Patent US4192685A successfully refreshed from Google Patents.
US4192685A
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US
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Photocurable unsaturated polyester resin composition and cross-linking agents
Assignee: Teijin Ltd
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Filing: 1978-02-01
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Granted: 1980-03-11
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Expires: 1998-02-01
Abstract
Abstract A photosensitive resin composition consisting essentially of an unsaturated polyester, a cross-linking agent and a photosensitizer, said cross-linking agent consisting of a compound having at least one radical-polymerizable double bond within the molecule and a compound expressed by the following formula ##STR1## wherein n is an integer of at least 1, p, q, and r is 0 or an integer of at least 1 with the proviso that p+q+r equals to 2-6, R 1 is a hydrogen or a methyl group, R 2 is a lower alkyl group optionally substituted with a halogen atom, and R 3 is an alkyl, aryl or acyl group optionally having a substituent.
Inventors
- 👤 Akihiro Horike
- 👤 Yoshio Itakura
- 👤 Tadashi Shingu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 13:20
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; C; C08; C08F; C08F283/00; C08F283/01
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
219 words
In photosensitive resin composition consisting essentially of: an unsaturated polyester having an acid value of at least 20 and present in from 0.01 to 10% by weight based on the weight of the entire composition; a cross-linking agent; and a photosensitizer; the improvement comprising: a cross-linking agent present in from 5 to 70% by weight based on the weight of the entire composition and consisting essentially of the combination of (1) a polyacrylate or polymethacrylate compound, (2) an acrylamide or methacrylamide compound present in from 1 to 20% by weight based on the weight of the entire composition of the formula ##STR5## wherein R is hydrogen or alkyl and X 1 and X 2 are organic groups, and (3) a compound present in from 0.5 to 40% by weight based on the weight of the entire composition and not more than 80% by weight based on the total weight of the cross-linking agent of the formula ##STR6## wherein n is an integer of at least 1, p, q, and r are 0 or an integer of at least 1, with the proviso that p+q+r equals from 2 to 6, R 1 is hydrogen or methyl, R 2 is lower alkyl optionally substituted with a halogen, and R 3 is alkyl, aryl or saturated acyl optionally substituted with a halogen.
Claim 2
Dependent Claim
219 words
In photosensitive resin composition consisting essentially of: an unsaturated polyester having an acid value of at least 20 and present in from 0.01 to 10% by weight based on the weight of the entire composition; a cross-linking agent; and a photosensitizer; the improvement comprising: a cross-linking agent present in from 5 to 70% by weight based on the weight of the entire composition and consisting essentially of the combination of (1) a polyacrylate or polymethacrylate compound, (2) an acrylamide or methacrylamide compound present in from 1 to 20% by weight based on the weight of the entire composition of the formula ##STR5## wherein R is hydrogen or alkyl and X 1 and X 2 are organic groups, and (3) a compound present in from 0.5 to 40% by weight based on the weight of the entire composition and not more than 80% by weight based on the total weight of the cross-linking agent of the formula ##STR6## wherein n is an integer of at least 1, p, q, and r are 0 or an integer of at least 1, with the proviso that p+q+r equals from 2 to 6, R 1 is hydrogen or methyl, R 2 is lower alkyl optionally substituted with a halogen, and R 3 is alkyl, aryl or saturated acyl optionally substituted with a halogen.
Claim 3
Dependent Claim
18 words
The improved composition of claim 1 wherein the acid value of the unsaturated polyester is at least 50.
Claim 4
Dependent Claim
63 words
The improved composition of claim 1 wherein said compound (3) is present in from 0.5 to 30% by weight based on the weight of the entire composition and from 10 to 70% by weight based on the weight of the cross-linking agent, and wherein said compound (2) is present in from 3 to 12% by weight on the weight of the entire composition.
Claim 5
Dependent Claim
45 words
The improved composition of claim 1 with the addition of a heat polymerization inhibitor present in an amount of 0.0001 to 5% by weight based on the weight of the entire composition and selected from the group consisting of phenols, hydroquinones, catechols, or picric acids.
