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US4190712A Expired / Lapsed US ⏱️ 0.0 years remaining

Low density energy management urethane foam

Assignee: Davidson Rubber Co Inc
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Filing: 1978-08-25
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Granted: 1980-02-26
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Expires: 1998-08-25
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Abstract

Abstract An impact energy-absorbing, low density urethane foam for use in automobile bumpers has good moldability and is relatively temperature insensitive, i.e. gives approximately the same physical performance over a wide range of temperatures. This foam is characterized by its good multiple impact performance and low compression set values. The foam is water blown in a closed mold from a quasi-prepolymer system. The molded density is preferably in the range of 5 to 10 PCF. The foam formulation is based on a polymer polyol of a poly (oxypropylene/ethylene) triol reacted with a styrene/acrylonitrile monomer mixture which triol thus modified is reacted with (1) a roughly 1/5 to 1.5/1 weight amount of a hydroxy terminated polybutadiene homopolymer based on polymer polyol, (2) a 50 to 150 equivalent weight polyol crosslinker of 2 to 6 functionality, (3) a MDI glycol or triol quasi-prepolymer, and (4) some water.

Inventors

  • 👤 Kirby E. L. Flanagan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:52
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/6552; C08G18/6558; C08G18/6564; C08G18/40; C08G18/63; C08G18/632; C08G18/6576; C08G18/6582; C08G18/6588; C08G18/67; C08G18/69; C08G18/698; C08G18/70; C08G18/72; C08G18/80; C08G18/8003; C08G18/8006; C08G18/8009; C08G18/8035; B; B60; B60R; B60R19/00; B60R19/02; B60R19/18; B60R2019/186; C08G2110/00; C08G2110/0041; C08G2110/0058; C08G2110/0066; C08G2110/0083; Y; Y10; Y10S; Y10S264/00; Y10S264/14

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 303 words
An impact energy-absorbing urethane foam made from the following formulation: ______________________________________ Parts by Weight ______________________________________ Polymer polyol 70 to 90 Polybutadiene polymer 10 to 120 Crosslinker 10 to 40 Water 1 to 5 Prepolymer To yield 90-115% Index Catalyst 0 to 2 ______________________________________ wherein: said polymer polyol has a molecular weight in the range of 4000 to 8000 and comprises in the range of 2 to 6 parts of a poly (C 2 -C 4 oxyalkylene) triol reacted with one part of a vinyl aromatic/olefinic C 3 -C 7 nitrile monomer mixture; said polybutadiene polymer is a hydroxy terminated polybutadiene homopolymer having a molecular weight in the range of 2000 to 4000, a functionality in the range of 2 to 3, and an equivalent weight in the range of 750 to 1750; said crosslinker is a polyol having a functionality in the range of 2 to 6 and an equivalent weight in the range of 50 to 150; said prepolymer is a reaction product of (a) an aromatic diisocyanate having one isocyanato group per aromatic nucleus and (b) a polyol having a molecular weight in the range of 100 to 1000, a functionality in the range of 2 to 6, an equivalent weight in the range of 30 to 150, and said prepolymer has a free isocyanate content in the range of 20 to 35 percent; and said urethane foam being prepared in a closed mold and having a density in the range of 4 to 15 lbs./ft. 3 , a specific energy at 50% C/D greater than 15 in.-lbs./in. 3 at 70° F. and 7 PCF, a temperature index -20°/125° F. of less than 5 and suffering less than a 3% impact set when impacted to a strain of 75% at 70° F. after allowing recovery for 30 minutes at 70° F.
Claim 2
Dependent Claim 303 words
An impact energy-absorbing urethane foam made from the following formulation: ______________________________________ Parts by Weight ______________________________________ Polymer polyol 70 to 90 Polybutadiene polymer 10 to 120 Crosslinker 10 to 40 Water 1 to 5 Prepolymer To yield 90-115% Index Catalyst 0 to 2 ______________________________________ wherein: said polymer polyol has a molecular weight in the range of 4000 to 8000 and comprises in the range of 2 to 6 parts of a poly (C 2 -C 4 oxyalkylene) triol reacted with one part of a vinyl aromatic/olefinic C 3 -C 7 nitrile monomer mixture; said polybutadiene polymer is a hydroxy terminated polybutadiene homopolymer having a molecular weight in the range of 2000 to 4000, a functionality in the range of 2 to 3, and an equivalent weight in the range of 750 to 1750; said crosslinker is a polyol having a functionality in the range of 2 to 6 and an equivalent weight in the range of 50 to 150; said prepolymer is a reaction product of (a) an aromatic diisocyanate having one isocyanato group per aromatic nucleus and (b) a polyol having a molecular weight in the range of 100 to 1000, a functionality in the range of 2 to 6, an equivalent weight in the range of 30 to 150, and said prepolymer has a free isocyanate content in the range of 20 to 35 percent; and said urethane foam being prepared in a closed mold and having a density in the range of 4 to 15 lbs./ft. 3 , a specific energy at 50% C/D greater than 15 in.-lbs./in. 3 at 70° F. and 7 PCF, a temperature index -20°/125° F. of less than 5 and suffering less than a 3% impact set when impacted to a strain of 75% at 70° F. after allowing recovery for 30 minutes at 70° F.
Claim 3
Dependent Claim 84 words
The urethane foam of claim 1 wherein: said polymer polyol is a 6000 molecular weight copolymer of a poly (oxypropylene-ethylene) triol reacted with a 50/50 by weight styrene/acrylonitrile monomer mixture; said polybutadiene polymer has a molecular weight of about 3000, a functionality of about 2.3, and an equivalent weight of 1250; said crosslinker is a sorbitol polyether having a reactive hydrogens and an equivalent weight of 115; said prepolymer is the reaction product of MDI and tripropylene glycol; and said catalyst is triethylene diamine.

References Cited (Backward Citations)

US3248373A Cited
US3591561A Cited
US3595814A Cited
US3664976A Cited
US3661811A Cited
US3630973A Cited
US4119586A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-25 1983-08-27 1984-02-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-25 1987-08-27 1988-02-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-25 1991-08-27 1992-02-26 $7700.00 Window Closed / Lapsed

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