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Water-soluble tetrakisazo dyestuffs derived from 4,4'-diaminoazobenzene

Assignee: ICI FRANCOLOR SA 8 AVENUE REAUMUR BOITE POSTALE 207 92142 CLAMART CEDEX FRANCE A Co OF FRANCE
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Filing: 1977-11-14
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Granted: 1979-10-02
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Expires: 1997-11-14
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Abstract

Abstract Dyestuffs of the formula: <IMAGE> (I) in which C2 represents the radical of the formula: <IMAGE> where X is NH2 or OH, C1 and C3 are different residues of molecules C1H and C3H free from azo groups and selected from the group consisting of acetylacetic derivatives, pyrazolonic derivatives, benzenic derivatives, and naphthalenic derivatives, only one of the molecules C1H and C3H being a naphthalenic derivative, one at least of the residues C1 and C3 having at least one and at most two sulphonic acid groups, and n having the value 0 or 1 and leather colored with such dyestuffs.

Inventors

  • 👤 Pierre Frank
  • 👤 Andre L. Sailer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 12:05
CPC Classifications
C; C09; C09B; C09B35/00; C09B35/50; C09B33/00; C09B33/18; C09B33/26; C09B35/35

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 175 words
Dyestuff of the formula: ##STR7## wherein C 1 is selected from the group consisting of ethyl-acetylacetate-2 yl; 1-phenyl-3-methyl-4-yl-5-pyrazolone, in which the benzene nucleus is substituted by a sulphonic acid group in the 3' or 4' position or by two sulphonic acid groups in the 2', 5' positions and by from 0 to 2 chlorine atoms; 1-(4'-sulphophenyl)-4-yl-3-carboxy-5-pyrazolone; acetoacetanilide-2-yl; phenol-yl; 1,3-dihydroxybenzene-yl; 1,3-diaminobenzene-yl; 2,4-diaminotoluene-yl; and 1-aminonaphthalene-yl-6- or 7-sulpho; C 3 is a phenyl substituted by one sulphonic acid group in the 3 or 4 position or by two sulphonic acid groups in the 2,5-positions or by one sulphonic acid group in the 2- and one methyl in the 4-positions or by one sulphonic acid group in the 5- and one chloro in the 2-positions; X is OH or NH 2 ; each of the residues C 1 and C 3 having at least one and at most two sulphonic acid groups; C 1 is a residue of a coupling component C 1 H and C 3 is a residue of a diazotisable amine C 3 NH 2 .
Claim 2
Dependent Claim 175 words
Dyestuff of the formula: ##STR7## wherein C 1 is selected from the group consisting of ethyl-acetylacetate-2 yl; 1-phenyl-3-methyl-4-yl-5-pyrazolone, in which the benzene nucleus is substituted by a sulphonic acid group in the 3' or 4' position or by two sulphonic acid groups in the 2', 5' positions and by from 0 to 2 chlorine atoms; 1-(4'-sulphophenyl)-4-yl-3-carboxy-5-pyrazolone; acetoacetanilide-2-yl; phenol-yl; 1,3-dihydroxybenzene-yl; 1,3-diaminobenzene-yl; 2,4-diaminotoluene-yl; and 1-aminonaphthalene-yl-6- or 7-sulpho; C 3 is a phenyl substituted by one sulphonic acid group in the 3 or 4 position or by two sulphonic acid groups in the 2,5-positions or by one sulphonic acid group in the 2- and one methyl in the 4-positions or by one sulphonic acid group in the 5- and one chloro in the 2-positions; X is OH or NH 2 ; each of the residues C 1 and C 3 having at least one and at most two sulphonic acid groups; C 1 is a residue of a coupling component C 1 H and C 3 is a residue of a diazotisable amine C 3 NH 2 .
Claim 3
Dependent Claim 18 words
Dyestuff according to claim 1 wherein the diazotisable amine C 3 NH 2 is aniline, toluidine or monochloroaniline.
Claim 4
Dependent Claim 23 words
Dyestuff according to claim 1 wherein C 1 H is 1-(4'-sulphophenyl)-3-methyl-5-pyrazolone, C 3 NH 2 is aniline-2,5 disulphonic acid and X is hydroxyl.
Claim 5
Dependent Claim 23 words
Dyestuff according to claim 1 wherein C 1 H is 1-(4'-sulphophenyl)-5-pyrazolone-3-carboxylic acid, C 3 NH 2 is aniline-2,5-disulphonic acid and X is hydroxyl.

References Cited (Backward Citations)

GB265553A Cited
US2018764A Cited
US2027206A Cited
US2106876A Cited
US2116206A Cited
US2259735A Cited
US3634390A Cited
US3917887A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-01 1983-04-02 1983-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-01 1987-04-02 1987-10-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-01 1991-04-02 1991-10-02 $7700.00 Window Closed / Lapsed

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