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US4197090A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for removing sulfur from coal

Assignee: Atlantic Richfield Co
•
Filing: 1978-02-10
•
Granted: 1980-04-08
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Expires: 1998-02-10
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Abstract

Abstract A process for reducing the pyritic sulfur content of coal comprising the steps of: (1) contacting an aqueous slurry of water and pyrite-containing coal particles at elevated temperature with oxygen, the contacting of step 1 being such that without step 2 the aqueous slurry would have a pH of less than 5.5; (2) maintaining the aqueous slurry of step 1 at a pH of from about 5.5 to 12.0; and (3) recovering coal particles of reduced pyritic sulfur content.

Inventors

  • 👤 Jin S. Yoo
  • 👤 Emmett H. Burk, Jr.
  • 👤 John A. Karch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:00
CPC Classifications
C; C10; C10L; C10L9/00; C10L9/02

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 56 words
A process for reducing the pyritic sulfur content of coal comprising: (1) contacting an aqueous slurry of water and pyrite-containing coal particles at elevated temperature with oxygen; (2) maintaining the aqueous slurry of step 1 at a pH of from about 5.5 to 12.0; and (3) separating water containing dissolved sulfur compounds from the coal particles.
Claim 2
Dependent Claim 56 words
A process for reducing the pyritic sulfur content of coal comprising: (1) contacting an aqueous slurry of water and pyrite-containing coal particles at elevated temperature with oxygen; (2) maintaining the aqueous slurry of step 1 at a pH of from about 5.5 to 12.0; and (3) separating water containing dissolved sulfur compounds from the coal particles.
Claim 3
Dependent Claim 17 words
The process of claim 1 wherein the pH in step 2 is from about 6.5 to 10.
Claim 4
Dependent Claim 17 words
The process of claim 1 wherein the temperature is from about 150° F. to about 350° F.
Claim 5
Dependent Claim 19 words
The process of claim 1 wherein the oxygen is at a pressure of from about 50 to 500 psig.
Claim 6
Dependent Claim 13 words
The process of claim 4 wherein oxygen gas is mixed with inert gas.
Claim 7
Dependent Claim 19 words
The process of claim 3 wherein the pH is maintained by adding an alkali material to the aqueous slurry.
Claim 8
Dependent Claim 29 words
The process of claim 6 wherein the alkali material is selected from the group consisting of potassium hydroxide, sodium hydroxide, potassium bicarbonate, sodium bicarbonate, ammonium bicarbonate and mixtures thereof.
Claim 9
Dependent Claim 24 words
The process of claim 3 wherein the aqueous slurry of water and coal particles contains from about 5 to 50%, by weight, coal particles.
Claim 10
Dependent Claim 24 words
The process of claim 8 wherein the aqueous slurry of water and coal particles contains from about 10 to 30%, by weight, coal particles.
Claim 11
Dependent Claim 17 words
The process of claim 3 wherein the coal particles have a particle size less than 5 mesh.
Claim 12
Dependent Claim 17 words
The process of claim 10 wherein the coal particles have a particle size less than 18 mesh.

References Cited (Backward Citations)

US2162221A Cited
US2346151A Cited
US3824084A Cited
US3909211A Cited
US3960513A Cited
US4054420A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-08 1983-10-08 1984-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-08 1987-10-08 1988-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-08 1991-10-08 1992-04-08 $7700.00 Window Closed / Lapsed

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