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Iridium oxide based electrochromic devices

Assignee: AT&T Inc
•
Filing: 1978-06-27
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Granted: 1980-03-04
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Expires: 1998-06-27
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Abstract

Abstract Electrochromic devices based on anodic iridium oxide as the electrochromic material have been made. These devices exhibit long term stability, memory, and good response times, e.g., less than 80 msec. for reflectivity changes of about 70% (50 msec. for 50% changes). Devices using an anodic iridium oxide film immersed in a sulfate electrolyte have been operated for more than 6×10 5 coloration/bleaching cycles at 0.5 Hz without noticeable change in properties. Response times and stability are also improved by a heat treatment of the anodic iridium oxide at temperatures between 40 and 100 degrees C.

Inventors

  • 👤 Gerardo Beni
  • 👤 Shimshon Gottesfeld
  • 👤 James D. E. McIntyre
  • 👤 Joseph L. Shay

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:44
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1514; G02F1/1523; G02F1/1525; G02F1/1524; G02F1/15245

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 71 words
An electrochromic device comprising a first electrode and a second electrode contacted with an electrolyte CHARACTERIZED IN THAT said first electrode contains anodic iridium oxide, said electrolyte has a pH in the range 2 to 12 and said electrolyte has an ionic conductivity greater than 0.01 ohm -1 cm -1 , whereby when an electrical potential is applied between said first electrode and said second electrode a reflectivity change is produced.
Claim 2
Dependent Claim 71 words
An electrochromic device comprising a first electrode and a second electrode contacted with an electrolyte CHARACTERIZED IN THAT said first electrode contains anodic iridium oxide, said electrolyte has a pH in the range 2 to 12 and said electrolyte has an ionic conductivity greater than 0.01 ohm -1 cm -1 , whereby when an electrical potential is applied between said first electrode and said second electrode a reflectivity change is produced.
Claim 3
Dependent Claim 18 words
The electrochemical device of claim 1 wherein the electrolyte has a pH in the range 3.5 to 10.5.
Claim 4
Dependent Claim 11 words
The electrochromic device of claim 1 wherein said electrolyte is acidic.
Claim 5
Dependent Claim 12 words
The electrochromic device of claim 1 wherein said electrolyte contains sulfate ions.
Claim 6
Dependent Claim 15 words
The electrochromic device of claim 4 wherein said electrolyte anion content consists essentially of sulfate.
Claim 7
Dependent Claim 26 words
The electrochromic device of claim 1 wherein said applied electrical potential is less than a potential which produces further substantial growth of said anodic iridium oxide.
Claim 8
Dependent Claim 16 words
The electrochromic device of claim 1 wherein said first electrode is essentially free of elemental Ir.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-03-04 1983-09-03 1984-03-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-03-04 1987-09-03 1988-03-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-03-04 1991-09-03 1992-03-04 $7700.00 Window Closed / Lapsed

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