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Metal chelate/anti-oxidant combinations with dimer-trimer acids, pipeline corrosion inhibitors

Assignee: ChampionX LLC
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Filing: 1979-04-12
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Granted: 1980-04-08
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Expires: 1999-04-12
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Abstract

Abstract A composition for inhibiting the corrosion of ferrous metal pipelines used to transport petroleum hydrocarbons comprising a major portion of a mixture of C 36 dicarboxylic dimer acid and a C 54 trimer acid, which mixture has an acid number of at least 110 and from 0.5 up to about 5% of a composition from the group consisting of: (a) an N,N'-di(ortho-hydroxyarylidene)-1,2-alkylenediamine in which the arylidene radical contains 6-7 carbon atoms and the alkylene radical contains 2-3 carbon atoms; and (b) a polymeric condensation product obtained by the reaction of a phenol having two reactive ring positions, a lower aliphatic aldehyde having 1-2 carbons, and a polyamine having a reactive hydrogen atom on at least two amino nitrogens, said condensation product being formed by condensing the foregoing reactants at a molar ratio of 2 mols of said aldehyde per mol of said phenol and a molar ratio of phenol to polyamine in the range of 1:1 to 2:1, respectively, at an elevated reaction temperature sufficient to form a polymerized condensation product.

Inventors

  • 👤 Alvis B. Gainer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:11
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/18; C10L1/188; C10L1/1881; C10L1/1883; C10L1/22; C10L1/222; C10L1/2222; C10L1/2225; C10L10/00; C10L10/04; C10L1/228; C10L1/2283

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 173 words
A composition for inhibiting the corrosion of ferrous metal pipelines used to transport petroleum hydrocarbons comprising a major portion of a mixture of C 36 dicarboxylic dimer acid and a C 54 trimer acid, which mixture has an acid number of at least 110 and from 0.5 up to about 5% of a composition from the group consisting of: (a) an N,N'-di(ortho-hydroxyarylidene) - 1,2-alkylenediamine in which the arylidene radical contains 6-7 carbon atoms and the alkylene radical contains 2-3 carbon atoms; and (b) a polymeric condensation product obtained by the reaction of a phenol having two reactive ring positions, a lower aliphatic aldehyde having 1-2 carbons, and a polyamine having a reactive hydrogen atom on at least two amino nitrogens, said condensation product being formed by condensing the foregoing reactants at a molar ratio of 2 mols of said aldehyde per mol of said phenol and a molar ratio of phenol to polyamine in the range of 1:1 to 2:1, respectively, at an elevated reaction temperature sufficient to form a polymerized condensation product.
Claim 2
Dependent Claim 173 words
A composition for inhibiting the corrosion of ferrous metal pipelines used to transport petroleum hydrocarbons comprising a major portion of a mixture of C 36 dicarboxylic dimer acid and a C 54 trimer acid, which mixture has an acid number of at least 110 and from 0.5 up to about 5% of a composition from the group consisting of: (a) an N,N'-di(ortho-hydroxyarylidene) - 1,2-alkylenediamine in which the arylidene radical contains 6-7 carbon atoms and the alkylene radical contains 2-3 carbon atoms; and (b) a polymeric condensation product obtained by the reaction of a phenol having two reactive ring positions, a lower aliphatic aldehyde having 1-2 carbons, and a polyamine having a reactive hydrogen atom on at least two amino nitrogens, said condensation product being formed by condensing the foregoing reactants at a molar ratio of 2 mols of said aldehyde per mol of said phenol and a molar ratio of phenol to polyamine in the range of 1:1 to 2:1, respectively, at an elevated reaction temperature sufficient to form a polymerized condensation product.
Claim 3
Dependent Claim 31 words
The composition of claim 1 where (a) is N,N'disalicylidene-1,2-propylenediamine and (b) is a Mannich polymer prepared by condensing 2 moles of P-dodecyl phenol with 1 mole each of formaldehyde and ethylenediamine.

References Cited (Backward Citations)

US2482761A Cited
US2904415A Cited
US2984550A Cited
US3912771A Cited
US4072474A Cited
US4002437A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-08 1983-10-08 1984-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-08 1987-10-08 1988-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-08 1991-10-08 1992-04-08 $7700.00 Window Closed / Lapsed

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