Patent US4181766A successfully refreshed from Google Patents.
US4181766A
Expired / Lapsed
US
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Laminates comprising weatherable coatings and primer compositions comprising a mixture of an acrylic polymer and a cellulosic ester
Assignee: 3M Co
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Filing: 1978-09-01
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Granted: 1980-01-01
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Expires: 1998-09-01
Abstract
Abstract The ability to withstand weathering by acrylic substrates having an abrasion resistant coating comprising a cured epoxy-terminated silane on the surface thereof is improved by using a particular primer composition between the coating and the substrate. The primer comprises a mixture of an acrylic polymer and cellulose esters of carboxylic acids.
Inventors
- 👤 Brian H. Williams
- 👤 J. Lamar Zollinger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 12:28
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/04; C08J7/042; C08J7/043; C08J7/046; C08J2333/00; C08J2333/04; C08J2333/06; C08J2333/10; C08J2333/12; C08J2401/00; C08J2401/08; C08J2401/10; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/25; Y10T428/252; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31652; Y10T428/31663; Y10T428/31667; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31891; Y10T428/31909; Y10T428/31928; Y10T428/31935
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
200 words
A multi-layered article comprising an acrylic substrate comprising at least 70% by weight of units having the formula: ##STR6## having coated on one surface thereof a composition comprising: (a) 10 to 85 percent by weight of an acrylic polymer comprising repeating units of the formula ##STR7## wherein R is H or CH 3 and R 4 is an alkyl group of 1 to 4 carbon atoms, said polymer having no more than 50% by weight of said repeating units having R 4 groups of more than 2 carbon atoms, (b) 15 to 90 percent by weight of cellulose esters of carboxylic acids, said esters having 0.5 to 5.5 percent by weight of unesterified hydroxyl groups, a viscosity at 25° C. of 300 to 10,000 centipoise, and an acyl content of no more than 56 percent by weight derived from carboxylic acids having 2 to 4 carbon atoms and no more than 20 percent by weight of said acyl content being derived from carboxylic acids having fewer than 3 carbon atoms, and (c) 0 to 65 percent by weight of an aliphatic epoxy compound, and coated over said composition an abrasion resistant coating comprising the cured product of an epoxy-terminated silane.
Claim 2
Dependent Claim
200 words
A multi-layered article comprising an acrylic substrate comprising at least 70% by weight of units having the formula: ##STR6## having coated on one surface thereof a composition comprising: (a) 10 to 85 percent by weight of an acrylic polymer comprising repeating units of the formula ##STR7## wherein R is H or CH 3 and R 4 is an alkyl group of 1 to 4 carbon atoms, said polymer having no more than 50% by weight of said repeating units having R 4 groups of more than 2 carbon atoms, (b) 15 to 90 percent by weight of cellulose esters of carboxylic acids, said esters having 0.5 to 5.5 percent by weight of unesterified hydroxyl groups, a viscosity at 25° C. of 300 to 10,000 centipoise, and an acyl content of no more than 56 percent by weight derived from carboxylic acids having 2 to 4 carbon atoms and no more than 20 percent by weight of said acyl content being derived from carboxylic acids having fewer than 3 carbon atoms, and (c) 0 to 65 percent by weight of an aliphatic epoxy compound, and coated over said composition an abrasion resistant coating comprising the cured product of an epoxy-terminated silane.
Claim 3
Dependent Claim
95 words
The article of claim 1 wherein said epoxy-terminated silane is selected from the group consisting of: ##STR8## wherein R 2 is a non-hydrolyzable divalent group of fewer than 12 carbon atoms, the backbone of which is composed of only C and O atoms or only C atoms, with no two oxygen atoms adjacent within the backbone of the divalent group, R 3 is selected from the groups consisting of an aliphatic hydrocarbon group of fewer than 10 carbon atoms and an acyl group of fewer than 10 carbon atoms, and m is 1 or 2.
Claim 4
Dependent Claim
37 words
The article of claim 1 wherein said epoxy-terminated silane is represented by the formula ##STR9## wherein n is 1 to 4, p is 1 to 6, and R 3 is alkyl of 1 to 4 carbon atoms.
Claim 5
Dependent Claim
71 words
The article of claim 2 wherein said abrasion resistant coating has a dry thickness of 2 to 30 microns and said cured composition contains 50 to 95 percent by weight of units derived from said epoxy-terminated silane, said coating further comprising at least 0.25% by weight of an ultraviolet radiation absorber, at least 0.001 percent by weight of an antioxidant, and at least 5% by weight of an aliphatic epoxide comonomer.
Claim 6
Dependent Claim
25 words
The article of claim 2 wherein said cellulose esters comprise an ester selected from the group consisting of cellulose acetate butyrate and cellulose acetate propionate.
Claim 7
Dependent Claim
25 words
The article of claim 4 wherein said cellulose esters comprise an ester selected from the group consisting of cellulose acetate butyrate and cellulose acetate propionate.
Claim 8
Dependent Claim
59 words
The article of claim 4 wherein said cellulose esters comprise an ester selected from the group consisting of cellulose acetate butyrate and cellulose acetate propionate, said acrylic polymer comprises a polymer which is selected from the class consisting of poly(methyl methacrylate) and poly(ethyl methacrylate), and said ultraviolet radiation absorbers are selected from the class consisting of benzophenones and benzotriazoles.
Claim 9
Dependent Claim
13 words
The article of claim 1 wherein said acrylic substrate comprises a retroreflective substrate.
Claim 10
Dependent Claim
13 words
The article of claim 5 wherein said acrylic substrate comprises a retroreflective substrate.
Claim 11
Dependent Claim
13 words
The article of claim 1 wherein said acrylic substrate comprises a retroreflective substrate.
Claim 12
Dependent Claim
12 words
The article of claim 5 wherein said epoxy-terminated silane comprises 3-glycidoxypropyltrimethoxy silane.
Claim 13
Dependent Claim
12 words
The article of claim 10 wherein said epoxy-terminated silane comprises 3-glycidoxypropyltrimethoxy silane.
Claim 14
Dependent Claim
42 words
The article of claim 2 wherein said composition has a dried coating thickness of at least 1.8 microns and said abrasion resistant coating layer is between 2 and 30 microns and is no more than four times the thickness of said composition.
Claim 15
Dependent Claim
42 words
The article of claim 5 wherein said composition has a dried coating thickness of at least 1.8 microns and said abrasion resistant coating layer is between 2 and 30 microns and is no more than four times the thickness of said composition.
Claim 16
Dependent Claim
42 words
The article of claim 7 wherein said composition has a dried coating thickness of at least 1.8 microns and said abrasion resistant coating layer is between 2 and 30 microns and is no more than four times the thickness of said composition.
Claim 17
Dependent Claim
42 words
The article of claim 12 wherein said composition has a dried coating thickness of at least 1.8 microns and said abrasion resistant coating layer is between 2 and 30 microns and is no more than four times the thickness of said composition.
Claim 18
Dependent Claim
16 words
The article of claim 7 wherein the aliphatic epoxy compound in said composition is 3,4-epoxycyclohexyl-methyl-3,4-epoxycyclohexane carboxylate.
Claim 19
Dependent Claim
20 words
The article of claims 8, 9, or 10 wherein said retrereflective sheeting comprises enclosed lens sheeting or encapsulated lens sheeting.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-12-31 | 1983-07-02 | 1984-01-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-12-31 | 1987-07-02 | 1988-01-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-12-31 | 1991-07-02 | 1992-01-01 | $7700.00 | Window Closed / Lapsed |