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US4179296A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic emulsion

Assignee: Fujifilm Holdings Corp
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Filing: 1977-12-15
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Granted: 1979-12-18
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Expires: 1997-12-15
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Abstract

Abstract A silver halide photographic emulsion containing, in supersensitizing amounts, a combination of at least one benzimidazolocarbocyanine dye wherein an aralkyl group substituted with an acidic group is connected to at least one nitrogen atom in the imidazole ring, which is represented by the following general formula (I): ##STR1## wherein V 1 , V 2 , V 3 and V 4 , which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluoromethyl group or a hydroxy group; R 1 , R 2 and R 3 , which may be the same or different, each represents an aliphatic group; A represents a sulfo group of a carboxy group; X 1 represents an acid residue; h represents an integer from 1 to 6; and i represents 0 or 1; and at least one cyanine dye represented by the following general formula (II): ##STR2## wherein Z 1 represents the atoms necessary to complete a thiazole ring or a selenazole ring; Z 2 represents the atoms necessary to complete a thiazole ring, a selenazole ring or an oxazole ring; R 4 represents a hydrogen atom, an aliphatic group or an aryl group; R 5 and R 6 , which may be the same or different, each represents an aliphatic group; X 2 represents an acid residue; and l and n each represents 0 or 1; which demonstrates reduced fog, reduced residual color and high sensitivity, and, further, which is endowed with desirable spectral sensitization distribution and minimized deterioration with the lapse of time under high temperature and humidity conditions.

Inventors

  • 👤 Akira Sato
  • 👤 Atsuo Iwamoto
  • 👤 Takeo Sakai
  • 👤 Haruo Takei

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 11:45
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/28; G03C1/29

