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US4196107A Expired / Lapsed US ⏱️ 0.0 years remaining

Semi-solid water-based coating compositions

Assignee: PPG Industries Inc
•
Filing: 1978-06-05
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Granted: 1980-04-01
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Expires: 1998-06-05
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Abstract

Abstract This invention relates to coating compositions which are "solid" prior to application, yet, which when applied to a substrate, flow and level in a manner similar to conventional coating compositions. The coating compositions of the invention comprise a gelled coating composition, capable of application and flow on a solid substrate comprising: (a) a water reducible polymer, (b) water, (c) an electrolyte, and (d) a colloidal gelling agent, gelable by interaction with the electrolyte, in an amount sufficient, when interacted with said electrolyte, to gel the composition to form a stable semisolid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force at a relatively small shearing rate; which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent contributed gel structure.

Inventors

  • 👤 James E. Jones
  • 👤 Rodger G. Temple
  • 👤 Jerome A. Seiner
  • 👤 Sharon L. Young
  • 👤 William G. Boberski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 22:19
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/04

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 107 words
A gelled coating composition, capable of application and flow on a solid substrate, comprising: (a) a water reducible, film-forming polymer, (b) water, (c) an electrolyte, and (d) a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate, (e) which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure.
Claim 2
Dependent Claim 107 words
A gelled coating composition, capable of application and flow on a solid substrate, comprising: (a) a water reducible, film-forming polymer, (b) water, (c) an electrolyte, and (d) a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate, (e) which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure.
Claim 3
Dependent Claim 13 words
A composition, as in claim 1, where the electrolyte is a polyfunctional salt.
Claim 4
Dependent Claim 16 words
A composition, as in claim 1, where the colloidal gelling agent is an anionic silica sol.
Claim 5
Dependent Claim 13 words
A composition, as in claim 3, where the electrolyte is a polyfunctional salt.
Claim 6
Dependent Claim 106 words
A gelled coating composition capable of application and flow on a solid substrate, comprising: (a) a water reducible film-forming polymer which is an electrolyte, (b) water, (c) a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon application of a relatively small shearing force, at a relatively small shearing rate, (d) which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure.
Claim 7
Dependent Claim 106 words
A gelled coating composition capable of application and flow on a solid substrate, comprising: (a) a water reducible film-forming polymer which is an electrolyte, (b) water, (c) a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon application of a relatively small shearing force, at a relatively small shearing rate, (d) which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure.
Claim 8
Dependent Claim 13 words
A composition, as in claim 5, where the polymeric electrolyte is a salt.
Claim 9
Dependent Claim 16 words
A composition, as in claim 5, where the colloidal gelling agent is an anionic silica sol.
Claim 10
Dependent Claim 13 words
A composition, as in claim 7, where the polymeric electrolyte is a salt.
Claim 11
Dependent Claim 42 words
A composition, as in claims 1 or 5, containing a water insoluble solvent which is not a solvent for the film forming polymer and whose presence contributes increased hiding by the creation of microvoids in a dried film produced from said composition.
Claim 12
Dependent Claim 11 words
A composition, as in claims 1 or 5, containing pigment particles.
Claim 13
Dependent Claim 15 words
A composition, as in claims 1 or 5, containing dispersed pigment particles carrying a charge.
Claim 14
Dependent Claim 14 words
A composition, as in claims 1 or 5, containing polymeric particles carrying a charge.
Claim 15
Independent Claim 108 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a preformed water-based coating composition: an electrolyte, and a colloidal gelling agent, gelable by interaction with said electrolyte in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid, and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 16
Independent Claim 108 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a preformed water-based coating composition: an electrolyte, and a colloidal gelling agent, gelable by interaction with said electrolyte in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid, and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 17
Dependent Claim 32 words
A method, as in claim 13, wherein the composition is heated at a temperature and for a time sufficient to cause the substantial completion of the interaction between the electrolyte and colloid.
Claim 18
Independent Claim 109 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a preformed water-based coating composition, containing an electrolyte: a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a viscosity stable semi-solid or solid, and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 19
Independent Claim 109 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a preformed water-based coating composition, containing an electrolyte: a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a viscosity stable semi-solid or solid, and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 20
Dependent Claim 32 words
A method, as in claim 15, wherein the composition is heated at a temperature and for a time sufficient to cause the substantial completion of the interaction between the electrolyte and colloid.
Claim 21
Independent Claim 112 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprising admixing with a water-based coating composition during the formulation of its ingredients: an electrolyte, and a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 22
Independent Claim 112 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprising admixing with a water-based coating composition during the formulation of its ingredients: an electrolyte, and a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 23
Dependent Claim 32 words
A method, as in claim 17, wherein the composition is heated at a temperature and for a time sufficient to cause the substantial completion of the interaction between the electrolyte and colloid.
Claim 24
Independent Claim 114 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a water-based coating composition, comprising a film-forming polymeric electrolyte, during the formulation of its ingredients: a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 25
Independent Claim 114 words
A method of forming a gelled coating composition capable of application and flow on a solid substrate, which coating composition, after being sheared to a coating viscosity, does not recover substantial colloidal gelling agent-electrolyte contributed gel structure, which method comprises admixing with a water-based coating composition, comprising a film-forming polymeric electrolyte, during the formulation of its ingredients: a colloidal gelling agent, gelable by interaction with said electrolyte, in an amount sufficient, when substantially interacted with said electrolyte, to gel the composition to form a stable semi-solid or solid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force, at a relatively small shearing rate.
Claim 26
Dependent Claim 32 words
A method, as in claim 18, where the composition is heated at a temperature and for a time sufficient to cause the substantial completion of the interaction between the electrolyte and colloid.
Claim 27
Independent Claim 28 words
A method as in claims 13, 14, 15, 16, 17, 18, 19 or 20 wherein a gel structure is formed after the composition is placed in a container.
Claim 28
Independent Claim 28 words
A method as in claims 13, 14, 15, 16, 17, 18, 19 or 20 wherein a thin polymeric film is placed upon the surface of the coating composition.
Claim 29
Independent Claim 25 words
A method as in claims 13, 14, 15, 16, 17, 18, 19 or 20 wherein the resultant gel is cut and placed into a container.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-04-01 1983-10-01 1984-04-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-04-01 1987-10-01 1988-04-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-04-01 1991-10-01 1992-04-01 $7700.00 Window Closed / Lapsed

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