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US4186267A
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Nickel stabilizers for synthetic polymers
Assignee: BASF Corp
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Filing: 1977-08-24
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Granted: 1980-01-29
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Expires: 1997-08-24
Abstract
Abstract Nickel complexes containing ortho- or para-hydroxybenzoate anions and a non-ionic amine ligand are valuable light-stabilizers for polymers, particularly for polyolefins. The complexes may also contain a second carboxylate anion, different from the benzoate anion, and in this case also the amine-free nickel compounds show a high stabilizing action.
Inventors
- 👤 Michael Rasberger
- 👤 Jean Rody
- 👤 Paul Moser
- 👤 Helmut Muller
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 08:21
CPC Classifications
C; C07; C07F; C07F15/00; C07F15/02; C07F15/025; C08; C08K; C08K5/00; C08K5/0091; C08K5/16; C08K5/17
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
128 words
Compounds of the formula I ##STR8## wherein either R 1 is hydroxyl and R 2 is hydrogen or R 1 is hydrogen and R 2 is hydroxyl, R 3 and R 4 are hydrogen or alkyl with 1-5 C atoms, either p is 1 and q is 1 or p is 2 and q is zero, X is optionally mono hydroxyl-substituted alkyl, cycloalkyl, phenyl, alkaphenyl, or phenylalkyl, m is a value from 1-2 and, n represents a value from 0 to 2 and L denotes a ligand R 5 --N(R 6 )--R 7 , wherein R 5 and R 6 together with the N atom form a pyrrolidine, or piperidine ring which is substituted by alkyl groups or is unsubstituted and R 7 is H, alkyl or phenylalkyl.
Claim 2
Dependent Claim
128 words
Compounds of the formula I ##STR8## wherein either R 1 is hydroxyl and R 2 is hydrogen or R 1 is hydrogen and R 2 is hydroxyl, R 3 and R 4 are hydrogen or alkyl with 1-5 C atoms, either p is 1 and q is 1 or p is 2 and q is zero, X is optionally mono hydroxyl-substituted alkyl, cycloalkyl, phenyl, alkaphenyl, or phenylalkyl, m is a value from 1-2 and, n represents a value from 0 to 2 and L denotes a ligand R 5 --N(R 6 )--R 7 , wherein R 5 and R 6 together with the N atom form a pyrrolidine, or piperidine ring which is substituted by alkyl groups or is unsubstituted and R 7 is H, alkyl or phenylalkyl.
Claim 3
Dependent Claim
132 words
Compounds according to claim 1, of the formula I, wherein R 1 , R 2 , R 3 , R 4 , m and n have the abovementioned meaning and L denotes a ligand R 5 --N(R 6 )--R 7 , wherein R 5 and R 6 together with the N atom form a piperidine ring, which is substituted by methyl groups or is unsubstituted, and R 7 is H, alkyl with 1-8 C atoms or aralkyl with 7-11 C atoms and either p is 1 and q is 1 or p is 2 and q is zero, and X is alkyl or hydroxyalkyl with 1-22 C atoms, cycloalkyl with 4-10 C atoms, phenyl which is optionally substituted by alkyl with 1-4 C atoms and/or hydroxyl, or phenylalkyl with 7-16 C atoms.
Claim 4
Dependent Claim
108 words
Compounds according to claim 1, of the formula I, wherein R 1 is hydroxyl, R 2 is hydrogen and R 3 and R 4 are each tertiary butyl, m is the number 1, n denotes a value from 0 to 2 and L denotes a ligand R 5 --N(R 6 )--R 7 , wherein R 5 and R 6 together with the N atom form a 2,2,6,6-tetramethylpiperidine ring and R 7 is H or alkyl with 1 to 8 C atoms, and either p is 1 and q is 1 or p is 2 and q is zero, and X is alkyl with 1 to 18 C atoms.
Claim 5
Dependent Claim
122 words
Compounds of the formula I according to claim 1, wherein either R 1 represents a hydroxyl group and R 2 represents hydrogen or R 1 represents hydrogen and R 2 represents a hydroxyl group, R 3 and R 4 represent hydrogen or alkyl with 1 to 5 C atoms, m represents a value from 1 to 2 and n represents a value from 0 to 2 and L denotes a ligand of the formula R 5 --N(R 6 )--R 7 , wherein R 5 and R 6 together with the N atom form a pyrrolidine, piperidine ring which is substituted by alkyl groups or is unsubstituted, and R 7 is H, alkyl or phenylalkyl and p is 2 and q is zero.
Claim 6
Dependent Claim
49 words
Compounds according to claim 4, wherein R 5 and R 6 together with the N atom form a piperidine ring which is substituted by methyl groups or is unsubstituted, and R 7 is H, alkyl with 1 to 8 C atoms or phenylalkyl with 7 to 11 C atoms.
Claim 7
Dependent Claim
59 words
Compounds according to claim 4, wherein R 1 represents a hydroxyl group, R 2 represents hydrogen, R 3 and R 4 each represent a tertiary butyl group, m represents the number 1, R 5 and R 6 together with the N atom form a 2,2,6,6-tetramethylpiperidine ring and R 7 is H or alkyl with 1 to 8 C atoms.
Claim 8
Dependent Claim
9 words
A compound of claim 1, having the formula ##STR9##
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-28 | 1983-07-30 | 1984-01-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-28 | 1987-07-30 | 1988-01-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-28 | 1991-07-30 | 1992-01-29 | $7700.00 | Window Closed / Lapsed |