Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
207 words
In a process for dismutation and transalkylation of alkyl aromatic hydrocarbons in the presence of a catalyst, the improvement comprises employing as said catalyst a mordenite containing less than 0.5% by weight of sodium, wherein the molar ration SiO 2 /Al 2 O 3 is in the range from 10 to 100, the mordenite further containing at least one metal selected from cobalt, nickel, silver and palladium, said catalyst having been produced by a process comprising eliminating the major portion of sodium from a mordenite in the sodium form; said mordenite having a molar ratio SiO 2 /Al 2 O 3 of about 10, said catalyst being obtained by incorporating said metal to said mordenite and drying of the resulting catalyst mass at about 50° to 150° C., and subjecting the resultant dried catalyst to a dry calcination between 300 and 700° C., in the presence of an inert or oxidizing dry gas containing less than 1% by volume of steam and then subjecting resultant calcined catalyst to a wet calcination between 250° and 700° C., in the presence of at least one gas selected from steam, an inert gas and an oxidizing gas, the inert or oxidizing gas containing by volume at least 3% of steam.
Claim 2
Dependent Claim
207 words
In a process for dismutation and transalkylation of alkyl aromatic hydrocarbons in the presence of a catalyst, the improvement comprises employing as said catalyst a mordenite containing less than 0.5% by weight of sodium, wherein the molar ration SiO 2 /Al 2 O 3 is in the range from 10 to 100, the mordenite further containing at least one metal selected from cobalt, nickel, silver and palladium, said catalyst having been produced by a process comprising eliminating the major portion of sodium from a mordenite in the sodium form; said mordenite having a molar ratio SiO 2 /Al 2 O 3 of about 10, said catalyst being obtained by incorporating said metal to said mordenite and drying of the resulting catalyst mass at about 50° to 150° C., and subjecting the resultant dried catalyst to a dry calcination between 300 and 700° C., in the presence of an inert or oxidizing dry gas containing less than 1% by volume of steam and then subjecting resultant calcined catalyst to a wet calcination between 250° and 700° C., in the presence of at least one gas selected from steam, an inert gas and an oxidizing gas, the inert or oxidizing gas containing by volume at least 3% of steam.
Claim 3
Dependent Claim
49 words
A process according to claim 1, wherein the metal, selected from cobalt, nickel, silver and palladium, is introduced in the catalyst by direct exchange of the sodium ions of the initial mordenite used for the manufacture of the catalyst, with metal ions selected from cobalt, nickel, silver and palladium.
Claim 4
Dependent Claim
101 words
A process according to claim 1, wherein the metal selected from cobalt, nickel, silver and palladium is introduced in the catalyst by first proceeding to an exchange of the sodium ions of the initial mordenite used for the manufacture of the catalyst, with H + or NH 4 + ions, this exchange being followed either with an exchange of H + or NH 4 + ions with the ions of at least one metal selected from cobalt, nickel, silver and palladium or with an impregnation of the the mordenite with at least one metal selected from cobalt, nickel, silver and palladium.
Claim 5
Dependent Claim
18 words
A process according to claim 1, wherein said dry gas contains less than 0.25% of steam by volume.
Claim 6
Dependent Claim
14 words
A process according to claim 1, wherein the wet calcination is performed with steam.
Claim 7
Dependent Claim
35 words
A process according to claim 1, wherein the wet calcination is performed by means of a mixture of steam with an inert or oxidizing gas, said mixture containing at least 10% by volume of steam.
Claim 8
Dependent Claim
31 words
A process according to claim 1, wherein the wet calcination is performed directly after the so-called "dry" first calcination, without any cooling step between the two dry and wet calcination steps.
Claim 9
Dependent Claim
34 words
A process according to claim 1, wherein the dry calcination in the presence of a dry gas is followed with the cooling of the resulting catalyst mass before proceeding to the wet second calcination.
Claim 10
Dependent Claim
25 words
A process according to claim 1, wherein the wet calcination is conducted between 350° and 600° C., under a pressure from 0.5 to 10 bars.
Claim 11
Dependent Claim
24 words
A process according to claim 1, wherein said at least one metal is nickel and wherein copper is also added as an additional metal.
Claim 12
Dependent Claim
15 words
A process according to claim 1 wherein the wet calcination is conducted at 300°-650° C.