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Process for improving the color yield and fastness properties of dyeings produced with anionic dyes on cellulose fibre material and cationic fibre-reactive compounds

Assignee: BASF Corp
•
Filing: 1977-06-09
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Granted: 1979-12-25
•
Expires: 1997-06-09
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Abstract

Abstract A process for improving the color yield and the wetfastness properties of dyeings produced on cellulose fibre material with anionic dyes, which process comprises treating the cellulose material before, during or after dyeing, with a cationic fibre-reactive compound of the formula ##STR1## wherein B represents a mono- or polynuclear heterocyclic radical, Hal represents a reactive halogen atom, X represents halogen, lower alkoxy, lower alkylthio, phenoxy, phenylthio, ##STR2## or the group of the formula ##STR3## each of W 1 and W 2 independently represents the direct bond, ##STR4## Z represents hydrogen, lower alkyl or hydroxy-lower alkyl, each of Q 1 and Q 2 independently represents an aliphatic or cycloaliphatic radical, each of R 1 , R 2 , V 1 , V 2 , Y 1 and Y 2 independently represents lower alkyl, or lower alkyl or benzyl each of which is substituted by halogen, hydroxy or cyano, or each of the pair of substituents R 1 and R 2 and Y 1 and Y 2 together with the nitrogen atom to which it is attached independently represents a 5- or 6-membered heterocyclic ring, or each of R 1 , R 2 and V 1 and Y 1 , Y 2 and V 2 together with the nitrogen atom to which it is attached independently represents a pyridine ring, or, if W 1 and W 2 are ##STR5## each of Z and V 1 and Z and V 2 together with the group >N--Q 1 --N< or >N--Q 2 --N< independently also represents a divalent heterocyclic radical, An ⊖ represents the anion of an organic or inorganic acid, and n is 1 or 2, with the proviso that an optional aftertreatment of the cellulose material is carried out according to a padding process.

Inventors

  • 👤 Pierre Perrin
  • 👤 Gert Hegar
  • 👤 Gerald Siegrist
  • 👤 Herbert Seiler
  • 👤 Ulrich Horn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:47
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/58; D06P3/60; C; C07; C07D; C07D251/00; C07D251/02; C07D251/12; C07D251/26; C07D251/40; C07D251/42; C07D251/44; C07D251/46; C07D251/48; C07D251/50; C09; C09B; C09B62/00; C09B62/02; D06P1/00; D06P1/44; D06P1/655; D06P1/66; D06P5/00; D06P5/02; D06P5/04; D06P5/06

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 137 words
A cationic compound of the formula ##STR28## wherein Hal is a reactive halogen atom, x is halogen, lower alkoxy, lower alkylthio, phenoxy, phenylthio, ##STR29## or the group of the formula ##STR30## each of W 1 and W 2 independently are the direct bond, ##STR31## Z is hydrogen, lower alkyl or hydroxy-lower alkyl, each of Q 1 and Q 2 independently are an aliphatic or cycloaliphatic radical, selected from the group consisting of alkylene of 2 to 4 carbon atoms and cyclohexylene, each of R 1 , R 2 , V 1 , V 2 , Y 1 and Y 2 independently are lower alkyl or benzyl or lower alkyl or benzyl each of which is substituted by halogen, hydroxyl or cyano, An.sup.⊖ is the anion of an organic or inorganic acid, and n is 1 or 2.
Claim 2
Dependent Claim 137 words
A cationic compound of the formula ##STR28## wherein Hal is a reactive halogen atom, x is halogen, lower alkoxy, lower alkylthio, phenoxy, phenylthio, ##STR29## or the group of the formula ##STR30## each of W 1 and W 2 independently are the direct bond, ##STR31## Z is hydrogen, lower alkyl or hydroxy-lower alkyl, each of Q 1 and Q 2 independently are an aliphatic or cycloaliphatic radical, selected from the group consisting of alkylene of 2 to 4 carbon atoms and cyclohexylene, each of R 1 , R 2 , V 1 , V 2 , Y 1 and Y 2 independently are lower alkyl or benzyl or lower alkyl or benzyl each of which is substituted by halogen, hydroxyl or cyano, An.sup.⊖ is the anion of an organic or inorganic acid, and n is 1 or 2.
Claim 3
Dependent Claim 24 words
A compound according to claim 1 of the formula (1) wherein X represents lower alkoxy, --NH 2 or the group of the formula (1b).
Claim 4
Dependent Claim 21 words
A compound according to claim 1 of the formula (1), wherein each of W 1 and W 2 independently represents ##STR32##
Claim 5
Dependent Claim 10 words
A compound according to claim 3, wherein Z represents hydrogen.
Claim 6
Dependent Claim 29 words
A compound according to claim 1 of the formula (1), wherein each of Q 1 and Q 2 independently represents an alkylene group of 2 to 4 carbon atoms.
Claim 7
Dependent Claim 19 words
A compound according to claim 5 wherein each of Q 1 and Q 2 independently represents ethylene or propylene.
Claim 8
Dependent Claim 17 words
A compound according to claim 35 of the formula (1), wherein Hal represents a reactive fluorine atom.
Claim 9
Dependent Claim 97 words
A compound according to claim 1 of the formula ##STR33## wherein X 1 represents lower alkoxy, --NH 2 or the group of the formula ##STR34## each of Q 3 and Q 4 independently represents alkylene of 2 of 4 carbon atoms, each of Z 2 and Z 3 independently represents hydrogen, methyl or ethyl, each of R 3 , R 4 , Y 3 and Y 4 independently represents lower alkyl, and each of V 3 and V 4 independently represents lower alkyl or benzyl, and Hal, n and An.sup.⊖ have the meaning given in claim 1.
Claim 10
Dependent Claim 61 words
A compound according to claim 8 of the formula ##STR35## wherein Hal 1 represents fluorine or chlorine, X 2 represents lower alkoxy, --NH 2 or the group of the formula ##STR36## Q 4 represents ethylene or propylene, R 5 represents methyl or ethyl, V 5 represents methyl, ethyl or benzyl, and An.sup.⊖ and n have the meanings given in claim 8.
Claim 11
Dependent Claim 21 words
A compound according to claim 9 of the formula (3) wherein X 2 represents lower alkoxy and Hal 1 represents chlorine.
Claim 12
Dependent Claim 10 words
A compound according to claim 10 of the formula ##STR37##
Claim 13
Dependent Claim 10 words
A compound according to claim 9 of the formula ##STR38##
Claim 14
Dependent Claim 10 words
A compound according to claim 9 of the formula ##STR39##
Claim 15
Dependent Claim 10 words
A compound according to claim 10 of the formula ##STR40##
Claim 16
Dependent Claim 10 words
A compound according to claim 9 of the formula ##STR41##

References Cited (Backward Citations)

US2725379A Cited
US3119822A Cited
DE633691C Cited
DE1094699B Cited
GB963811A Cited
GB1017862A Cited
US3310557A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-24 1983-06-25 1983-12-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-24 1987-06-25 1987-12-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-24 1991-06-25 1991-12-25 $7700.00 Window Closed / Lapsed

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