Stripping column and process for removal of volatile matter

Claim 2

A process for removing volatile matter from a slurry containing sedimentary solid matter and the volatile matter comprising feeding the slurry into a stripping column at the top portion while introducing a stripping gas into the column at the bottom portion, said column comprising a plurality of trays disposed one above another and each comprising a plurality of tray segments and a downcomer, each of the tray segments being so formed as to have a plurality of inclined slits and inclined planes to provide a gas-liquid-solid mixed phase above the tray, said tray segments being so arranged that the direction of the slits vary from segment to segment in turn thereby accelerating the flowing velocity of the slurry on the tray and providing a zigzag flow to the slurry on the tray; the improvement comprising the steps of: inhibiting the gas-solid-liquid mixed phase on the tray from flowing freely to the downcomer to the next lower tray to thereby ensure a sufficient resident time of said mixed phase on the tray; simultaneously with said inhibiting step preventing deposit of sedimentary matter on the tray by passing and guiding a part of the slurry to said downcomer; effecting said step of simultaneously inhibiting said free flow of said mixed phase and preventing depositing of sedimentary matter on the tray by providing a baffle on the downstream side of the tray and providing a clearance between the lower end of the baffle plate and the tray such that the baffle restricts the flow of the said mixed phase while the clearance passes a part of the slurry and the sedimentary matter which would otherwise deposit on the tray; and impinging and directing at least part of said mixed phase to the underside of the next higher tray to thereby clean said next upper tray and render the tray self-cleaning, said impinging and directing step being effected by providing at least one stream breaker above the tray and providing said stream breaker with a plurality of slits through which the mixed phase blows to impinge on the overlying tray to effecting said cleaning.

Claim 3

A process according to claim 1 wherein said step of impinging and directing at least a part of the mixed phase to the underside of the next higher tray comprises directing said mixed phase upwardly perpendicular to the reverse side of the next upper tray.

Claim 4

A process according to claim 1 further comprising disposing the stream breaker so as to form an acute angle between the stream breaker and the tray in the range of 40°-75°.

Claim 5

A process according to claim 1 wherein said stream breaker is made of expanded metal.

Claim 6

A process according to claim 1, wherein the slurry is an aqueous slurry compring polyvinlchloride particles and vinylchloride monomer and the stripping gas is steam.

Claim 7

A process according to claim 5, wherein all of the condensate withdrawn from the column at the top is refluxed thereto.

Claim 8

A process according to claim 1, wherein the stripping gas is fed at the top portion of the column and simultaneously at the bottom portion thereof.

Claim 9

A process according to claim 1, wherein the stripping gas is steam.

Claim 10

A process for removing vinyl chloride monomer from an aqueous polyvinyl chloride slurry containing the vinyl chloride monomer comprising the steps of: feeding the slurry into a stripping column at the top portion while introducing a stripping gas into the column at the bottom portion, said column comprising a plurality of trays disposed one above another and each comprising a plurality of tray segments and a downcomer, each of the tray segments being so formed as to have a plurality of inclined slits and inclined planes to provide a gas-liquid-solid mixed phase above the tray, said tray segments being so arranged that the direction of the slits vary from segment to segment in turn thereby accelerating the flowing velocity of the slurry on the tray and providing a zigzag flow to the slurry on the tray; inhibiting the gas-solid-liquid mixed phase on the tray from flowing freely to the downcomer to the next lower tray to thereby ensure a sufficient resident time of said mixed phase on the tray; simultaneously with said inhibiting step preventing deposit of sedimentary matter on the tray by passing and guiding a part of the slurry to said downcomer; effecting said step of simultaneously inhibiting said free flow of said mixed phase and preventing depositing of sedimentary matter on the tray by providing a baffle on the downstream side of the tray and providing a clearance between the lower end of the baffle plate and the tray such that the baffle restricts the flow of the said mixed phase while the clearance passes a part of the slurry and the sedimentary matter which would otherwise deposit on the tray; impinging and directing at least part of said mixed phase to the underside of the next higher tray to thereby clean said next higher tray and render the tray self-cleaning; said impinging and directing step being effected by providing stream breakers above the tray and providing said stream breakers with a plurality of slits through which the mixed phase blows to impinge on said next overlying tray to effect said cleaning; maintaining the slurry at at least 40° C. at the top of the column and not higher than 110° C. at the bottom thereof while the column is kept at a reduced pressure; and then recovering the volatile matter from the column at the top and the volatile matter-stripped slurry therefrom at the bottom.

