Abstract Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable azo dye moiety. The compound has the formula: ##STR1## wherein: G is a metal chelating group (or a salt or hydrolyzable precursor thereof) or a group which together with a ##STR2## is CAR (bonded through the oxygen); G 1 is a hydroxy group (or a salt or hydrolyzable precursor thereof); Z is an electron withdrawing group; Z' is alkyl, aryl or N(R) 2 (R being H, alkyl or aryl); CAR is a ballasted carrier moiety; and t is 0 or 1. The dye can be transferred imagewise to an image-receiving layer where it can be contacted with metal ions to form a metal-complexed azo dye transfer image of excellent stability. The retained dye image in the photographic element can also be bleached, fixed and metallized to form a color transparency or a motion picture film.
A photographic element comprising a support having thereon a layer comprising a photographic mordant having bound thereto a coordination complex of a polyvalent metal ion and a compound having the following formula: ##STR27## wherein: G is a metal chelating group; Z is an electron withdrawing group having the formula --CON(R) 2 , --SO 2 N(R) 2 , --COOR, --CN, SO 2 R' or --COR', wherein R' is an alkyl group of 1 to 8 carbon atoms or an aryl group of 6 to 10 carbon atoms, and each R is H or R'; and Z' is an alkyl group of 1 to 8 carbon atoms, an aryl group of 6 to 10 carbon atoms or N(R) 2 .
Claim 2
Dependent Claim
118 words
A photographic element comprising a support having thereon a layer comprising a photographic mordant having bound thereto a coordination complex of a polyvalent metal ion and a compound having the following formula: ##STR27## wherein: G is a metal chelating group; Z is an electron withdrawing group having the formula --CON(R) 2 , --SO 2 N(R) 2 , --COOR, --CN, SO 2 R' or --COR', wherein R' is an alkyl group of 1 to 8 carbon atoms or an aryl group of 6 to 10 carbon atoms, and each R is H or R'; and Z' is an alkyl group of 1 to 8 carbon atoms, an aryl group of 6 to 10 carbon atoms or N(R) 2 .
Claim 3
Dependent Claim
24 words
The photographic element of claim 1 wherein the metal ion is nickel (II), copper (II), zinc (II), platinum (II), palladium (II) or cobalt (II).