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 499 words
A silver halide photographic emulsion containing, in supersensitizing amounts, a combination of at least one benzimidazolocarbocyanine dye wherein an aralkyl group substituted with an acidic group is connected to at least one nitrogen atom in the imidazole ring, which is represented by the following general formula (I-B) ##STR15## wherein V 101 , V 102 , V 103 and V 104 , which may be the same or different, each represents a hyrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluoromethyl group or a hydroxy group, with the proviso that at least one of V 101 and V 102 , and V 103 and V 104 , represents simultaneously a chlorine atom; R 1 , R 2 and R 3 , which may be the same or different, each represents an aliphatic group, with the proviso that R 3 can also be a substituted alkyl group; A represents a sulfo group or a carboxy group; X 1 represents an acid residue; h represents an integer from 1 to 6; and i represents 0 or 1; at least one cyanine dye represented by the following general formula (II): ##STR16## wherein Z 1 and Z 2 are selected from one of the following combinations (A)-(E): (A) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessary to complete a benzothiazole or a naphthothiazole nucleus; (B) Z 1 represents the atoms necessary to complete a benzothiazole nucleus, and Z 2 represents the atoms necessary to complete a benzoxazole nucleus; (C) Z 1 represents the atoms necessary to complete a benzothiazole nucleus, and Z 2 represents the atoms necessary to complete a naphthoxazole nucleus; (D) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessaty to complete a benzoxazole nucleus; (E) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessary to complete a naphthoxazole nucleus, wherein a heterocyclic nucleus and/or a benzene nucleus, present in a naphthothiazole or naphthoxaxole group, may be substituted with one or more substituents selected from the group consisting of an alkyl group containing 6 or less carbon atoms, an alkenyl group containing 6 or less carbon atoms, a cycloalkyl group containing 6 or less carbon atoms, an aryl group, which may be mono- or bicyclic, a hydroxy group, an alkoxy group containing 7 or less carbon atoms, an acyl group containing 8 or less carbon atoms, a carboxy group, an alkoxycarbonyl group containing 8 or less carbon atoms, or a halogen atom; R 4 represents a hydrogen atom, an aliphatic group or an aryl group; R 5 and R 6 , which may be the same or different, each represents an aliphatic group; X 2 represents an acid residue; and l represents 1 and n represents 0 or 1.
Claim 2
Dependent Claim 499 words
A silver halide photographic emulsion containing, in supersensitizing amounts, a combination of at least one benzimidazolocarbocyanine dye wherein an aralkyl group substituted with an acidic group is connected to at least one nitrogen atom in the imidazole ring, which is represented by the following general formula (I-B) ##STR15## wherein V 101 , V 102 , V 103 and V 104 , which may be the same or different, each represents a hyrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluoromethyl group or a hydroxy group, with the proviso that at least one of V 101 and V 102 , and V 103 and V 104 , represents simultaneously a chlorine atom; R 1 , R 2 and R 3 , which may be the same or different, each represents an aliphatic group, with the proviso that R 3 can also be a substituted alkyl group; A represents a sulfo group or a carboxy group; X 1 represents an acid residue; h represents an integer from 1 to 6; and i represents 0 or 1; at least one cyanine dye represented by the following general formula (II): ##STR16## wherein Z 1 and Z 2 are selected from one of the following combinations (A)-(E): (A) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessary to complete a benzothiazole or a naphthothiazole nucleus; (B) Z 1 represents the atoms necessary to complete a benzothiazole nucleus, and Z 2 represents the atoms necessary to complete a benzoxazole nucleus; (C) Z 1 represents the atoms necessary to complete a benzothiazole nucleus, and Z 2 represents the atoms necessary to complete a naphthoxazole nucleus; (D) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessaty to complete a benzoxazole nucleus; (E) Z 1 represents the atoms necessary to complete a naphthothiazole nucleus, and Z 2 represents the atoms necessary to complete a naphthoxazole nucleus, wherein a heterocyclic nucleus and/or a benzene nucleus, present in a naphthothiazole or naphthoxaxole group, may be substituted with one or more substituents selected from the group consisting of an alkyl group containing 6 or less carbon atoms, an alkenyl group containing 6 or less carbon atoms, a cycloalkyl group containing 6 or less carbon atoms, an aryl group, which may be mono- or bicyclic, a hydroxy group, an alkoxy group containing 7 or less carbon atoms, an acyl group containing 8 or less carbon atoms, a carboxy group, an alkoxycarbonyl group containing 8 or less carbon atoms, or a halogen atom; R 4 represents a hydrogen atom, an aliphatic group or an aryl group; R 5 and R 6 , which may be the same or different, each represents an aliphatic group; X 2 represents an acid residue; and l represents 1 and n represents 0 or 1.
Claim 3
Dependent Claim 38 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a naphthothiazole nucleus; and Z 2 represents the atoms necessary to complete a benzothiazole nucleus or a naphthothiazole nucleus.
Claim 4
Dependent Claim 34 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a benzothiazole nucleus; and Z 2 represents the atoms necessary to complete a benzoxazole nucleus.
Claim 5
Dependent Claim 34 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a benzothiazole nucleus; and Z 2 represents the atoms necessary to complete a naphthoxazole nucleus.
Claim 6
Dependent Claim 34 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a naphthothiazole nucleus; and Z 2 represents the atoms necessary to complete a benzoxazole nucleus.
Claim 7
Dependent Claim 34 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a naphthothiazole nucleus; and Z 2 represents the atoms necessary to complete a nphthoxazole nucleus.
Claim 8
Dependent Claim 74 words
The silver halide photographic emulsion as described in claim 1, wherein Z 1 represents the atoms necessary to complete a benzothiazole nucleus which is substituted at the 5-position with a halogen atom, an alkoxy group, an alkyl group or a phenyl group and Z 2 represents the atoms necessary to complete a benzoxazole nucleus which is substituted at the 5-position with a halogen atom, an alkoxy group, an alkyl group or a phenyl group.

References Cited (Backward Citations)

US2973264A Cited
US3623883A Cited
US3764340A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-17 1983-06-18 1983-12-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-17 1987-06-18 1987-12-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-17 1991-06-18 1991-12-18 $7700.00 Window Closed / Lapsed

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