Claim 6
Dependent Claim
81 words
The improved composition of claim 1 wherein compound (2) is selected from the group consisting of acrylamide, diacetone acrylamide, and methacrylamide, compound (1) is selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and and triethylene glycol dimethacrylate, and compound (3) is selected from the group consisting of butoxyethyl methacrylate, diethylene glycol monoethyl ether methacrylate, diethylene glycol monobutyl ether methacrylate, ethoxyethyl methacrylate, 2-hydroxyethyl methacrylate acetate, diethylene glycol monomethacrylate acetate, phenoxyethyl methacrylate, and 3-chloro-2-hydroxypropyl methacrylate acetate.
Claim 7
Dependent Claim
117 words
The composition of claim 1 wherein said acrylamide compound is selected from the group consisting of acrylamide, diacetone acrylamide, N-methylol acrylamide, N-ethylol acrylamide, N-butyrol acrylamide, N-methyl acrylamide, N-isopropyl acrylamide, and N,N-dimethyl acrylamide; said methacrylamide compound is selected from the group consisting of methacrylamide, N-methylol acrylamide, N-ethylolacrylamide, N-butyrol acrylamide, N-methyl methacrylamide and N-isopropyl methacrylamide; said polyacrylate compound is selected from the group consisting of diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, polyethylene glycol diacrylate, trimethylol propane triacrylate and pentaerythritol triacrylate; and said poly methacrylate compound is selected from the group consisting of diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, dipropylene glycol dimethacrylate, polypropylene glycol dimethacrylate, trimethylol propane trimethacrylate and glycerine trimethacrylate.
Claim 8
Dependent Claim
25 words
The composition of claim 1 wherein said compound (2) is at least one compound selected from the group consisting of acrylamide, diacetone acrylamide, and methacrylamide.
Claim 9
Dependent Claim
33 words
The composition of claim 1 wherein said compound (1) is at least one compound selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and triethylene glycol dimethacrylate.
Claim 10
Dependent Claim
43 words
The composition of claim 1 wherein said compound (3) is selected from the group consisting of butoxyethyl methacrylate, diethylene glycol monoethyl ether methacrylate, diethylene glycol monobutyl ether methacrylate, ethoxyethyl methacrylate, 2-hydroxyethyl methacrylate acetate, diethylene glycol monomethacrylate acetate, phenoxyethyl methacrylate, and 3-chloro-2-hydroxypropyl methacrylate acetate.
Claim 11
Dependent Claim
33 words
The composition of claim 1 wherein R 3 is an alkyl group selected from the group consisting of methyl, ethyl, propyl and butyl, said alkyl group optionally being substituted with a halogen atom.
Claim 12
Dependent Claim
32 words
The composition of claim 1 wherein R 3 is an aryl group selected from the group consisting of phenyl and naphthyl, wherein said aryl group may be substituted with a halogen atom.
Claim 13
Dependent Claim
36 words
The composition of claim 1 wherein R 3 is a saturated acyl group selected from the group consisting of acetyl, propionyl, butyryl and benzoyl, wherein said saturated acyl group may be substituted with a halogen atom.
Claim 14
Dependent Claim
88 words
The composition of claim 9 wherein said compound (1) is at least one compound selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and triethylene glycol dimethacrylate; said compound (2) is at least one compound selected from the group consiting of acrylamide, diacetone acrylamide, and methacrylamide; and said compound (3) has as the R 3 moiety in the formula a moiety selected from the group consisting of methyl, ethyl, propyl, butyl, phenyl, naphthyl, acetyl, propionyl, butyryl, benzoyl, and their halogen substitution products.
Claim 15
Dependent Claim
53 words
The compound of claim 13 wherein the acid value of the unsaturated polyester is at least 50, and wherein said compound (2) is present in from 3 to 12% and said compound (3) is present in from 10 to 70%, both amounts being by weight based on the weight of the entire composition.
References Cited (Backward Citations)
US3628963A
Cited
US3839171A
Cited
GB1304112A
Cited
US3759807A
Cited
JPS4814173B1
Cited
US3695877A
Cited
US3794494A
Cited
US3827959A
Cited
US3827960A
Cited
JPS51999A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-03-11 | 1983-09-10 | 1984-03-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-03-11 | 1987-09-10 | 1988-03-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-03-11 | 1991-09-10 | 1992-03-11 | $7700.00 | Window Closed / Lapsed |