US4174374A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Maintaining the separation efficiency of immobilized liquid membranes in gas separation methods and apparatus
Assignee: General Electric Co
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Filing: 1978-08-16
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Granted: 1979-11-13
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Expires: 1998-08-16
Abstract
Abstract Disclosed are an improved method and apparatus employing at least one immobilized liquid membrane separated from a liquid sweep by a gas-permeable barrier for removing a gaseous component from a gaseous mixture. The improvements include use of one or more liquid-filled passages extending through the gas-permeable barrier to effect diffusive transfer of active carrier species from the liquid sweep into the membrane, thereby maintaining the separation efficiency of each membrane. In a preferred embodiment, the improvements are applied to removal of hydrogen sulfide from mixtures thereof with carbon dioxide as found in gasified coal.
Inventors
- 👤 Stephen L. Matson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 04:32
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22; B01D53/229; B01D53/228; B01D61/00; B01D61/38
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
150 words
In a method for removing a gaseous component from a gaseous mixture comprising: contacting said mixture with an immobilized liquid membrane containing in the liquid thereof at least one carrier species which is reversibly chemically reactive with said component to effect facilitated transport of said component through said membrane to a gas-permeable barrier which is substantially impervious to said liquid; passing the gases emerging from said membrane through said gas-permeable barrier; and absorbing in a sweep liquid the gases emerging from said gas-permeable barrier; the improvement for substantially maintaining the separation efficiency of said membrane; comprising: said sweep liquid containing a quantity of said carrier species; and said sweep liquid being contacted with said immobilized liquid membrane through a discrete passage extending transversely through said barrier, to effect diffusive transfer of at least a portion of said reactive species from said sweep liquid into the liquid immobilized in said membrane.
Claim 2
Dependent Claim
150 words
In a method for removing a gaseous component from a gaseous mixture comprising: contacting said mixture with an immobilized liquid membrane containing in the liquid thereof at least one carrier species which is reversibly chemically reactive with said component to effect facilitated transport of said component through said membrane to a gas-permeable barrier which is substantially impervious to said liquid; passing the gases emerging from said membrane through said gas-permeable barrier; and absorbing in a sweep liquid the gases emerging from said gas-permeable barrier; the improvement for substantially maintaining the separation efficiency of said membrane; comprising: said sweep liquid containing a quantity of said carrier species; and said sweep liquid being contacted with said immobilized liquid membrane through a discrete passage extending transversely through said barrier, to effect diffusive transfer of at least a portion of said reactive species from said sweep liquid into the liquid immobilized in said membrane.
Claim 3
Dependent Claim
16 words
The improvement of claim 1, wherein said barrier is microporous and substantially non-wettable by said liquid.
Claim 4
Dependent Claim
29 words
The improvement of claim 1, wherein said gaseous component is hydrogen sulfide and said immobilized liquid is an aqueous solution containing carbonate and bicarbonate ions as the carrier species.
Claim 5
Dependent Claim
33 words
The improvement of claim 1, wherein said sweep liquid is continually passed along and in contact with the barrier surface from which the gases emerge to continually maintain separation efficiency of said membrane.
Claim 6
Dependent Claim
248 words
In a method of removing a gaseous component from a gaseous mixture, comprising: contacting said mixture with a first immobilized liquid membrane containing in the liquid at least one reactive species which is reversibly chemically reactive with said gaseous component to effect facilitated transport of said component through said first membrane to a first gas-permeable barrier which is substantially impervious to said liquid; passing the gases emerging from said first membrane through said first gas-permeable barrier; and contacting gases emerging from said first gas-permeable barrier with a second immobilized liquid membrane containing in the liquid thereof a quantity of said reactive species to effect facilitated transport of said gaseous component through said second membrane; the improvement for substantially maintaining separation efficiency of said membranes, comprising: (a) passing gases emerging from said second membrane through a second gas-permeable barrier, (b) absorbing in a sweep liquid the gases emerging from said second gas-permeable barrier, (c) each of said barriers having at least one discrete passage extending transversely therethrough, (d) said sweep liquid containing an amount of said reactive species, and (e) said sweep liquid being contacted with said second membrane through the passage in said second barrier and being in diffusional flow communication with the liquid in said first membrane through the passage in said first barrier to effect transfer of at least a portion of said reactive species from said sweep liquid into both the immobilized liquid in said first membrane and the immobilized liquid in said second membrane.
Claim 7
Dependent Claim
248 words
In a method of removing a gaseous component from a gaseous mixture, comprising: contacting said mixture with a first immobilized liquid membrane containing in the liquid at least one reactive species which is reversibly chemically reactive with said gaseous component to effect facilitated transport of said component through said first membrane to a first gas-permeable barrier which is substantially impervious to said liquid; passing the gases emerging from said first membrane through said first gas-permeable barrier; and contacting gases emerging from said first gas-permeable barrier with a second immobilized liquid membrane containing in the liquid thereof a quantity of said reactive species to effect facilitated transport of said gaseous component through said second membrane; the improvement for substantially maintaining separation efficiency of said membranes, comprising: (a) passing gases emerging from said second membrane through a second gas-permeable barrier, (b) absorbing in a sweep liquid the gases emerging from said second gas-permeable barrier, (c) each of said barriers having at least one discrete passage extending transversely therethrough, (d) said sweep liquid containing an amount of said reactive species, and (e) said sweep liquid being contacted with said second membrane through the passage in said second barrier and being in diffusional flow communication with the liquid in said first membrane through the passage in said first barrier to effect transfer of at least a portion of said reactive species from said sweep liquid into both the immobilized liquid in said first membrane and the immobilized liquid in said second membrane.
Claim 8
Dependent Claim
34 words
The improvement of claim 5, wherein said gaseous component is hydrogen sulfide and the immobilized liquid in each of said membranes is an aqueous solution containing carbonate and bicarbonate ions as the carrier species.
Claim 9
Dependent Claim
28 words
The improvement of claim 5, wherein said sweep liquid is continually passed along and in contact with the surface of said second barrier from which the gases emerge.
Claim 10
Dependent Claim
24 words
The improvement of claim 5, wherein the pressure of the sweep liquid is at least slightly higher than the pressure of the gaseous mixture.
Claim 11
Dependent Claim
18 words
The improvement of claim 5, wherein each of said barriers is microporous and substantially non-wettable by said liquid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-12 | 1983-05-14 | 1983-11-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-12 | 1987-05-14 | 1987-11-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-12 | 1991-05-14 | 1991-11-13 | $7700.00 | Window Closed / Lapsed |