US4172858A
Expired / Lapsed
US
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Flame-resistant polymer compositions
Assignee: FMC Corp
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Filing: 1977-03-04
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Granted: 1979-10-30
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Expires: 1997-03-04
Abstract
Abstract Flameproofing of aromatic polymers is achieved by adding a synergistic combination of (a) a phosphorus compound and (b) a compound of formula R(CH 2 X) n , wherein R is an aromatic or heterocyclic residue, X is a leaving group and n is at least 2. Preferred phosphorus compounds are esters of phosphoric acid. The flameproofed polymers may contain aromatic groups in the main chain or as side-groups, for instance styrene polymers and copolymers, aromatic polyesters, polycarbonates and polyphenylene oxides.
Inventors
- 👤 Brian G. Clubley
- 👤 Boyce I. D. Davis
- 👤 Thomas G. Hyde
- 👤 Frank Lamb
- 👤 Donald R. Randell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 12:15
CPC Classifications
C; C08; C08L; C08L101/00; C08L101/02; C08K; C08K5/00; C08K5/0008; C08K5/0066
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
290 words
A composition which comprises a polymer selected from the group consisting of (1) a homopolymer or copolymer of styrene or α-methyl styrene, (2) a blend of (1) with polyphenylene oxide, polysulfone, vinyl chloride resin or polycarbonate, (3) a styrene cured unsaturated polyester resin, and (4) a polymer containing an aromatic group in the polymer chain and selected from the group consisting of polycarbonates, polyphenylene ethers, polysulfides, polyurethanes, polyhydrazides, linear polyesters, polysulfones, polyamides,polyimides, polybenzimidazoles and polyanhydrides, and a flame-retarding combination of (a) a phosphorus compound selected from the group consisting of a phosphine oxide, a phosphorus oxy acid, a salt of a phosphorus oxy acid and an ester of a phosphorus oxy acid, and (b) a compound of the formula (A).sub.a (--CH.sub.2 --).sub.b [--CH.sub.2 (OCH.sub.2).sub.m OCH.sub.2 --].sub.c (--CH.sub.2 OH).sub.d wherein A is an unsubstituted aromatic hydrocarbon, an aromatic hydrocarbon substituted by up to two substituents selected from the group of halogen, alkyl with 1 to 4 cabon atoms, haloalkyl with 2 to 4 carbon atoms, hydroxyl, alkoxy with 1 to 4 carbon atoms or acyloxy with 2 to 4 carbon atoms, or diphenyl ether radical, a is 2 to 20 and is equal to b+c+1, b is 0 to 19, c is 0 to 19, d is 0 to 2a, and m is 0 to 10, there being present per molecule (a) at least two of the groups (CH 2 OH), (b) at least two of the groups (--CH 2 OCH 2 --) or (c) at least one group (CH 2 OH) and one group (--CH 2 OCH 2 --) and wherein the groups (--CH 2 --), [--CH 2 (OCH 2 ) m OCH 2 --] and (--CH 2 OH) are all directly attached to the nucleus of radicals A only.
Claim 2
Dependent Claim
290 words
A composition which comprises a polymer selected from the group consisting of (1) a homopolymer or copolymer of styrene or α-methyl styrene, (2) a blend of (1) with polyphenylene oxide, polysulfone, vinyl chloride resin or polycarbonate, (3) a styrene cured unsaturated polyester resin, and (4) a polymer containing an aromatic group in the polymer chain and selected from the group consisting of polycarbonates, polyphenylene ethers, polysulfides, polyurethanes, polyhydrazides, linear polyesters, polysulfones, polyamides,polyimides, polybenzimidazoles and polyanhydrides, and a flame-retarding combination of (a) a phosphorus compound selected from the group consisting of a phosphine oxide, a phosphorus oxy acid, a salt of a phosphorus oxy acid and an ester of a phosphorus oxy acid, and (b) a compound of the formula (A).sub.a (--CH.sub.2 --).sub.b [--CH.sub.2 (OCH.sub.2).sub.m OCH.sub.2 --].sub.c (--CH.sub.2 OH).sub.d wherein A is an unsubstituted aromatic hydrocarbon, an aromatic hydrocarbon substituted by up to two substituents selected from the group of halogen, alkyl with 1 to 4 cabon atoms, haloalkyl with 2 to 4 carbon atoms, hydroxyl, alkoxy with 1 to 4 carbon atoms or acyloxy with 2 to 4 carbon atoms, or diphenyl ether radical, a is 2 to 20 and is equal to b+c+1, b is 0 to 19, c is 0 to 19, d is 0 to 2a, and m is 0 to 10, there being present per molecule (a) at least two of the groups (CH 2 OH), (b) at least two of the groups (--CH 2 OCH 2 --) or (c) at least one group (CH 2 OH) and one group (--CH 2 OCH 2 --) and wherein the groups (--CH 2 --), [--CH 2 (OCH 2 ) m OCH 2 --] and (--CH 2 OH) are all directly attached to the nucleus of radicals A only.
