Abstract The invention relates to the reaction of cyclopentadienyl-transition metal compounds, (C 5 H 5 ) 2 M or C 5 H 5 --M(L) n (M=transition metal, L=olefin), with alkali metal in the presence of olefins, with detachment of the C 5 H 5 rings from the transition metal atom to form alkali metal cyclopentadienide, leads, to transition metal-olefin complex compounds free of alkali metal or also containing alkali metal, in yields of greater than 65%, the latter compounds being able to contain one or even several alkali metal atoms per transition metal atom. It is moreover possible, depending on the selection of the stoichiometry or of the reaction compounds, and depending on the nature of the transition metal, to detach only one or also both cyclopentadienyl rings from the transition metal atom, so that by this method the most various transition metal-olefin complex compounds can be prepared, namely transition metal-olefin complex compounds containing C 5 H 5 or alkali metal-transition metal-olefin complex compounds free of C 5 H 5 .
Inventors
👤 Klaus Jonas
Bibliographic Details
Application Number—
JurisdictionUS
Data Sourcegoogle_patents
Last Synchronized2026-11-04 00:04
CPC Classifications
C; C07; C07F; C07F15/00
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
72 words
Method of preparing transition metal-olefin complex compounds and alkali metal-transition metal-olefin complex compounds or their solutions, either containing C 5 H 5 or free of C 5 H 5 , respectively, which essentially comprises reacting transition-metallocene complex compounds of metals of Group VIII or metals chromium, molybdenum, titanium or vanadium with an alkali metal or an alkali metal-transition metal complex compound, in suitable solvents, at temperatures between -60° C. and +100° C.
Claim 2
Dependent Claim
72 words
Method of preparing transition metal-olefin complex compounds and alkali metal-transition metal-olefin complex compounds or their solutions, either containing C 5 H 5 or free of C 5 H 5 , respectively, which essentially comprises reacting transition-metallocene complex compounds of metals of Group VIII or metals chromium, molybdenum, titanium or vanadium with an alkali metal or an alkali metal-transition metal complex compound, in suitable solvents, at temperatures between -60° C. and +100° C.
Claim 3
Dependent Claim
15 words
Method of claim 1, characterized in that the transition metals are iron, cobalt and nickel.
Claim 4
Dependent Claim
22 words
Method of claim 1, characterized in that chromium, molybdenum, titanium or vanadium are used instead of the transition metals of Group VIII.
Claim 5
Dependent Claim
46 words
Method of claim 1 characterized in that the reaction between the transition-metallocene complex compounds or metals of Group VIII or metals chromium, molybdenum, titanium or vanadium with an alkali metal or an alkali metal-transition metal complex compound is carried out in the presence of an olefin.