Patent US4181687A successfully refreshed from Google Patents.
US4181687A
Expired / Lapsed
US
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Bonding thermoplastic resins
Assignee: OSI Specialties Inc
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Filing: 1978-10-02
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Granted: 1980-01-01
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Expires: 1998-10-02
Abstract
Abstract Bonding between thermoplastic resins and inorganic oxide substrates is improved by providing to the resin/inorganic oxide interface as an adhesion promoter a combination of (a) a copolymer of an ethylenically unsaturated organic monomer and an unsaturated organosilane containing hydrolyzable groups; and (b) a monomeric hydrolytically reactive organosilane.
Inventors
- 👤 Robert J. Ward
- 👤 James H. Kawakami
- 👤 Neil J. McCarthy, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:18
CPC Classifications
C; C09; C09D; C09D201/00; C08; C08K; C08K5/00; C08K5/54; C08K9/00; C08K9/04; C08K9/06; C08L; C08L101/00; C08L43/00; C08L43/04; C09J; C09J157/00; C09J157/04; C09J5/00; C09J5/02; C08L2666/00; C08L2666/02; C08L2666/14; C09J2400/00; C09J2400/20; C09J2400/22; C09J2400/228; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31703
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
218 words
An improved thermoplastic resin composition, having excellent bond strength with inorganic oxide substrates, comprising: (A) a thermoplastic resin; (B) from about 0.05 to about 10 weight percent, based on the weight of said thermoplastic resin (A) of a copolymer having polymerized therein (i) from 75 to 95 mole percent of at least one ethylenically unsaturated organic monomer and (ii) from 5 to 25 mole percent of at least one unsaturated organosilane monomer of the formula RSiX n R'.sub.(3-n) wherein R is a monovalent organic radical containing a vinyl group, R' is a monovalent hydrocarbon radical containing up to 10 carbon atoms, n is a integer from 1 to 3, and X is a hydrolyzable group chosen from the group consisting of alkoxy of 1 to 4 carbon atoms, alkoxyalkoxy containing up to 6 carbon atoms, acyloxy of 2 to 4 carbon atoms, phenoxy, and oxime; and (C) from about 0.1 to about 100 mole percent, based on the number of moles of polymerized unsaturated organosilane present in the copolymer component (B) of a monomeric hydrolytically reactive organosilane of the formula R".sub.(4-x) SiX x wherein X is a hydrolyzable group as previously defined, R" is a monovalent organic radical of from 1 to 12 carbon atoms and x is a integer having a value of from 1 to 4.
Claim 2
Dependent Claim
218 words
An improved thermoplastic resin composition, having excellent bond strength with inorganic oxide substrates, comprising: (A) a thermoplastic resin; (B) from about 0.05 to about 10 weight percent, based on the weight of said thermoplastic resin (A) of a copolymer having polymerized therein (i) from 75 to 95 mole percent of at least one ethylenically unsaturated organic monomer and (ii) from 5 to 25 mole percent of at least one unsaturated organosilane monomer of the formula RSiX n R'.sub.(3-n) wherein R is a monovalent organic radical containing a vinyl group, R' is a monovalent hydrocarbon radical containing up to 10 carbon atoms, n is a integer from 1 to 3, and X is a hydrolyzable group chosen from the group consisting of alkoxy of 1 to 4 carbon atoms, alkoxyalkoxy containing up to 6 carbon atoms, acyloxy of 2 to 4 carbon atoms, phenoxy, and oxime; and (C) from about 0.1 to about 100 mole percent, based on the number of moles of polymerized unsaturated organosilane present in the copolymer component (B) of a monomeric hydrolytically reactive organosilane of the formula R".sub.(4-x) SiX x wherein X is a hydrolyzable group as previously defined, R" is a monovalent organic radical of from 1 to 12 carbon atoms and x is a integer having a value of from 1 to 4.
Claim 3
Dependent Claim
40 words
Composition as claimed in claim 1, wherein said monomeric hydrolytically reactive organosilane is present at a concentration of from 5 to 100 mole percent, based on the number of moles of polymerized unsaturated organosilane present in the copolymer component (B).
Claim 4
Dependent Claim
17 words
Composition as claimed in claim 1, wherein said copolymer comprises a copolymer of methyl methacrylate and gamma-methacryloxypropyltrimethoxysilane.
References Cited (Backward Citations)
US3306800A
Cited
US4043953A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-12-31 | 1983-07-02 | 1984-01-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-12-31 | 1987-07-02 | 1988-01-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-12-31 | 1991-07-02 | 1992-01-01 | $7700.00 | Window Closed / Lapsed |