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US4189942A Expired / Lapsed US ⏱️ 0.0 years remaining

Temperature indicating device using a pressure sensitive polyisobutylene adhesive seal

Assignee: PY MAH Corp
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Filing: 1978-04-13
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Granted: 1980-02-26
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Expires: 1998-04-13
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Abstract

Abstract There is provided a temperature indicating device such as a thermometer having a thermally conductive foil as a carrier layer, the carrier layer having one or more cavities formed by depression in the foil material. The depressions are filled with solid mixtures which melt at predetermined temperatures and are composed of ortho-chloronitrobenzene, ortho-bromonitrobenzene, and a dyestuff. A transparent cover layer seals the cavities and their contents. The transparent cover layer and carrier layer are bonded to each other by means of a pressure-sensitive adhesive which includes polyisobutylene.

Inventors

  • 👤 Egenius A. Giezen
  • 👤 Gerrit D. B. van Houwelingen
  • 👤 Marietta Cramer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:41
CPC Classifications
C; C09; C09B; C09B69/00; C09K; C09K5/00; C09K5/02; C09K5/06; C09K9/00; C09K9/02; G; G01; G01K; G01K11/00; G01K11/06; G01K11/12; G01K11/16; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/24; Y10T428/24479; Y10T428/24521; Y10T428/24545; Y10T428/24554; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/269; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696; Y10T428/31855; Y10T428/31931

