US4191249A
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US
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Reducing the relative water/petroleum movement in a petroleum producing reservoir
Assignee: Union Oil Company of California
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Filing: 1978-11-16
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Granted: 1980-03-04
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Expires: 1998-11-16
Abstract
Abstract A method for reducing the relative water/petroleum movement in a reservoir wherein there is injected a slug of an oil containing both an oil-soluble thickening agent and a suspension of a solid particulate water-soluble thickening agent.
Inventors
- 👤 Amir M. Sarem
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:58
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/52; C09K8/528; C09K8/54; C09K8/58; C09K8/588; Y; Y10; Y10S; Y10S166/00; Y10S166/902
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
49 words
A method fo reducing the relative water/petroleum movement in a petroleum-containing water drive reservoir penetrated by one or more wells comprising: (a) injecting into the reservoir a slug of an oil containing both an oil-soluble thickening agent and a solid particulate water-soluble thickening agent, and (b) producing the well.
Claim 2
Independent Claim
49 words
A method fo reducing the relative water/petroleum movement in a petroleum-containing water drive reservoir penetrated by one or more wells comprising: (a) injecting into the reservoir a slug of an oil containing both an oil-soluble thickening agent and a solid particulate water-soluble thickening agent, and (b) producing the well.
Claim 3
Dependent Claim
24 words
The method of claim 1 wherein the method is preceded by the injection of a slug of an aqueous composition containing a scale inhibitor.
Claim 4
Dependent Claim
96 words
The method of claim 2 wherein the scale inhibitor is selected from the group consisting of a water-soluble polyvalent metal salt of a hydrolyzed polyacrylamide having a molecular weight of about 5,000 to 50,000; a sulfonated alkali lignin having a degree of sulfonation of about 0.8 to 4.0; a polyamino polycarboxylic compound; a polyphosphate glass; an organic phosphate; a phosphate mixed ester of hydroxy amines containing less than 8 carbon atoms in hydrocarbon groups attached to the amino nitrogen and hydroxy hydrocarbons containing at least 6 carbon atoms in a hydrocarbon group; and a phosphoric acid.
Claim 5
Dependent Claim
46 words
The method of claim 1 wherein the oil-soluble thickening agent is selected from the group consisting of polymethyl laurylate, polyalkyl styrene, polybutadiene, polyisobutylene, a bivalent or trivalent metallic soap of a monocarboxylic acid having 14 or more carbon atoms per molecule and, a powdered colloidal silica.
Claim 6
Dependent Claim
23 words
The method of claim 1 wherein the oil-soluble thickening agent is present in a concentration of about 0.2 to 2 percent by weight.
Claim 7
Dependent Claim
48 words
The method of claim 1 wherein the water-soluble thickening agent is selected from the group consisting of water-soluble polymers, cellulose derivatives, alkaline alkali metal silicates having a molar ratio of M 2 O/SiO 2 of 1 or above wherein M is an alkali metal atom, and natural gums.
Claim 8
Dependent Claim
14 words
The method of claim 6 wherein the water-soluble thickening agent is partially hydrolyzed polyacrylamide.
Claim 9
Dependent Claim
23 words
The method of claim 1 wherein the water-soluble thickening agent is present in a concentration of about 0.2 to 2 percent by weight.
Claim 10
Independent Claim
122 words
A method for reducing the water/oil ratio produced from a well completed in an oil-containing water drive reservoir penetrated by one or more wells comprising: (a) injecting into the reservoir a slug of an oil containing both an oil-soluble thickening agent selected from the group consisting of polymethyl laurylate, polyalkyl styrene, polybutadiene, polyisobutylene, a bivalent or trivalent metallic soap of a monocarboxylic acid having 14 or more carbon atoms, a powdered colloidal silica and a solid particulate water-soluble thickening agent selected from the group consisting of water-soluble polymers, cellulose derivatives, alkaline alkali metal silicates having a molar ratio of M 2 O/SiO 2 of 1 or above wherein M is an alkali metal atom, and natural gums, and (b) producing the well.
