Patent US4176113A successfully refreshed from Google Patents.
US4176113A
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Process for dyeing polyesters in the melt
Assignee: BASF Corp
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Filing: 1977-10-21
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Granted: 1979-11-27
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Expires: 1997-10-21
Abstract
Abstract Use of anthraquinone derivatives of the formula ##STR1## wherein X is --NH-- or --S--, one Y is --NHCOR, R being an alkyl, aryl or heterocyclic residue, the other Y are hydrogen, Z is halogen, and n is 0, 1, 2 or 3, whereby Z may be 1 to 3 halogen bound to aryl and/or anthraquinone nucleus and/or the residue R, for dyeing polyesters in the melt.
Inventors
- 👤 Arnold Wick
- 👤 Max Jost
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 22:04
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/20; C08K5/0008; C08K5/0041; C09; C09B; C09B1/00; C09B1/16; C09B1/20; C09B1/36; C09B1/56; C09B1/58; C09B1/585
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
197 words
A process for dyeing polyesters in the melt, by intimately mixing with said polyester in the melt, an anthraquinone derivative of the formula ##STR14## wherein R 1 is hydrogen, halogen, alkyl or alkoxy having 1-4 C atoms, and R 2 and R 3 are hydrogen, halogen or alkyl having 1-4 C atoms, with R 2 and R 3 being hydrogen if R 1 is alkoxy, X is an --NH-- group or an --S-- atom, one Y is the radical of the formula --NHCOR and the other two Y groups are hydrogen, with R being alkyl having 1-4 C atoms, a mononuclear five- or six-membered heterocyclic radical or a radical of the formula ##STR15## in which R 4 is hydrogen, halogen, hydroxyl, alkyl or alkoxy having 1-4 C atoms, phenyl or phenoxy, R 5 is hydrogen, halogen or alkyl having 1-4 C atoms and R 6 is hydrogen or halogen, with R 6 being halogen if R 4 is halogen or alkyl, Z is halogen and n is O, 1, 2 or 3, and 1-3 Z's can be bound as substituents R 1 to R 3 and/or as substituents on the anthraquinone nucleus or on the radical R.
Claim 2
Dependent Claim
197 words
A process for dyeing polyesters in the melt, by intimately mixing with said polyester in the melt, an anthraquinone derivative of the formula ##STR14## wherein R 1 is hydrogen, halogen, alkyl or alkoxy having 1-4 C atoms, and R 2 and R 3 are hydrogen, halogen or alkyl having 1-4 C atoms, with R 2 and R 3 being hydrogen if R 1 is alkoxy, X is an --NH-- group or an --S-- atom, one Y is the radical of the formula --NHCOR and the other two Y groups are hydrogen, with R being alkyl having 1-4 C atoms, a mononuclear five- or six-membered heterocyclic radical or a radical of the formula ##STR15## in which R 4 is hydrogen, halogen, hydroxyl, alkyl or alkoxy having 1-4 C atoms, phenyl or phenoxy, R 5 is hydrogen, halogen or alkyl having 1-4 C atoms and R 6 is hydrogen or halogen, with R 6 being halogen if R 4 is halogen or alkyl, Z is halogen and n is O, 1, 2 or 3, and 1-3 Z's can be bound as substituents R 1 to R 3 and/or as substituents on the anthraquinone nucleus or on the radical R.
Claim 3
Dependent Claim
11 words
Process according to claim 1, wherein halogen denotes chlorine or bromine.
Claim 4
Dependent Claim
83 words
Process according to claim 1, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR16## wherein n is 0, 1 or 2 if halogen is on the anthraquinone nucleus or as radical R 1 to R 3 in the molecule, and X is an --NH-- group or an --S-- atom, one Y is a radical of the formula --NHCOR and the other Y is hydrogen, and R, R 1 , R 2 and R 3 have the meanings given in claim 1.
Claim 5
Dependent Claim
67 words
Process according to claim 1, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR17## wherein n is a number from 1 to 3, X is an --NH-- group or an --S-- atom, one Y is a radical of the formula --NHCOR and the other Y is hydrogen, and Z, R, R 1 , R 2 and R 3 have the meanings given in claim 1.
Claim 6
Dependent Claim
22 words
Process according to claim 4, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR18## wherein AlK1 is methyl or ethyl.
Claim 7
Dependent Claim
33 words
Process according to claim 4, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR19## wherein R 1 , R 4 , Z and n have the meanings given in claim 1.
Claim 8
Dependent Claim
16 words
Process according to claim 4, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR20##
Claim 9
Dependent Claim
62 words
Process according to claim 1, wherein the dyestuffs used are anthraquinone derivatives of the formula ##STR21## wherein R 7 and R 8 are hydrogen or methyl or ethyl groups, and R 9 is a methyl group, or a phenyl group optionally substituted by chlorine or by a methyl or ethyl group, and Z and n have the meanings given in claim 1.
Claim 10
Dependent Claim
10 words
A product prepared by the process according to claim 1.
References Cited (Backward Citations)
GB1000887A
Cited
US3720693A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-26 | 1983-05-28 | 1983-11-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-26 | 1987-05-28 | 1987-11-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-26 | 1991-05-28 | 1991-11-27 | $7700.00 | Window Closed / Lapsed |