlusal surface of one tooth of a pair of occluding teeth and then the coated tooth and the uncoated tooth of said pair are brought into occluding relationship so that a portion of said coating is transferred to the occlusal surface of said uncoated tooth as a thin marking at each contact point between said teeth, said marking has sufficient color intensity to permit visual location of each contact point on the occlusal surface of said uncoated tooth; and a thickening agent at a concentration in said composition of from about 10 weight percent to about 50 weight percent which comprises a material selected from the group consisting of: A--a member selected from the group consisting of a solid glycol ester and a solid ethoxylated ester formed therefrom, said solid glycol ester having at least one free hydroxyl group and being an ester of a fatty acid containing from 12 to 22 carbon atoms and of a glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) d --H where d is 3 to 27 and a glycol having the formula HO--(C 3 H 6 O) g --H where g is 2 to 20, said ethoxylated ester being a reaction product of 2-30 moles of ethylene oxide and one mole of said solid glycol ester; B--a mixture of (1) a component at a concentration of from about 3 weight percent to about 50 weight percent of said coating composition and selected from the group consisting of a glycol ester and an ethoxylated ester formed therefrom, said glycol ester having at least one free hydroxyl group and being an ester of a fatty acid containing from 12 to 22 carbon atoms and of a glycol selected from the group consisting of a glycol containing n hydroxyl groups and from n to n+2 carbon atoms where n is 2 to 10, a glycol having the formula HO--(C 2 H 4 O) x --H where x is 3 to 27 and a glycol having the formula HO--(C 3 H 6 O) y --H where y is 2 to 20, and of (2) a component selected from the group consisting of a fatty acid at a concentration of from about 1 weight percent to about 30 weight percent of said coating composition and containing from 12 to 22 carbon atoms, a fatty acid ester of a fatty acid containing 10 to 22 carbon atoms and of an aliphatic monohydroxyl alcohol containing from 1 to 4 carbon atoms, said fatty acid ester at a concentration of from about 1 weight percent to about 5 weight percent of said coating composition; a fatty alcohol at a concentration of from about 0.1 weight percent of about 5 weight percent of said coating composition and containing from 10 to 30 carbon atoms, an ethoxylated fatty alcohol at a concentration of from about 0.3 weight percent to about 2 weight percent of said coating composition and which is a reaction product of one mole of fatty alcohol containing from 10 to 30 carbon atoms and 2 to 30 moles of ethylene oxide, an aliphatic hydrocarbon oil at a concentration of from about 1 weight percent to about 10 weight percent of said coating composition, and an alkanolamine which is at a concentration of from about 1 percent to about 10 weight percent of said coating composition and which is a secondary or tertiary amine containing from 4 to b 9 carbon atoms, with each alkanol moiety thereof containing 2 to 3 carbon atoms; and C--a mixture of a solid fatty acid at a concentration of from about 7 weight percent to about 40 weight percent of said coating composition and containing 12 to 22 carbon atoms and an alkanolamine which is at a concentration which is about 0.1 to 1.0 of that needed to exactly neutralize said fatty acid in said mixture C and which is a secondary or tertiary amine containing from 4 to 9 carbon atoms, with each alkanol moiety thereof containing 2 to 3 carbon atoms; said composition being in the form of a readily deformable paste which is capable of being smeared as a thin, immobile coating on the occlusal surface of said coated tooth, a portion of said coating capable of being transferred to the occlusal surface of said uncoated tooth when said pair of occluding teeth is brought into occluding relationship, as a thin marking at each contact point between said teeth, said coating being sufficiently thin to permit said occluding teeth to enter into a substantially unimpaired occluding relationship, the mixture of said liquid glycol and said thickening agent serving as a carrier for said coloring agent and being removable from said teeth by a water rinse.
Claim 3
Dependent Claim
28 words
The coating composition of claim 1 wherein said liquid glycol is at a concentration of from about 65 weight percent to about 85 weight percent of said composition.
Claim 4
Dependent Claim
33 words
The coating composition of claim 1 wherein said liquid glycol is selected from the group consisting of ethylene glycol, propylene glycol, glycerin, sorbitol, diethylene glycol, dipropylene glycol, diglycerin, polyethylene glycol and polypropylene glycol.
Claim 5
Dependent Claim
18 words
The coating composition of claim 3 wherein said liquid glycol is a mixture of glycerin and propylene glycol.
Claim 6
Dependent Claim
14 words
The coating composition of claim 1 wherein said coloring agent is a food coloring.
Claim 7
Dependent Claim
28 words
The coating composition of claim 1 wherein said coloring agent is at a concentration of from about 0.1 weight percent to about 2 weight percent of said composition.
Claim 8
Dependent Claim
28 words
The coating composition of claim 1 wherein said thickening agent is at a concentration of from about 15 weight percent to about 35 weight percent of said composition.
Claim 9
Dependent Claim
29 words
The coating composition of claim 1 wherein said member A is at a concentration of from about 15 weight percent to about 35 weight percent of said coating composition.
Claim 10
Dependent Claim
15 words
The coating composition of claim 1 wherein said member A is said solid glycol ester.
Claim 11
Dependent Claim
46 words
The coating composition of claim 1 wherein said member A is selected from the group consisting of the monostearate, monopalmitate and monolaurate of ethylene glycol, propylene glycol, glycerin, sorbitol, sucrose, diethylene glycol, dipropylene glycol, diglycerin, sorbitan, polyethylene glycol and polypropylene glycol, and the ethoxylated derivatives thereof.
