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US4175926A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer combination useful in fuel oil to improve cold flow properties

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1978-01-16
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Granted: 1979-11-27
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Expires: 1998-01-16
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Abstract

Abstract Ethylene polymers or copolymers, which are pour depressants for middle distillate fuel, in combination with a second polymer having alkyl groups of 6 to 18 carbon atoms, and derived from either dicarboxylic acid esters or olefins, are useful in improving the cold flow properties of middle distillate fuel oils wherein a portion, e.g., 5 wt. % or more, of the fuel boils above 700 DEG F.

Inventors

  • 👤 Max J. Wisotsky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 08:20
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/18; C10L1/192; C10L1/195; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/165; C10L1/196; C10L1/1963; C10L1/1966; C10L1/197; C10L1/1973

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 327 words
A fuel composition comprising a fuel consisting of wax-containing middle distillate pertroleum light fuel oil boiling in the range of 250° to 900° F., having a viscosity of 1.6 to 7.5 centistokes at 100° F., having less than 1 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C., and of which at least 5 wt. % of said oil boils above 700° F. according to ASTM-D-1160, which oil has been improved in its low temperature flow properties, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of one part by weight of an oil soluble ethylene backbone middle distillate pour point depressing polymer having a number average molecular weight in the range of about 1000 to 6000 per (b) 0.2 to 4 parts by weight of a second oil soluble polymer having a number average molecular weight in the range of about 1000 to 100,000; wherein said ethylene backbone polymer is selected from the group consisting of branched polyethylene, and copolymers consisting essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester of the formula: ##STR4## wherein R 1 is hydrogen or methyl; R 2 is a --OOCR 4 or --COOR 4 group wherein R 4 is a C 1 to C 4 alkyl group, and R 3 is hydrogen, and mixtures of said comonomers, and wherein said second polymer is a polymer selected from the group consisting of: (a) ester copolymers consisting of dialkyl fumarate copolymerized with 5 to 70 mole % of a comonomer selected from the group consisting of vinyl acetate and alkyl methacrylate, wherein said alkyl groups of said fumarate and said methacrylate consist essentially of C 6 to C 16 straight chain alkyl groups; and (b) polymers consisting essentially of C 8 to C 18 alpha monoolefin moieties.
Claim 2
Dependent Claim 327 words
A fuel composition comprising a fuel consisting of wax-containing middle distillate pertroleum light fuel oil boiling in the range of 250° to 900° F., having a viscosity of 1.6 to 7.5 centistokes at 100° F., having less than 1 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C., and of which at least 5 wt. % of said oil boils above 700° F. according to ASTM-D-1160, which oil has been improved in its low temperature flow properties, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of one part by weight of an oil soluble ethylene backbone middle distillate pour point depressing polymer having a number average molecular weight in the range of about 1000 to 6000 per (b) 0.2 to 4 parts by weight of a second oil soluble polymer having a number average molecular weight in the range of about 1000 to 100,000; wherein said ethylene backbone polymer is selected from the group consisting of branched polyethylene, and copolymers consisting essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester of the formula: ##STR4## wherein R 1 is hydrogen or methyl; R 2 is a --OOCR 4 or --COOR 4 group wherein R 4 is a C 1 to C 4 alkyl group, and R 3 is hydrogen, and mixtures of said comonomers, and wherein said second polymer is a polymer selected from the group consisting of: (a) ester copolymers consisting of dialkyl fumarate copolymerized with 5 to 70 mole % of a comonomer selected from the group consisting of vinyl acetate and alkyl methacrylate, wherein said alkyl groups of said fumarate and said methacrylate consist essentially of C 6 to C 16 straight chain alkyl groups; and (b) polymers consisting essentially of C 8 to C 18 alpha monoolefin moieties.
Claim 3
Dependent Claim 33 words
A fuel composition according to claim 1, wherein said ethylene backbone polymer is a copolymer of ethylene and a vinyl alcohol ester of a C 1 to C 4 saturated aliphatic monocarboxylic acid.
Claim 4
Dependent Claim 15 words
A fuel composition according to claim 1, wherein said ethylene backbone polymer is said polyethylene.
Claim 5
Dependent Claim 20 words
A fuel composition according to claim 1, wherein said second polymer is said copolymer of dialkyl fumarate and vinyl acetate.
Claim 6
Dependent Claim 28 words
A fuel composition according to claim 1, wherein said second polymer is a copolymer of C 8 , C 10 , C 14 and C 16 alpha monoolefins.
Claim 7
Dependent Claim 38 words
A fuel composition according to claim 1, wherein said second polymer is a copolymer of dialkyl fumarate and an alkyl methacrylate wherein said alkyl groups of said fumarate and said methacrylate contain about 12 to 16 carbon atoms.
Claim 8
Dependent Claim 49 words
A fuel composition according to claim 1, wherein said fuel has a viscosity of about 2 to 3 centistokes at 100° F. and said ethylene backbone polymer is a copolymer of ethylene and vinyl acetate having a number average molecular weight in the range of about 1000 to 6000.
Claim 9
Dependent Claim 21 words
A fuel composition according to claim 7, wherein said second polymer is a copolymer of a dialkyl fumarate and vinyl acetate.
Claim 10
Dependent Claim 29 words
A fuel composition according to claim 7, wherein said second polymer is a copolymer of C 8 , C 10 , C 14 , and C 16 alpha monoolefins.
Claim 11
Dependent Claim 40 words
A fuel composition according to claim 7, wherein said second polymer is a copolymer of a dialkyl fumarate and an alkyl methacrylate, and wherein said alkyl groups of said fumarate and said methacrylate contain about 12 to 16 carbon atoms.

References Cited (Backward Citations)

US4010006A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-26 1983-05-28 1983-11-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-26 1987-05-28 1987-11-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-26 1991-05-28 1991-11-27 $7700.00 Window Closed / Lapsed

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