Claim 11

A process for removing vinyl chloride monomer from an aqueous polyvinyl chloride slurry containing the vinyl chloride monomer comprising the steps of: feeding the slurry into a stripping column at the top portion while introducing a stripping gas into the column at the bottom portion, said column comprising a plurality of trays disposed one above another and each comprising a plurality of tray segments and a downcomer, each of the tray segments being so formed as to have a plurality of inclined slits and inclined planes to provide a gas-liquid-solid mixed phase above the tray, said tray segments being so arranged that the direction of the slits vary from segment to segment in turn thereby accelerating the flowing velocity of the slurry on the tray and providing a zigzag flow to the slurry on the tray; inhibiting the gas-solid-liquid mixed phase on the tray from flowing freely to the downcomer to the next lower tray to thereby ensure a sufficient resident time of said mixed phase on the tray; simultaneously with said inhibiting step preventing deposit of sedimentary matter on the tray by passing and guiding a part of the slurry to said downcomer; effecting said step of simultaneously inhibiting said free flow of said mixed phase and preventing depositing of sedimentary matter on the tray by providing a baffle on the downstream side of the tray and providing a clearance between the lower end of the baffle plate and the tray such that the baffle restricts the flow of the said mixed phase while the clearance passes a part of the slurry and the sedimentary matter which would otherwise deposit on the tray; impinging and directing at least part of said mixed phase to the underside of the next higher tray to thereby clean said next higher tray and render the tray self-cleaning; said impinging and directing step being effected by providing stream breakers above the tray and providing said stream breakers with a plurality of slits through which the mixed phase blows to impinge on said next overlying tray to effect said cleaning; maintaining the slurry at at least 40° C. at the top of the column and not higher than 110° C. at the bottom thereof while the column is kept at a reduced pressure; and then recovering the volatile matter from the column at the top and the volatile matter-stripped slurry therefrom at the bottom.

Claim 12

A stripping column for removing volatile matter from a slurry containing sedimentary solid matter and the volatile matter by contacting the slurry with a stripping gas, comprising a plurality of trays each comprising a plurality of tray segments and a downcomer, each of the tray segments being so formed as to have a plurality of inclined planes and inclined slits so that the opening direction (Z) of the slits of each tray segment is different from, or crosses obliquely, the direction (Y) of the main stream of the slurry on the tray and so that the opening direction of the slits of one tray segment is different from, or crosses obliquely, that of the slits of another tray segment adjacent to the former, thereby enabling the slurry on the tray and the gas-solid-liquid mixed phase formed above the tray by the stripping gas blown upward through the slits to flow zigzag, characterized by a baffle plate installed above the down-stream end of the tray with a clearance being provided between the tray and the lower end of the baffle plate, thereby to guide the sedimentary solid matter through the clearance to the downcomer without deposition thereof on the tray, said baffle plate also inhibiting the free flow of the gas-solid-liquid mixed phase on the tray to the downcomer to thereby ensure a sufficient residence time of said mixed phase on the tray, and further comprising at least one slitted stream breaker disposed above the tray, said stream breaker having means defining a plurality of upwardly directed slits which open upwardly to pass the gas-solid-liquid mixed phase upwardly to impinge on the reverse side of the next overlying upper tray, thereby cleaning and preventing the slits of the next upper tray from becoming clogged.

Claim 13

A stripping column for removing volatile matter from a slurry containing sedimentary solid matter and the volatile matter by contacting the slurry with a stripping gas, comprising a plurality of trays each comprising a plurality of tray segments and a downcomer, each of the tray segments being so formed as to have a plurality of inclined planes and inclined slits so that the opening direction (Z) of the slits of each tray segment is different from, or crosses obliquely, the direction (Y) of the main stream of the slurry on the tray and so that the opening direction of the slits of one tray segment is different from, or crosses obliquely, that of the slits of another tray segment adjacent to the former, thereby enabling the slurry on the tray and the gas-solid-liquid mixed phase formed above the tray by the stripping gas blown upward through the slits to flow zigzag, characterized by a baffle plate installed above the down-stream end of the tray with a clearance being provided between the tray and the lower end of the baffle plate, thereby to guide the sedimentary solid matter through the clearance to the downcomer without deposition thereof on the tray, said baffle plate also inhibiting the free flow of the gas-solid-liquid mixed phase on the tray to the downcomer to thereby ensure a sufficient residence time of said mixed phase on the tray, and further comprising at least one slitted stream breaker disposed above the tray, said stream breaker having means defining a plurality of upwardly directed slits which open upwardly to pass the gas-solid-liquid mixed phase upwardly to impinge on the reverse side of the next overlying upper tray, thereby cleaning and preventing the slits of the next upper tray from becoming clogged.

Claim 14

A stripping column according to claim 10 wherein the stream breaker is disposed to provide an acute angle between the stream breaker and the tray in the range of 40°-75°.

Claim 15

A stripping column according to claim 10, wherein the stream breaker is made of expanded metal.

Claim 16

A stripping column according to claim 10 wherein said baffle plate is of a solid material.

Claim 17

A stripping column according to claim 10, wherein said clearance between the tray and the lower end of the baffle plate is in the range of 2 to 10 mm.

Claim 18

A stripping column according to claim 10, wherein the portion of the tray just below the downcomer of the next upper tray forms a deck plate inclined with respect to the tray thereby to prevent stagnation of the slurry on said portion.

Claim 19

A stripping column according to claim 10, further comprising a perforated support ring supporting the tray thereon.

Claim 20

A stripping column according to claim 10, wherein the plurality of tray segments are each made of expanded metal.