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US4189397A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilization of 1,1,1-trichloroethane compositions against metal-induced decomposition with a polyalkylene glycol monoalkyl ether

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1977-12-15
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Granted: 1980-02-19
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Expires: 1997-12-15
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Abstract

Abstract 1,1,1-trichloroethane is stabilised against metal-induced decomposition by incorporating a polyalkylene glycol monoalkyl ether.

Inventors

  • 👤 Christopher S. Allen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:50
CPC Classifications
C; C23; C23G; C23G5/00; C23G5/02; C23G5/028; C23G5/02854; C23G5/02861; C23G5/02877; C07; C07C; C07C17/00; C07C17/38; C07C17/42

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 57 words
A stabilised solvent composition consisting essentially of 1,1,1-trichloroethane with a stabilising amount of from 0.01% to 5% by weight of a stabiliser which is a polyalkylene glycol monoalkyl ether of formula ##STR2## where R is an alkyl group containing 1 to 4 carbon atoms, R' is hydrogen or a methyl group and n is 2 or 3.
Claim 2
Dependent Claim 57 words
A stabilised solvent composition consisting essentially of 1,1,1-trichloroethane with a stabilising amount of from 0.01% to 5% by weight of a stabiliser which is a polyalkylene glycol monoalkyl ether of formula ##STR2## where R is an alkyl group containing 1 to 4 carbon atoms, R' is hydrogen or a methyl group and n is 2 or 3.
Claim 3
Dependent Claim 15 words
A composition as claimed in claim 1 wherein the stabiliser is diethylene glycol monoalkyl ether.
Claim 4
Dependent Claim 15 words
A composition as claimed in claim 2 wherein the stabiliser is diethylene glycol monomethyl ether.
Claim 5
Dependent Claim 15 words
A composition as claimed in claim 2 wherein the stabiliser is diethylene glycol monoethyl ether.
Claim 6
Dependent Claim 16 words
A composition stabilised as claimed in claim 2 wherein the stabiliser is diethylene glycol monobutyl ether.
Claim 7
Dependent Claim 26 words
A composition as claimed in claim 1 wherein the stabiliser is present in an amount in the range 0.2% to 5% by weight of the solvent.
Claim 8
Dependent Claim 19 words
A composition as claimed in claim 6 wherein the range is 0.2% to 2% by weight of the solvent.
Claim 9
Dependent Claim 41 words
A composition as claimed in claim 1 in which there is also incorporated a stabilising amount of at least one additional stabiliser selected from the group consisting of organic nitrates, nitriles, nitroalkanes, epoxides, cyclic ethers, amines, alcohols, pyrrole and substituted pyrroles.
Claim 10
Dependent Claim 29 words
A composition as claimed in claim 8 in which the at least one additional stabiliser is present in an amount not greater than 3% by weight of the 1,1,1-trichloroethane.
Claim 11
Dependent Claim 29 words
A method of inhibiting decomposition of 1,1,1-trichloroethane due to the presence of metals which comprises incorporating in said 1,1,1-trichloroethane a polyalkylene glycol monoalkyl ether as described in claim 1.
Claim 12
Dependent Claim 32 words
The method of claim 10 further comprising incorporating at least one additional stabiliser selected from the group consisting of organic nitrates, nitriles, nitroalkanes, epoxides, cyclic ethers, amines, alcohols, pyrrole, and substituted pyrroles.
Claim 13
Dependent Claim 25 words
A method of degreasing metal and other articles which comprises bringing the articles into contact with the stabilised solvent composition as described in claim 11.
Claim 14
Dependent Claim 34 words
The method of claim 12 wherein said solvent composition includes at least one additional stabiliser selected from the group consisting of organic nitrates, nitriles, nitroalkanes, epoxides, cyclic ethers, amines, alcohols, pyrrole, and substituted pyrroles.

References Cited (Backward Citations)

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GB892286A Cited
US3074890A Cited
GB930973A Cited
US3128315A Cited
US3269953A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-18 1983-08-20 1984-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-18 1987-08-20 1988-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-18 1991-08-20 1992-02-19 $7700.00 Window Closed / Lapsed

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