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US4192826A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermosetting, electrostatically sprayable compositions containing blocked acid catalyst

Assignee: EIDP Inc
•
Filing: 1978-09-18
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Granted: 1980-03-11
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Expires: 1998-09-18
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Abstract

Abstract Thermosetting liquid coating compositions, based on polymer capable of being crosslinked with nitrogen resin crosslinkers, nitrogen resin crosslinker, and blocked acid catalyst prepared from materials containing at least one oxirane functionality and a sulfonic acid and having a resistivity of at least one megohm are provided. The novel thermosetting coating compositions are particularly useful in electrostatic spraying applications.

Inventors

  • 👤 Aleksander Beresniewicz
  • 👤 John P. Gallagher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:35
CPC Classifications
C; C09; C09D; C09D201/00; C09D201/02; C09D167/00

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 199 words
A thermosetting liquid electrostatically sprayable composition consisting essentially of: (A) film forming constituents consisting essentially of: (1) 50-80 parts, by weight of the film formers, of an ester blend consisting essentially of: (a) 40-80 parts by weight, based on the weight of the blend, of a polyester of the following structure: ##STR4## its isomer through the secondary hydroxyl group of mixtures thereof, wherein n=0-10 and at least 65% by weight is n=3 or less; and (b) 60-20 parts by weight, based on the weight of the blend, of a polyester of the following structure: ##STR5## its isomer through the secondary hydroxyl group or mixtures thereof, wherein n=0-10 and at least 65% by weight is n=3 or less and wherein m=2-4; and (2) 50-20 parts, by weight of the film formers, of peralkoxymethylmelamine; and (B) sufficient blocked acid catalyst to contain 0.05-2 parts, by weight of the film formers, of potentially available sulfonic acid, wherein the blocked catalyst is the reaction product of a material containing at least one oxirane functionality and a sulfonic acid is an equivalent ratio of at least one; and wherein the composition has a resistivity of at least 1 megohm and up to 3.5 megohms.
Claim 2
Dependent Claim 199 words
A thermosetting liquid electrostatically sprayable composition consisting essentially of: (A) film forming constituents consisting essentially of: (1) 50-80 parts, by weight of the film formers, of an ester blend consisting essentially of: (a) 40-80 parts by weight, based on the weight of the blend, of a polyester of the following structure: ##STR4## its isomer through the secondary hydroxyl group of mixtures thereof, wherein n=0-10 and at least 65% by weight is n=3 or less; and (b) 60-20 parts by weight, based on the weight of the blend, of a polyester of the following structure: ##STR5## its isomer through the secondary hydroxyl group or mixtures thereof, wherein n=0-10 and at least 65% by weight is n=3 or less and wherein m=2-4; and (2) 50-20 parts, by weight of the film formers, of peralkoxymethylmelamine; and (B) sufficient blocked acid catalyst to contain 0.05-2 parts, by weight of the film formers, of potentially available sulfonic acid, wherein the blocked catalyst is the reaction product of a material containing at least one oxirane functionality and a sulfonic acid is an equivalent ratio of at least one; and wherein the composition has a resistivity of at least 1 megohm and up to 3.5 megohms.
Claim 3
Dependent Claim 12 words
The composition of claim 1 having a resistivity of about 1.5-3.5 megohms.
Claim 4
Dependent Claim 65 words
The composition of claim 1 wherein the oxirane containing material is selected from the group consisting of ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, an epoxy resins and the sulfonic acid is selected from the group consisting of methane sulfonic acid, para-toluene sulfonic acid, alkyl benzene sulfonic acid wherein the alkyl group contains 2-12 carbon atoms, and 2-methacryloxyethyl sulfonic acid, its homopolymers and copolymers.
Claim 5
Dependent Claim 35 words
The composition of claim 3 wherein said polyester blend contains 65 parts, by weight of the blend, of the polyester component (a) and 35 parts, by weight of the blend, of the polyester component (b).

References Cited (Backward Citations)

US4002777A Cited
US3684565A Cited
US3759854A Cited
US3804920A Cited
US3842021A Cited
US3868338A Cited
DE2356768B1 Cited
GB1481182A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-03-11 1983-09-10 1984-03-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-03-11 1987-09-10 1988-03-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-03-11 1991-09-10 1992-03-11 $7700.00 Window Closed / Lapsed

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