US4172785A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the separation of Cu++ -ions from sewage, waste water and aqueous solutions
Assignee: Evonik Operations GmbH
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Filing: 1977-09-19
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Granted: 1979-10-30
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Expires: 1997-09-19
Abstract
Abstract Copper (Cu ++ )-ions are separated from an effluent containing complexing agents which are ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anionic salts, by using an HS-containing triazine compound and Fe +++ -ions in a quantity at least equal to the amount of complexing agent.
Inventors
- 👤 Helmut Knorre
- 👤 Gerhard Pohl
- 👤 Klaus Stutzel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 01:06
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/52; C02F1/5272; C01; C01G; C01G3/00; C01G49/00; C01G49/02; C01G49/06; C02F1/72; C02F1/722; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/911; Y10S210/912
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
191 words
A process for the separation of Cu ++ -ions from an aqueous liquid in which said Cu ++ ions exist as complexes of ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anions, comprising contacting said liquid with an HS-containing triazine compound of the general formula ##STR4## in which: R is hydrogen, the same or different alkyl with 1 to 3 carbons, --NR 1 R 2 or --OR 3 ; R 1 , r 2 and R 3 are hydrogen, the same or different alkyl with 1 to 6 carbons or phenyl; n is a whole number from 0 to 2, or of a water soluble salt to precipitate said Cu ++ ions, and wherein said compound is contacted in an amount such that at least one equivalent of mercapto or mercaptide groups is present per equivalent of said Cu ++ ions and the precipitation of the Cu ++ -ions takes place in the presence of an at least equivalent quantity of Fe +++ -ions, related to the complexing agent content in the liquid, and at a pH value between 4 and 10, and separating the precipitate from the aqueous liquid.
Claim 2
Dependent Claim
191 words
A process for the separation of Cu ++ -ions from an aqueous liquid in which said Cu ++ ions exist as complexes of ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anions, comprising contacting said liquid with an HS-containing triazine compound of the general formula ##STR4## in which: R is hydrogen, the same or different alkyl with 1 to 3 carbons, --NR 1 R 2 or --OR 3 ; R 1 , r 2 and R 3 are hydrogen, the same or different alkyl with 1 to 6 carbons or phenyl; n is a whole number from 0 to 2, or of a water soluble salt to precipitate said Cu ++ ions, and wherein said compound is contacted in an amount such that at least one equivalent of mercapto or mercaptide groups is present per equivalent of said Cu ++ ions and the precipitation of the Cu ++ -ions takes place in the presence of an at least equivalent quantity of Fe +++ -ions, related to the complexing agent content in the liquid, and at a pH value between 4 and 10, and separating the precipitate from the aqueous liquid.
Claim 3
Dependent Claim
42 words
A process as in claim 1 wherein the precipitation of Cu ++ -ions takes place in the presence of a molar excess of Fe +++ -ions in the amount of 10 to 200%, related to the complexing agent content in the liquid.
Claim 4
Dependent Claim
42 words
A process as in claim 1 wherein the precipitation of Cu +++ -ions takes place in the presence of a molar excess of Fe +++ -ions in the amount of 50 to 100%, related to the complexing agent content in the liquid.
Claim 5
Dependent Claim
30 words
A process as in claim 1 wherein the concentration of Fe +++ -ions in the solution is arrived at by potentiometric indicated addition of an aqueous Fe +++ -salt solution.
Claim 6
Dependent Claim
58 words
A process as in claim 1 wherein filtration is used to separate the precipitate and subsequent to the precipitation and separation of the Cu ++ -ions, hydrogen peroxide is added to the filtrate containing a Fe +++ -ion complex at pH values above 7 and thereby precipitation the Fe +++ -ions and separating barely soluble Fe(OH) 3 .
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-10-29 | 1983-04-30 | 1983-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-10-29 | 1987-04-30 | 1987-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-10-29 | 1991-04-30 | 1991-10-30 | $7700.00 | Window Closed / Lapsed |