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Passivation of metals on cracking catalysts with an antimony tris (hydrocarbyl sulfide)

Assignee: Phillips Petroleum Co
•
Filing: 1978-07-25
•
Granted: 1980-02-26
•
Expires: 1998-07-25
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Abstract

Abstract A hydrocarbon cracking catalyst is treated with an antimony tris (hydrocarbyl sulfide) to passivate thereon contaminating metals, e.g., vanadium, iron, and/or nickel. Used or unused catalyst can be treated.

Inventors

  • 👤 Brent J. Bertus
  • 👤 Dwight L. McKay
  • 👤 Harold W. Mark

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 06:21
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; Y; Y10; Y10S; Y10S502/00; Y10S502/521

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 29 words
A method for passivating a contaminating metal upon a hydrocarbon cracking catalyst, which comprises contacting said cracking catalyst with an antimony tris (hydrocarbyl sulfide) to add the same thereto.
Claim 2
Independent Claim 29 words
A method for passivating a contaminating metal upon a hydrocarbon cracking catalyst, which comprises contacting said cracking catalyst with an antimony tris (hydrocarbyl sulfide) to add the same thereto.
Claim 3
Dependent Claim 35 words
A process according to claim 1 wherein the cracking catalyst is one which contains at least one of silica-alumina and a zeolite and the contaminating metal is at least one of vanadium, iron, and/or nickel.
Claim 4
Dependent Claim 31 words
A cracking catalyst suitable for cracking a hydrocarbon which has been treated to passivate a contaminating metal whenever it appears thereon by incorporating with said catalyst an antimony tris (hydrocarbyl sulfide).
Claim 5
Dependent Claim 31 words
A cracking catalyst suitable for cracking a hydrocarbon which has been treated to passivate a contaminating metal whenever it appears thereon by incorporating with said catalyst an antimony tris (hydrocarbyl sulfide).
Claim 6
Dependent Claim 29 words
A cracking catalyst suitable for cracking a hydrocarbon which has been treated to passivate a contaminating metal whenever it appears thereon, by incorporating with said catalyst antimony tris (thiophenoxide).
Claim 7
Dependent Claim 29 words
A cracking catalyst suitable for cracking a hydrocarbon which has been treated to passivate a contaminating metal whenever it appears thereon, by incorporating with said catalyst antimony tris (thiophenoxide).
Claim 8
Dependent Claim 29 words
A method according to claim 1 wherein the antimony tris (hydrocarbyl sulfide) is represented by the formula (RS) 3 Sb wherein R contains not more than 18 carbon atoms.
Claim 9
Dependent Claim 39 words
A method according to claim 5 wherein the antimony compound is at least one selected from antimony tris (ethyl sulfide), antimony tris (cyclohexylsulfide), antimony tris (tetradecyl sulfide), antimony tris (thiophenoxide), antimony tris (benzyl sulfide), and antimony tris (dibutylphenyl sulfide).
Claim 10
Dependent Claim 14 words
A method according to claim 1 wherein the antimony compound is antimony tris (thiophenoxide).

References Cited (Backward Citations)

US2129693A Cited
US3506567A Cited
US3711422A Cited
US3756989A Cited
US4031002A Cited
US3979472A Cited
US4036740A Cited
US4111845A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-25 1983-08-27 1984-02-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-25 1987-08-27 1988-02-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-25 1991-08-27 1992-02-26 $7700.00 Window Closed / Lapsed

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