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Process for the separation of Cu++ -ions from sewage, waste water and aqueous solutions

Assignee: Evonik Operations GmbH
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Filing: 1977-09-19
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Granted: 1979-10-30
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Expires: 1997-09-19
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Abstract

Abstract Copper (Cu ++ )-ions are separated from an effluent containing complexing agents which are ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anionic salts, by using an HS-containing triazine compound and Fe +++ -ions in a quantity at least equal to the amount of complexing agent.

Inventors

  • 👤 Helmut Knorre
  • 👤 Gerhard Pohl
  • 👤 Klaus Stutzel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 15:39
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/52; C02F1/5272; C01; C01G; C01G3/00; C01G49/00; C01G49/02; C01G49/06; C02F1/72; C02F1/722; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/911; Y10S210/912

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 191 words
A process for the separation of Cu ++ -ions from an aqueous liquid in which said Cu ++ ions exist as complexes of ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anions, comprising contacting said liquid with an HS-containing triazine compound of the general formula ##STR4## in which: R is hydrogen, the same or different alkyl with 1 to 3 carbons, --NR 1 R 2 or --OR 3 ; R 1 , r 2 and R 3 are hydrogen, the same or different alkyl with 1 to 6 carbons or phenyl; n is a whole number from 0 to 2, or of a water soluble salt to precipitate said Cu ++ ions, and wherein said compound is contacted in an amount such that at least one equivalent of mercapto or mercaptide groups is present per equivalent of said Cu ++ ions and the precipitation of the Cu ++ -ions takes place in the presence of an at least equivalent quantity of Fe +++ -ions, related to the complexing agent content in the liquid, and at a pH value between 4 and 10, and separating the precipitate from the aqueous liquid.
Claim 2
Dependent Claim 191 words
A process for the separation of Cu ++ -ions from an aqueous liquid in which said Cu ++ ions exist as complexes of ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anions, comprising contacting said liquid with an HS-containing triazine compound of the general formula ##STR4## in which: R is hydrogen, the same or different alkyl with 1 to 3 carbons, --NR 1 R 2 or --OR 3 ; R 1 , r 2 and R 3 are hydrogen, the same or different alkyl with 1 to 6 carbons or phenyl; n is a whole number from 0 to 2, or of a water soluble salt to precipitate said Cu ++ ions, and wherein said compound is contacted in an amount such that at least one equivalent of mercapto or mercaptide groups is present per equivalent of said Cu ++ ions and the precipitation of the Cu ++ -ions takes place in the presence of an at least equivalent quantity of Fe +++ -ions, related to the complexing agent content in the liquid, and at a pH value between 4 and 10, and separating the precipitate from the aqueous liquid.
Claim 3
Dependent Claim 42 words
A process as in claim 1 wherein the precipitation of Cu ++ -ions takes place in the presence of a molar excess of Fe +++ -ions in the amount of 10 to 200%, related to the complexing agent content in the liquid.
Claim 4
Dependent Claim 42 words
A process as in claim 1 wherein the precipitation of Cu +++ -ions takes place in the presence of a molar excess of Fe +++ -ions in the amount of 50 to 100%, related to the complexing agent content in the liquid.
Claim 5
Dependent Claim 30 words
A process as in claim 1 wherein the concentration of Fe +++ -ions in the solution is arrived at by potentiometric indicated addition of an aqueous Fe +++ -salt solution.
Claim 6
Dependent Claim 58 words
A process as in claim 1 wherein filtration is used to separate the precipitate and subsequent to the precipitation and separation of the Cu ++ -ions, hydrogen peroxide is added to the filtrate containing a Fe +++ -ion complex at pH values above 7 and thereby precipitation the Fe +++ -ions and separating barely soluble Fe(OH) 3 .

References Cited (Backward Citations)

DE2240549A1 Cited
US3778368A Cited
US3816306A Cited
US3931007A Cited
JPS5110176A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-29 1983-04-30 1983-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-29 1987-04-30 1987-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-29 1991-04-30 1991-10-30 $7700.00 Window Closed / Lapsed

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