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 95 words
A temperature indicating device comprising (a) a thermally conductive foil as a carrier layer provided with one or more cavities formed by depressions in the foil material, at least one of which depressions is filled with a solid mixture which melts at a predetermined temperature and includes ortho-chloronitrobenzene, ortho-bromonitrobenzene and a dyestuff, and (b) a transparent cover layer sealing said cavities and their contents, characterized in that said transparent cover layer and said carrier layer are bonded to each other by means of an adhesive layer of a pressure-sensitive adhesive, said adhesive being substantially polyisobutylene.
Claim 2
Dependent Claim 95 words
A temperature indicating device comprising (a) a thermally conductive foil as a carrier layer provided with one or more cavities formed by depressions in the foil material, at least one of which depressions is filled with a solid mixture which melts at a predetermined temperature and includes ortho-chloronitrobenzene, ortho-bromonitrobenzene and a dyestuff, and (b) a transparent cover layer sealing said cavities and their contents, characterized in that said transparent cover layer and said carrier layer are bonded to each other by means of an adhesive layer of a pressure-sensitive adhesive, said adhesive being substantially polyisobutylene.
Claim 3
Dependent Claim 26 words
A temperature indicating device according to claim 1, characterized in that the average molecular weight of said polyisobutylene is in the range of 50,000 to 5,000,000.
Claim 4
Dependent Claim 26 words
A temperature indicating device according to claim 2, characterized in that the average molecular weight of said polyisobutylene is in the range of 150,000 to 4,000,000.
Claim 5
Dependent Claim 53 words
A temperature indicating device according to claim 2, characterized in that said adhesive layer includes a mixture of 30-70% by weight of polyisobutylene having an average molecular weight in the range of 70,000 to 100,000 and 70-30% by weight of polyisobutylene having an average molecular weight in the range of 1,000,000 to 3,500,000.
Claim 6
Dependent Claim 48 words
A temperature indicating device according to claim 4, characterized in that said adhesive layer includes practically equal parts by weight of polyisobutylene having an average molecular weight in the range of 70,000 to 100,000 and polyisobutylene having an average molecular weight in the range of 1,000,000 to 3,500,000.
Claim 7
Dependent Claim 21 words
A temperature indicating device according to claim 1, characterized in that said carrier layer includes aluminium foil having an etched surface.
Claim 8
Dependent Claim 31 words
A temperature indicating device according to claim 6, characterized in that said carrier layer includes aluminium foil provided with a polyisobutylene surface layer applied from a solution in an organic solvent.
Claim 9
Dependent Claim 28 words
A temperature indicating device according to claim 7, characterized in that said polyisobutylene surface layer applied to the carrier layer has a thickness of 2 to 10 microns.
Claim 10
Dependent Claim 34 words
A temperature indicating device according to claim 7, characterized in that said surface layer applied to the carrier layer is of polyisobutylene having an average molecular weight in the range of 2,000,000 to 3,500,000.
Claim 11
Dependent Claim 48 words
A temperature indicating device according to claim 9, characterized in that said carrier layer provided with a polyisobutylene surface layer is bonded to the transparent cover layer by means of a pressure-sensitive adhesive layer of polyisobutylene having an average molecular weight in the range of 2,000,000 to 3,500,000.
Claim 12
Dependent Claim 56 words
A temperature indicating device according to claim 1, characterized in that said dyestuff is selected from the group of dyestuffs which in accordance with the Colour Index are referred to as solvent blue 10, solvent blue 44, solvent blue 45, solvent blue 49, solvent blue 67, solvent red 90, solvent orange 59 and solvent green 19.
Claim 13
Dependent Claim 21 words
A temperature indicating device according to claim 1, further including an indicator layer of absorbent material superimposed on the solid mixture.
Claim 14
Dependent Claim 108 words
A temperature indicating device comprising (a) a thermally conductive foil as a carrier layer provided with one or more cavities formed by depressions in the foil material, at least one of which depressions is filled with a solid mixture which melts at a predetermined temperature and includes ortho-chloronitrobenzene, ortho-bromonitrobenzene and a dyestuff, and (b) an indicator layer of absorbent material superimposed on the solid mixture, and (c) a transparent cover layer sealing the cavities and their contents, characterized in that the transparent cover layer and the carrier layer are bonded to each other by means of an adhesive layer of a pressure-sensitive adhesive, said adhesive being substantially polyisobutylene.
Claim 15
Dependent Claim 108 words
A temperature indicating device comprising (a) a thermally conductive foil as a carrier layer provided with one or more cavities formed by depressions in the foil material, at least one of which depressions is filled with a solid mixture which melts at a predetermined temperature and includes ortho-chloronitrobenzene, ortho-bromonitrobenzene and a dyestuff, and (b) an indicator layer of absorbent material superimposed on the solid mixture, and (c) a transparent cover layer sealing the cavities and their contents, characterized in that the transparent cover layer and the carrier layer are bonded to each other by means of an adhesive layer of a pressure-sensitive adhesive, said adhesive being substantially polyisobutylene.
Claim 16
Dependent Claim 26 words
A temperature indicating device according to claim 13, characterized in that the average molecular weight of the polyisobutylene is in the range of 50,000 to 5,000,000.
Claim 17
Dependent Claim 26 words
A temperature indicating device according to claim 14, characterized in that the average molecular weight of the polyisobutylene is in the range of 150,000 to 4,000,000.
Claim 18
Dependent Claim 53 words
A temperature indicating device according to claim 14, characterized in that the adhesive layer includes a mixture of 30-70% by weight of polyisobutylene having an average molecular weight in the range of 70,000 to 100,000 and 70-30% by weight of polyisobutylene having an average molecular weight in the range of 1,000,000 to 3,500,000.
Claim 19
Dependent Claim 49 words
A temperature indicating device according to claim 16, characterized in that the adhesive layer consists of practically equal parts by weight of polyisobutylene having an average molecular weight in the range of 70,000 to 100,000 and polyisobutylene having an average molecular weight in the range of 1,000,000 to 3,500,000.
Claim 20
Dependent Claim 22 words
A temperature indicating device according to claim 13, characterized in that the carrier layer consists of aluminium foil having an etched surface.
Claim 21
Dependent Claim 32 words
A temperature indicating device according to claim 18, characterized in that the carrier layer consists of aluminium foil provided with a polyisobutylene surface layer applied from a solution in an organic solvent.
Claim 22
Dependent Claim 28 words
A temperature indicating device according to claim 19, characterized in that the polyisobutylene surface layer applied to the carrier layer has a thickness of 2 to 10 microns.
Claim 23
Dependent Claim 34 words
A temperature indicating device according to claim 19, characterized in that the surface layer applied to the carrier layer is of polyisobutylene having an average molecular weight in the range of 2,000,000 to 3,500,000.
Claim 24
Dependent Claim 48 words
A temperature indicating device according to claim 21, characterized in that the carrier layer provided with a polyisobutylene surface layer is bonded to the transparent cover layer by means of a pressure-sensitive adhesive layer of polyisobutylene having an average molecular weight in the range of 2,000,000 to 3,500,000.
Claim 25
Dependent Claim 56 words
A temperature indicating device according to claim 13, characterized in that the dyestuff is selected from the group of dyestuffs which in accordance with the Colour Index are referred to as solvent blue 10, solvent blue 44, solvent blue 45, solvent blue 49, solvent blue 67, solvent red 90, solvent orange 59 and solvent green 19.

References Cited (Backward Citations)

US3002385A Cited
US3704985A Cited
US3826141A Cited
US3946612A Cited
US3765243A Cited
US3922917A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-25 1983-08-27 1984-02-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-25 1987-08-27 1988-02-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-25 1991-08-27 1992-02-26 $7700.00 Window Closed / Lapsed

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