Claim 11
Independent Claim
122 words
A method for reducing the water/oil ratio produced from a well completed in an oil-containing water drive reservoir penetrated by one or more wells comprising: (a) injecting into the reservoir a slug of an oil containing both an oil-soluble thickening agent selected from the group consisting of polymethyl laurylate, polyalkyl styrene, polybutadiene, polyisobutylene, a bivalent or trivalent metallic soap of a monocarboxylic acid having 14 or more carbon atoms, a powdered colloidal silica and a solid particulate water-soluble thickening agent selected from the group consisting of water-soluble polymers, cellulose derivatives, alkaline alkali metal silicates having a molar ratio of M 2 O/SiO 2 of 1 or above wherein M is an alkali metal atom, and natural gums, and (b) producing the well.
Claim 12
Independent Claim
200 words
A method for prolonging the life of a scale inhibitor injected into an oil-containing water drive reservoir comprising: (a) injecting a slug of an aqueous composition containing a scale inhibitor selected from the group consisting of a water-insoluble polyvalent metal salt of a hydrolyzed polyacrylamide having a molecular weight of about 5,000 to 50,000; a sulfonated alkali lignin having a degree of sulfonation of about 0.8 to 4.0; a polyamino polycarboxylic compound; a polyphosphate glass; an organic phosphate; a phosphate mixed ester of hydroxy amines containing less than 8 carbon atoms in hydrocarbon groups attached to the amino nitrogen and hydroxy hydrocarbons containing at least 6 carbon atoms in a hydrocarbon group; and a phosphoric acid, (b) injecting a slug of an oil containing both an oil-soluble thickening agent selected from the group consisting of polymethyl laurylate, polyalkyl styrene, polybutadiene, polyisobutylene, a bivalent or trivalent metallic soap of a monocarboxylic acid and a solid particulate water-soluble thickening agent selected from the group consisting of water-soluble polymers, cellulose derivatives, alkaline alkali metal silicates having a molar ratio of M 2 O/SiO 2 of 1 or above wherein M is an alkali metal atom, and natural gums, and (c) producing the well.
Claim 13
Independent Claim
200 words
A method for prolonging the life of a scale inhibitor injected into an oil-containing water drive reservoir comprising: (a) injecting a slug of an aqueous composition containing a scale inhibitor selected from the group consisting of a water-insoluble polyvalent metal salt of a hydrolyzed polyacrylamide having a molecular weight of about 5,000 to 50,000; a sulfonated alkali lignin having a degree of sulfonation of about 0.8 to 4.0; a polyamino polycarboxylic compound; a polyphosphate glass; an organic phosphate; a phosphate mixed ester of hydroxy amines containing less than 8 carbon atoms in hydrocarbon groups attached to the amino nitrogen and hydroxy hydrocarbons containing at least 6 carbon atoms in a hydrocarbon group; and a phosphoric acid, (b) injecting a slug of an oil containing both an oil-soluble thickening agent selected from the group consisting of polymethyl laurylate, polyalkyl styrene, polybutadiene, polyisobutylene, a bivalent or trivalent metallic soap of a monocarboxylic acid and a solid particulate water-soluble thickening agent selected from the group consisting of water-soluble polymers, cellulose derivatives, alkaline alkali metal silicates having a molar ratio of M 2 O/SiO 2 of 1 or above wherein M is an alkali metal atom, and natural gums, and (c) producing the well.
Claim 14
Dependent Claim
22 words
The method of claim 10 wherein the scale inhibitor is present in a concentration of about 0.5 to 5 percent by weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-03-04 | 1983-09-03 | 1984-03-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-03-04 | 1987-09-03 | 1988-03-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-03-04 | 1991-09-03 | 1992-03-04 | $7700.00 | Window Closed / Lapsed |