Pivalyl-acetanilide couplers and photographic elements including them

Claim 2

A multilayer color photographic element including a base and at least one silver halide emulsion layer characterized by having at least one two-equivalent pivalylacetanilide coupler having attached to the reactive methylene thereof a 5-membered heterocyclic nucleus, said nucleus bonded to said methylene from a nitrogen atom in the 1-position on said heterocyclic nucleus, said 5-membered nucleus having nitrogen atoms in the 2- and 4-positions respectively bonded by double bonds to carbon atoms in the 3- and 5-positions, said at least one coupler being in reactive association with the silver halide of said at least one silver halide emulsion.

Claim 3

A photographic element according to claim 1 characterized by having said at least one coupler dissolved in a substantially water-immiscible organic solvent dispersed in said at least one silver halide emulsion layer.

Claim 4

A photographic element according to claim 2 wherein said at least one coupler is further characterized by having at least one substituent attached to the phenyl nucleus of the acetanilide moiety thereof selected from the class consisting of halogen, alkyl, carboxy and sulphoxy directly attached to said phenyl nucleus or attached through amine, carbonyl, alkylene, oxygen, sulphur, or phenyl groups.

Claim 5

A photographic element according to claim 3 wherein said at least one coupler is characterized by having, attached to the phenyl nucleus of the acetanilide moiety thereof, a substituent selected from the class consisting of halogen and alkyl groups directly attached to said phenyl nucleus or attached to said phenyl nucleus through amine, carbonyl, oxygen, sulphur, or phenyl groups.

Claim 6

A photographic element according to claim 4 further characterized by having, attached to the aniline moiety thereof or the 5-membered heterocyclic nucleus, alkyl groups having a total of from 10 to 25 carbon atoms.

Claim 7

A photographic element according to claim 1 wherein said at least one coupler is further characterized by having attached to the reactive methylene as said 5-membered heterocyclic a 1,2,4-triazole group as a splitting off nucleus, and by having attached to the 3-position of said five-membered heterocyclic nucleus a substituent selected from the class consisting of halogen, carboxy acid ester, phenyl, alkyl, phenylamino, 4-nitrogen containing heterocyclic, alkylthio, alkylsulfoxy, and amino groups.

Claim 8

A photographic element according to claim 1 wherein said at least one coupler is further characterized by said splitting off heterocyclic nucleus being represented by the formulae: ##STR5## wherein R 1 and R 2 each represent a hydrogen atom or a substituent chosen within the class of halogen; a carboxy acid ester whose alkyl chain has from 1 to 18 carbon atoms; an amino group; a nitrogen containing heterocyclic nucleus attached through said nitrogen atom; an alkyl group having from 1 to 18 carbon atoms; an alkylthio or alkoxy group having from 1 to 18 carbon atoms; an alkylsulphoxy group having from 1 to 18 carbon atoms; a carboxy acid group; a sulphoxy acid group; a non substituted phenyl group or a phenyl group substituted with substituents chosen from the class consisting of halogen, alkyl having from 1 to 18 carbon atoms; carboxy acid ester whose alkyl chain contains from 1 to 18 carbon atoms, cyano, an alkoxy group having from 1 to 18 carbon atoms, and a sulphoxy acid group.

Claim 9

The photographic element of claim 1 wherein said 5-membered heterocyclic nucleus attached to the reactive methylene is 1,2,4-triazole.