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US4178206A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming glass fiber dispersions with cationic quaternary ammonium surfactants having at least two long chain groups

Assignee: Building Materials Corp of America
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Filing: 1978-02-10
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Granted: 1979-12-11
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Expires: 1998-02-10
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Abstract

Abstract In accordance with the present invention, there is provided herein improved glass fiber dispersions for making uniform glass fiber mats by the wet-laid process. The well dispersed glass fiber compositions of this invention usually are prepared by mixing chopped glass fibers in water with a small amount of a select group of cationic quaternary ammonium compounds which have at least two long chain groups as part of the molecule. As features of the invention, the dispersions may be formed at relatively high glass fiber consistencies, in neutral or slightly alkaline solutions, and without generation of a high degree of foams. The resultant dispersions then are used to make very high quality glass fiber mats at high rates of production.

Inventors

  • 👤 Paritosh M. Chakrabarti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:44
CPC Classifications
D; D21; D21H; D21H13/00; D21H13/36; D21H13/38; D21H13/40; C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/25

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 192 words
In the manufacture of uniform glass mats at a high rate of production by the wet-laid process, the improved method which comprises forming an aqueous dispersion of glass fibers by mixing bundles of said fibers of about 1/4 to 3 inches in length in an aqueous medium at a fiber consistency of about 0.001 to 3.0% with about 5-500 ppm of a cationic quaternary ammonium surfactant compound having the formula: ##STR20## where R 1 , R 2 , R 3 and R 4 are selected from the group consisting of aliphatic and aromatic hydrocarbon radicals, straight chain or branched, or two or more form a cyclic group, saturated or unsaturated, substituted or unsubstituted, at least two of said radicals containing at least 10 carbon atoms each, being the same or different, the sum of the carbon atoms in R 1 , R 2 , R 3 and R 4 being at least 22 and less than about 48, and X is an anion thereby to substantially disperse said bundles into individual fibers within the aqueous medium, and, passing said dispersion through a mat-forming screen to form the desired uniform glass fiber mat.
Claim 2
Dependent Claim 192 words
In the manufacture of uniform glass mats at a high rate of production by the wet-laid process, the improved method which comprises forming an aqueous dispersion of glass fibers by mixing bundles of said fibers of about 1/4 to 3 inches in length in an aqueous medium at a fiber consistency of about 0.001 to 3.0% with about 5-500 ppm of a cationic quaternary ammonium surfactant compound having the formula: ##STR20## where R 1 , R 2 , R 3 and R 4 are selected from the group consisting of aliphatic and aromatic hydrocarbon radicals, straight chain or branched, or two or more form a cyclic group, saturated or unsaturated, substituted or unsubstituted, at least two of said radicals containing at least 10 carbon atoms each, being the same or different, the sum of the carbon atoms in R 1 , R 2 , R 3 and R 4 being at least 22 and less than about 48, and X is an anion thereby to substantially disperse said bundles into individual fibers within the aqueous medium, and, passing said dispersion through a mat-forming screen to form the desired uniform glass fiber mat.
Claim 3
Dependent Claim 18 words
A method according to claim 1 wherein said two radicals contain between 12 and 18 carbon atoms each.
Claim 4
Dependent Claim 22 words
A method according to claim 1 wherein R 1 , R 2 , R 3 and R 4 radicals are aliphatic radicals.
Claim 5
Dependent Claim 17 words
A method according to claim 2 wherein at least two of said radicals form a cyclic ring.
Claim 6
Dependent Claim 23 words
A method according to claim 1 wherein said anion is selected from the group consisting of halogen, alkyl sulfate, acetate and formate anion.
Claim 7
Dependent Claim 14 words
A method according to claim 1 wherein two of said radicals are lower alkyl.
Claim 8
Dependent Claim 28 words
A method according to claim 1 wherein said glass fibers are diluted from a more concentrated consistency to a lower consistency before being passed through said mat-forming screen.
Claim 9
Dependent Claim 28 words
A method according to claim 1 wherein said amount of cationic quaternary ammonium compound is about 20-200 ppm, and said fiber consistency is about 0.05 to about 1%.
Claim 10
Dependent Claim 16 words
A method according to claim 1 wherein said compound is di(hydrogenated tallow alkyl) dimethyl ammonium chloride.
Claim 11
Dependent Claim 15 words
A method according to claim 1 wherein said compound is di(soya alkylamine) dimethyl ammonium chloride.
Claim 12
Dependent Claim 16 words
A method according to claim 1 wherein said compound is methyl (1) tallowacylamidoethyl (2) tallowalkylimidazolinium methosulfate.
Claim 13
Dependent Claim 16 words
A method according to claim 1 wherein said compound is ethyl (1) heptadecylamidoethyl (2) steareylimidazolinium ethosulfate.
Claim 14
Dependent Claim 14 words
A method according to claim 1 wherein said compound is di(cocoalkyl) dimethyl ammonium chloride.
Claim 15
Dependent Claim 26 words
A method according to claim 1 wherein said fibers are about 1/2 to 2 inches in length and about 3 to about 20 microns in diameter.
Claim 16
Dependent Claim 28 words
A method according to claim 1 which further comprises: precoating said glass fibers with said compound having the formula of claim 1 prior to forming said aqueous dispersion.
Claim 17
Dependent Claim 19 words
A method according to claim 15 wherein said fibers contain about 0.01 to 1% by weight of the surfactant.
Claim 18
Dependent Claim 19 words
A method according to claim 16 wherein the fibers are coated with between 0.025 to 0.25% of the compound.
Claim 19
Dependent Claim 27 words
A method to claim 1 further including the steps of: drying and curing said mat with a binder to form a finished mat product of high quality.
Claim 20
Dependent Claim 16 words
A method according to claim 1 in which said fibers are about 1 inch in length.
Claim 21
Dependent Claim 16 words
A method according to claim 1 in which said fibers are about 15 microns in diameter.

References Cited (Backward Citations)

US3228825A Cited
US3573158A Cited
US3554863A Cited
US3766003A Cited
BE838373A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-12-10 1983-06-11 1983-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-12-10 1987-06-11 1987-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-12-10 1991-06-11 1991-12-11 $7700.00 Window Closed / Lapsed

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