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US4189205A Expired / Lapsed US ⏱️ 0.0 years remaining

Coated copper reflector

Assignee: INFRARED IND Inc
•
Filing: 1978-02-21
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Granted: 1980-02-19
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Expires: 1998-02-21
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Abstract

Abstract A reflector or mirror for the visible and rear infrared spectrum is formed by multicoating copper with one-fifth wavelength and three-quarter wavelength films. These films are alternating low and high index films, and MgF 2 and TiO 2 are presently preferred. A thin bonding layer of TiO 2 is used to secure adhesion of the MgF 2 to the copper. This coating enhances the reflectance in the visible range without appreciable degradation of reflectance in the near infrared, so that the resultant curve of reflectance-versus-frequency is substantially flat. The resulting coating is hard and tough and may be cleaned without injury and withstands high humidity.

Inventors

  • 👤 Peter T. Vandehei

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 17:11
CPC Classifications
G; G02; G02B; G02B5/00; G02B5/08; G02B5/0816; G02B5/085; G02B5/0858; C; C03; C03C; C03C17/00; C03C17/34; C03C17/36; C03C17/3602; C03C17/3615; C03C17/3621; C03C17/3649; C03C17/3657; C03C17/3663; G02B5/20; G02B5/28; G02B5/281; G02B5/282; G02B5/285; C03C2217/00; C03C2217/70; C03C2217/73; C03C2217/734

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 111 words
In a metallic copper reflector having an enhanced reflectance in the visible wavelength range without substantial degradation in the near infrared and resistant to humidity and abrasion, the improvement comprising: (a) first layer on said copper of hard transparent material having a thickness of twenty to one hundred Angstroms; (b) a second layer of low-index transparent material having an optical thickness of 0.2 of a visible wavelength; (c) a third layer of high-index transparent material having an optical thickness of one-fourth of said visible wavelength; (d) and at least one pair of layers of first low-index and then high-index transparent materials, each layer having a thickness of one-fourth of said wavelength.
Claim 2
Dependent Claim 111 words
In a metallic copper reflector having an enhanced reflectance in the visible wavelength range without substantial degradation in the near infrared and resistant to humidity and abrasion, the improvement comprising: (a) first layer on said copper of hard transparent material having a thickness of twenty to one hundred Angstroms; (b) a second layer of low-index transparent material having an optical thickness of 0.2 of a visible wavelength; (c) a third layer of high-index transparent material having an optical thickness of one-fourth of said visible wavelength; (d) and at least one pair of layers of first low-index and then high-index transparent materials, each layer having a thickness of one-fourth of said wavelength.
Claim 3
Dependent Claim 16 words
A reflector as set forth in claim 1 wherein said first layer is TiO 2 .
Claim 4
Dependent Claim 23 words
A reflector as set forth in claim 1 wherein the low-index material is MgF 2 and the high-index material is TiO 2 .
Claim 5
Dependent Claim 24 words
A reflector as set forth in claim 1 wherein the wavelength is in the range of four hundred seventy-five to five hundred twenty-five millimicrons.
Claim 6
Dependent Claim 105 words
In a metallic copper reflector having an enhanced reflectance in the visible wavelength range, the improvement comprising: (a) a protective layer of hard transparent material on said copper; (b) a first layer of low-index material on said protective layer having an optical thickness of 0.2 of a selected visible wavelength; (c) a second layer of high-index transparent material on said low-index layer having an optical thickness of one-fourth of said wavelength; (d) and at least one pair of layers placed on said second layer of first low-index and then high-index transparent material, each layer having an optical thickness of one fourth of said visible wavelength.
Claim 7
Dependent Claim 105 words
In a metallic copper reflector having an enhanced reflectance in the visible wavelength range, the improvement comprising: (a) a protective layer of hard transparent material on said copper; (b) a first layer of low-index material on said protective layer having an optical thickness of 0.2 of a selected visible wavelength; (c) a second layer of high-index transparent material on said low-index layer having an optical thickness of one-fourth of said wavelength; (d) and at least one pair of layers placed on said second layer of first low-index and then high-index transparent material, each layer having an optical thickness of one fourth of said visible wavelength.
Claim 8
Independent Claim 130 words
The method of improving the reflectance of copper in the visible spectrum without substantial degradation in the near infrared range, which comprises: (a) selecting a wavelength in the visible spectrum about which enhancement is desired; (b) depositing an opaque layer of copper upon a substrate over a time period not exceeding two minutes; (c) immediately thereafter coating the copper with a transparent layer of material of a thickness sufficient to protect the copper from oxidation; (d) coating the protected surface with a low-index transparent material to a thickness of 0.2 of the selected wavelength; (e) and coating said low-index material with alternate layers of first high-index and then low-index transparent material, each having a thickness of one-fourth of said selected wavelength until at least three of said coatings are added.
Claim 9
Independent Claim 130 words
The method of improving the reflectance of copper in the visible spectrum without substantial degradation in the near infrared range, which comprises: (a) selecting a wavelength in the visible spectrum about which enhancement is desired; (b) depositing an opaque layer of copper upon a substrate over a time period not exceeding two minutes; (c) immediately thereafter coating the copper with a transparent layer of material of a thickness sufficient to protect the copper from oxidation; (d) coating the protected surface with a low-index transparent material to a thickness of 0.2 of the selected wavelength; (e) and coating said low-index material with alternate layers of first high-index and then low-index transparent material, each having a thickness of one-fourth of said selected wavelength until at least three of said coatings are added.

References Cited (Backward Citations)

US2519722A Cited
US2854349A Cited
US3758185A Cited
US4065626A Cited
US4142006A Cited
US4093349A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-02-18 1983-08-20 1984-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-02-18 1987-08-20 1988-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-02-18 1991-08-20 1992-02-19 $7700.00 Window Closed / Lapsed

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