Claim 3
Dependent Claim
17 words
A composition according to claim 1 wherein component (a) is an ester of a phosphorus oxy acid.
Claim 4
Dependent Claim
28 words
A composition according to claim 1 wherein the amount of component (a) plus component (b) is from 1 to 100 parts by weight per 100 parts of polymer.
Claim 5
Dependent Claim
28 words
A composition according to claim 3 wherein the amount of component (a) plus component (b) is from 2 to 35 parts by weight per 100 parts of polymer.
Claim 6
Dependent Claim
22 words
A composition according to claim 1 wherein the ratio of component (a) to component (b) is from 1:10 to 10:1 by weight.
Claim 7
Dependent Claim
14 words
A composition according to claim 5 wherein the ratio is from 1:1 to 8:1.
Claim 8
Dependent Claim
16 words
A composition according to claim 5 wherein the ratio is from 2:1 to 4:1 by weight.
Claim 9
Dependent Claim
19 words
A composition according to claim 1 wherein the polymer is a homopolymer or copolymer of styrene or α-methyl styrene.
Claim 10
Dependent Claim
18 words
A composition according to claim 1 wherein the polymer is a copolymer of styrene with butadiene or butadiene/acrylonitrile.
Claim 11
Dependent Claim
18 words
A composition according to claim 1 wherein the polymer is a copolymer of styrene and an unsaturated polyester.
Claim 12
Dependent Claim
26 words
A composition according to claim 1 wherein the component (a) is an ester derived from phosphoric acid, phosphorus acid, a phosphonic acid, or a phosphinic acid.
Claim 13
Dependent Claim
18 words
A composition according to claim 11 wherein component (a) is an ester of an acid containing pentavalent phosphorus.
Claim 14
Dependent Claim
16 words
A composition according to claim 11 wherein the ester is a triaryl phosphate or tri-haloalkyl phosphate.
Claim 15
Dependent Claim
13 words
A composition according to claim 1 wherein component (a) is a phosphine oxide.
Claim 16
Dependent Claim
14 words
A composition according to claim 14 wherein component (a) is a triaryl phosphone oxide.
Claim 17
Dependent Claim
16 words
A composition according to claim 1 wherein component (a) is a salt of a phosphorus acid.
Claim 18
Dependent Claim
28 words
A composition according to claim 16 wherein component (a) is an alkali metal, ammonium or amine salt of phosphoric acid, phosphorus acid, a phosphonic or a phosphonic acid.
Claim 19
Dependent Claim
10 words
A composition according to claim 1 wherein m is 0.
Claim 20
Dependent Claim
18 words
A composition according to claim 1 wherein A is a benzene, naphthalene, anthracene, biphenyl or diphenyl ether radical.
Claim 21
Dependent Claim
49 words
A composition according to claim 1 wherein A is unsubstituted or is substituted by one of the substituents halogen, alkyl with 1 to 4 carbon atoms, haloalkyl with 2 to 4 carbon atoms, hydroxyl, alkoxy with 1 to 4 carbon atoms or acyloxy with 2 to 4 carbon atoms.
Claim 22
Dependent Claim
19 words
A composition according to claim 1 wherein more than 50 mol % of residue A are derived from naphthalene.
Claim 23
Dependent Claim
19 words
A composition according to claim 21 wherein more than 75 mol % of radicals A are derived from napthalene.
Claim 24
Dependent Claim
21 words
A composition according to claim 1 wherein the oligomer (b) has a number average molecular weight of from 300 to 3500.
Claim 25
Dependent Claim
16 words
A composition according to claim 23 wherein the average molecular weight is from 350 to 1500.
Claim 26
Dependent Claim
16 words
A composition according to claim 24 wherein the average molecular weight is from 400 to 1000.
Claim 27
Dependent Claim
38 words
A composition according to claim 1 wherein A is derived from naphthalene, the radicals being linked by (--CH 2 OCH 2 --) groups in the positions 1,4; 1,5; 1,6; 1,7; 2,5; 2,6 or 2,7 on the naphthalene radical.
Claim 28
Dependent Claim
21 words
A composition according to claim 26 wherein the radicals are linked in the 1,4 or 1,5 positions on the naphthalene radical.
Claim 29
Dependent Claim
35 words
A composition according to claim 1 additionally containing a heat stabilizer, light stabilizer, UV absorber, antioxidant, filler, pigment, lubricant, blowing agent, fungicide, additive to improve mould release, optical brightening agent or other fire retardant additive.
Claim 30
Dependent Claim
16 words
A composition according to claim 1 wherein component (b) is a compound of the formula ##STR64##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-10-29 | 1983-04-30 | 1983-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-10-29 | 1987-04-30 | 1987-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-10-29 | 1991-04-30 | 1991-10-30 | $7700.00 | Window Closed / Lapsed |