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US4195103A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of desensitizing carbonless paper

Assignee: Wallace Computer Services Inc
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Filing: 1978-08-30
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Granted: 1980-03-25
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Expires: 1998-08-30
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Abstract

Abstract A method of desensitizing carbonless paper by subjecting N-vinyl pyrrolidone and a free radical copolymerizable compound having at least one terminal ethylenic group per molecule in situ to ultra violet radiation.

Inventors

  • 👤 John C. H. Chang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:17
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/128; Y; Y10; Y10S; Y10S428/00; Y10S428/914

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 104 words
A method of desensitizing a carbonless paper having as a color developer thereof a member selected from the class consisting of an acid clay, a phenolic novolac resin and a metal salt of an organic carboxylic acid, comprising applying from about 10 to about 35 parts N-vinylpyrrolidone, from about 65 to about 90 parts of a free-radical co-polymerizable compound having at least one terminal ethylenic group per molecule and from about 1% to about 10% of the combined weight of said N-vinylpyrrolidone and said free-radical copolymerizable compound of a photoinitiator to selected portions of said paper and thereafter subjecting said paper to ultraviolet radiation.
Claim 2
Independent Claim 104 words
A method of desensitizing a carbonless paper having as a color developer thereof a member selected from the class consisting of an acid clay, a phenolic novolac resin and a metal salt of an organic carboxylic acid, comprising applying from about 10 to about 35 parts N-vinylpyrrolidone, from about 65 to about 90 parts of a free-radical co-polymerizable compound having at least one terminal ethylenic group per molecule and from about 1% to about 10% of the combined weight of said N-vinylpyrrolidone and said free-radical copolymerizable compound of a photoinitiator to selected portions of said paper and thereafter subjecting said paper to ultraviolet radiation.
Claim 3
Dependent Claim 50 words
The method of claim 1 in which said compound has the following formula ##STR2## wherein R 1 is a hydrogen atom, or an alkyl group having from 1 to 4 carbon atoms; R 2 represents a block of the ethylenically unsaturated compound, n is an integer of 1 to 10.
Claim 4
Dependent Claim 20 words
The method of claim 1 in which said photoinitiator is present in an amount of about 3% to about 8%.
Claim 5
Dependent Claim 48 words
The method of claim 1 in which said photoinitiator is enhanced by the presence of a synergist in an amount of about 1% to about 10% by weight of said copolymer, said photoinitiator being a member selected from the class consisting of dimethylaminoethanol, diethylaminoethanol, N-methyl diethanolamine, and N-methylmorpholine.
Claim 6
Dependent Claim 30 words
The method of claim 1 in which the viscosity of the mixture of said N-vinylprrolidone, the co-polymerizable compound and the photoinitiator is from about 1,000 cps to about 100,000 cps.
Claim 7
Dependent Claim 19 words
The method of claim 5 in which said viscosity is in the range of about 2,000 to 80,000 cps.
Claim 8
Dependent Claim 171 words
In a method of desensitizing a carbonless paper having as a color developer thereof a member selected from the class consisting of an acid clay, a phenolic novolac resin and a metal salt of an organic carboxylic acid, the steps of applying N-vinylpyrrolidone and ethylenically unsaturated oligomers having the following formula ##STR3## wherein R 1 is a hydrogen atom, or an alkyl group having from 1 to 4 carbon atoms; R 2 represents a block of the ethylenically unsaturated compound, n is an integer of 1 to 10, and in the presence of a photoinitiator to selected portions of a carbonless paper and thereafter subjecting said paper to ultraviolet radiation to form said N-vinylpyrrolidone and ethylenically unsaturated oligomers into a copolymer to densensitize the electronaccepting moiety of said carbonless paper, said copolymer including from about 10 to about 35 parts of N-vinylpyrrolidone and from about 90 to about 65 parts of the free-radical copolymerizable compound, said photoinitiator being present in about 1% to about 10% of the weight of said copolymer.
Claim 9
Dependent Claim 171 words
In a method of desensitizing a carbonless paper having as a color developer thereof a member selected from the class consisting of an acid clay, a phenolic novolac resin and a metal salt of an organic carboxylic acid, the steps of applying N-vinylpyrrolidone and ethylenically unsaturated oligomers having the following formula ##STR3## wherein R 1 is a hydrogen atom, or an alkyl group having from 1 to 4 carbon atoms; R 2 represents a block of the ethylenically unsaturated compound, n is an integer of 1 to 10, and in the presence of a photoinitiator to selected portions of a carbonless paper and thereafter subjecting said paper to ultraviolet radiation to form said N-vinylpyrrolidone and ethylenically unsaturated oligomers into a copolymer to densensitize the electronaccepting moiety of said carbonless paper, said copolymer including from about 10 to about 35 parts of N-vinylpyrrolidone and from about 90 to about 65 parts of the free-radical copolymerizable compound, said photoinitiator being present in about 1% to about 10% of the weight of said copolymer.

References Cited (Backward Citations)

US4012538A Cited
US3952117A Cited
US4007310A Cited
US4073968A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-03-25 1983-09-24 1984-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-03-25 1987-09-24 1988-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-03-25 1991-09-24 1992-03-25 $7700.00 Window Closed / Lapsed

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