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US4185965A Expired / Lapsed US ⏱️ 0.0 years remaining

Amine derivatives of hydrocarbyl lactam carboxylic acids as fuel additives

Assignee: Texaco Inc
•
Filing: 1977-12-27
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Granted: 1980-01-29
•
Expires: 1997-12-27
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Abstract

Abstract This invention relates to motor fuel compositions containing dihydroimidazoline, tetrahydropyrimidine and amide derivatives of hydrocarbyl substituted lactam acids.

Inventors

  • 👤 Raymond C. Schlicht
  • 👤 William M. Cummings

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 07:47
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/232

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 217 words
A motor fuel composition comprising a mixture of hydrocarbons in the gasoline boiling range and an additive mixture including, in a concentration of from 0.001 to 0.1 weight percent, a substituted butyrolactam of the formula: ##STR5## wherein R is a hydrocarbyl radical of from 1 to 12 carbon atoms, an N-mono- or N,N-di-hydrocarbyl substituted aminoalkyl radical wherein each hydrocarbyl moiety and said alkyl moiety contains from 1 to 12 carbon atoms, or an N-butyrolactam alkyl radical containing the substituents R 1 , R 2 and R 3 and wherein said alkyl moiety contains from 1 to 12 carbon atoms; R 1 is a hydrocarbon radical of from 1 to 20 carbon atoms; each of R 2 and R 3 is a hydrogen atom or a hydrocarbyl radical of from 1 to 500 carbon atoms, provided that only one of R 2 and R 3 is hydrogen; and only one of R 2 and R 3 is hydrocarbyl; each of R 4 and R 5 is hydrogen or a hydrocarbyl radical of from 1 to 25 carbon atoms; R 6 is a hydrocarbyl radical of from 1 to 25 carbon atoms or an amino alkyl or poly (azaalkyl) radical; n has a value of 0 to 1 inclusive; and each of said hydrocarbyl substituents is unsubstituted or substituted.
Claim 2
Dependent Claim 217 words
A motor fuel composition comprising a mixture of hydrocarbons in the gasoline boiling range and an additive mixture including, in a concentration of from 0.001 to 0.1 weight percent, a substituted butyrolactam of the formula: ##STR5## wherein R is a hydrocarbyl radical of from 1 to 12 carbon atoms, an N-mono- or N,N-di-hydrocarbyl substituted aminoalkyl radical wherein each hydrocarbyl moiety and said alkyl moiety contains from 1 to 12 carbon atoms, or an N-butyrolactam alkyl radical containing the substituents R 1 , R 2 and R 3 and wherein said alkyl moiety contains from 1 to 12 carbon atoms; R 1 is a hydrocarbon radical of from 1 to 20 carbon atoms; each of R 2 and R 3 is a hydrogen atom or a hydrocarbyl radical of from 1 to 500 carbon atoms, provided that only one of R 2 and R 3 is hydrogen; and only one of R 2 and R 3 is hydrocarbyl; each of R 4 and R 5 is hydrogen or a hydrocarbyl radical of from 1 to 25 carbon atoms; R 6 is a hydrocarbyl radical of from 1 to 25 carbon atoms or an amino alkyl or poly (azaalkyl) radical; n has a value of 0 to 1 inclusive; and each of said hydrocarbyl substituents is unsubstituted or substituted.
Claim 3
Dependent Claim 37 words
A motor fuel composition as claimed in claim 1, wherein said gasoline boiling range is from about 75° F. to 450° F., and said butyrolactam is present in a concentration of about 0.01 to 0.075 weight percent.
Claim 4
Dependent Claim 23 words
A motor fuel composition as claimed in claim 2, wherein R 3 is an alkenyl radical of from 8 to 500 carbon atoms.
Claim 5
Dependent Claim 23 words
A motor fuel composition as claimed in claim 2, wherein R 2 is an alkenyl radical of from 8 to 500 carbon atoms.
Claim 6
Dependent Claim 14 words
A motor fuel composition as claimed in claim 2, wherein R 1 is phenyl.
Claim 7
Dependent Claim 21 words
A motor fuel composition as claimed in claim 2, wherein each of R 4 and R 5 is a hydrogen atom.
Claim 8
Dependent Claim 28 words
A motor fuel composition as claimed in claim 2, wherein R 6 is an aminoalkyl radical in which said alkyl group contains from 1 to 6 carbon atoms.
Claim 9
Dependent Claim 38 words
A motor fuel composition as claimed in claim 2, wherein R 6 is a poly(azaalkyl) radical in which each alkyl moiety contains from 2 to 6 carbon atoms and said azaalkyl moieties recur from 1 to 10 times.
Claim 10
Dependent Claim 24 words
A motor fuel composition as claimed in claim 2, wherein R is an N-(butyrolactam) alkyl radical in which said N-(butyrolactam) is a recurring unit.
Claim 11
Dependent Claim 23 words
A motor fuel composition as claimed in claim 2, wherein R is a lower alkyl group of from 1 to 6 carbon atoms.
Claim 12
Dependent Claim 13 words
A motor fuel composition as claimed in claim 2, wherein R is methyl.
Claim 13
Dependent Claim 15 words
A motor fuel composition as claimed in claim 2, wherein R is an N,N-dialkylaminoalkyl substituent.
Claim 14
Dependent Claim 26 words
A motor fuel composition as claimed in claim 2, wherein R 2 or R 3 is an alkenyl radical of from 8 to 300 carbon atoms.
Claim 15
Dependent Claim 37 words
A motor fuel composition as claimed in claim 2, wherein R is an N-(butyrolactam) alkyl moiety isomeric or identical to that to which R is attached and said alkyl moiety contains from 1 to 7 carbon atoms.
Claim 16
Dependent Claim 19 words
A motor fuel composition as claimed in claim 13, wherein R 2 or R 3 is a polybutenyl radical.
Claim 17
Dependent Claim 19 words
A motor fuel composition as claimed in claim 13, wherein R 2 or R 3 is a tetrapropenyl radical.
Claim 18
Dependent Claim 16 words
A motor fuel composition as claimed in claim 2, wherein n has a value of 0.
Claim 19
Dependent Claim 16 words
A motor fuel composition as claimed in claim 2, wherein said butyrolactam is 2(3)-polybutenyl-3-(1'-aminoethyl dihydroimidazolin-2'-yl)-4-phenyl-5-methyl butyrolactam.
Claim 20
Dependent Claim 15 words
A motor fuel composition as claimed in claim 2, wherein said butyrolactam is 2(3)-polybutenyl-3-[1'-(3,6,9-triazanonyl)-dihydroimidazolin-2'-yl]-4-phenyl-5-methyl butyrolactam.

References Cited (Backward Citations)

US3138610A Cited
US4070370A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-01-28 1983-07-30 1984-01-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-01-28 1987-07-30 1988-01-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-01-28 1991-07-30 1992-01-29 $7700.00 Window Closed / Lapsed

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