Claim 12
Dependent Claim
13 words
The coating composition of claim 10 wherein said member A is glyceryl monostearate.
Claim 13
Dependent Claim
18 words
The coating composition of claim 1 wherein said component (1) in said mixture B is said glycol ester.
Claim 14
Dependent Claim
51 words
The coating composition of claim 1 wherein said component (1) in said mixture B is selected from the group consisting of the monooleate, monostearate, monopalmitate and monolaurate of ethylene glycol, propylene glycol, glycerin, sorbitol, sucrose, diethylene glycol, dipropylene glycol, diglycerin, sorbitan, polyethylene glycol and polypropylene glycol and the ethoxylated derivatives thereof.
Claim 15
Dependent Claim
13 words
The coating composition of claim 13 wherein said component (1) is glyceryl monostearate.
Claim 16
Dependent Claim
29 words
The coating composition of claim 1 wherein said component (1) is at a concentration of from about 5 weight percent to about 35 weight percent of said coating composition.
Claim 17
Dependent Claim
33 words
The coating composition of claim 1 wherein said fatty acid of said component (2) in said mixture B is selected from the group consisting of stearic, palmitic, lauric, myristic, oleic and linoleic acids.
Claim 18
Dependent Claim
13 words
The coating composition of claim 16 wherein said fatty acid is stearic acid.
Claim 19
Dependent Claim
36 words
The coating composition of claim 1 wherein said fatty acid of said component (2) in said mixture is at a concentration of from about 2 weight percent to about 15 weight percent of said coating composition.
Claim 20
Dependent Claim
39 words
The coating composition of claim 1 wherein said fatty acid ester of said component (2) in said mixture B is selected from the group consisting of methyl laurate, isopropyl myristate, isopropyl palmitate, n-butyl stearate, isopropyl isostearate and n-butyl oleate.
Claim 21
Dependent Claim
14 words
The coating composition of claim 19 wherein said fatty acid ester is isopropyl palmitate.
Claim 22
Dependent Claim
38 words
The coating composition of claim 1 wherein said fatty acid ester of said component (2) in said mixture B is at a concentration of from about 1 weight percent to about 3 weight percent of said coating composition.
Claim 23
Dependent Claim
33 words
The coating composition of claim 1 wherein said fatty alcohol of said component (2) in said mixture B is selected from the group consisting of palmityl, stearyl, myristyl, oleyl, cetyl and lauryl alcohols.
Claim 24
Dependent Claim
13 words
The coating composition of claim 22 wherein said fatty alcohol is cetyl alcohol.
Claim 25
Dependent Claim
29 words
The coating composition of claim 1 wherein said fatty alcohol is at a concentration of from about 2 weight percent to about 5 weight percent of said coating composition.
Claim 26
Dependent Claim
42 words
The coating composition of claim 1 wherein said ethoxylated fatty alcohol of said component (2) in said mixture B is selected from the group consisting of laureth-4, laureth-20, laureth-23, steareth-20, ceteth-10, ceteth-20, ceteth-28, polyoxyethylene (10) oleyl ether and polyoxyethylene (20) oleyl ether.
Claim 27
Dependent Claim
13 words
The coating composition of claim 25 wherein said ethoxylated fatty alcohol is laureth-23.
Claim 28
Dependent Claim
30 words
The coating composition of claim 1 wherein said ethoxylated fatty alcohol is at a concentration of from about 0.5 weight percent to about 1 weight percent of said coating composition.
Claim 29
Dependent Claim
22 words
The coating composition of claim 1 wherein said aliphatic hydrocarbon oil of said component (2) in said mixture B is mineral oil.
Claim 30
Dependent Claim
29 words
The coating composition of claim 1 wherein said hydrocarbon oil is at a concentration of from about 4 weight percent to about 7 weight percent of said coating composition.
Claim 31
Dependent Claim
35 words
The coating composition of claim 1 wherein said alkanolamine in said mixture C or of said component (2) in said mixture B is selected from the group consisting of diethanolamine, diisopropanolamine, triethanolamine, triisopropanolamine and N-methyldiethanolamine.
Claim 32
Dependent Claim
11 words
The coating composition of claim 30 wherein said alkanolamine is triisopropanolamine.
Claim 33
Dependent Claim
28 words
The coating composition of claim 1 wherein said alkanolamine is at a concentration of from about 1 weight percent to about 3 weight percent of said coating composition.
Claim 34
Dependent Claim
27 words
The coating composition of claim 1 wherein said fatty acid in said mixture C is selected from the group consisting of stearic, palmitic, lauric and myristic acids.
Claim 35
Dependent Claim
13 words
The coating composition of claim 33 wherein said fatty acid is stearic acid.
Claim 36
Dependent Claim
33 words
The coating composition of claim 1 wherein said fatty acid in said mixture C is at a concentration of from about 12 weight percent to about 30 weight percent of said coating composition.
References Cited (Backward Citations)
CA645133A
Cited
US3118230A
Cited
US2171759A
Cited
US2112762A
Cited
US2589306A
Cited
US2623827A
Cited
US2633637A
Cited
US2674797A
Cited
US2752681A
Cited
US2966417A
Cited
US3627546A
Cited
US3421223A
Cited
US3672842A
Cited
GB1343704A
Cited
US3914131A
Cited
US3918160A
Cited
US3813781A
Cited
US3873687A
Cited
US3959881A
Cited
JPS5265363A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-15 | 1983-10-15 | 1984-04-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-15 | 1987-10-15 | 1988-04-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-15 | 1991-10-15 | 1992-04-15 | $7700.00 | Window Closed / Lapsed |