Patent US4169831A successfully refreshed from Google Patents.
US4169831A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Water-soluble tetrakisazo dyestuffs derived from 4,4'-diaminoazobenzene
Assignee: ICI FRANCOLOR SA 8 AVENUE REAUMUR BOITE POSTALE 207 92142 CLAMART CEDEX FRANCE A Co OF FRANCE
•
Filing: 1977-11-14
•
Granted: 1979-10-02
•
Expires: 1997-11-14
Abstract
Abstract Dyestuffs of the formula: <IMAGE> (I) in which C2 represents the radical of the formula: <IMAGE> where X is NH2 or OH, C1 and C3 are different residues of molecules C1H and C3H free from azo groups and selected from the group consisting of acetylacetic derivatives, pyrazolonic derivatives, benzenic derivatives, and naphthalenic derivatives, only one of the molecules C1H and C3H being a naphthalenic derivative, one at least of the residues C1 and C3 having at least one and at most two sulphonic acid groups, and n having the value 0 or 1 and leather colored with such dyestuffs.
Inventors
- 👤 Pierre Frank
- 👤 Andre L. Sailer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:05
CPC Classifications
C; C09; C09B; C09B35/00; C09B35/50; C09B33/00; C09B33/18; C09B33/26; C09B35/35
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
175 words
Dyestuff of the formula: ##STR7## wherein C 1 is selected from the group consisting of ethyl-acetylacetate-2 yl; 1-phenyl-3-methyl-4-yl-5-pyrazolone, in which the benzene nucleus is substituted by a sulphonic acid group in the 3' or 4' position or by two sulphonic acid groups in the 2', 5' positions and by from 0 to 2 chlorine atoms; 1-(4'-sulphophenyl)-4-yl-3-carboxy-5-pyrazolone; acetoacetanilide-2-yl; phenol-yl; 1,3-dihydroxybenzene-yl; 1,3-diaminobenzene-yl; 2,4-diaminotoluene-yl; and 1-aminonaphthalene-yl-6- or 7-sulpho; C 3 is a phenyl substituted by one sulphonic acid group in the 3 or 4 position or by two sulphonic acid groups in the 2,5-positions or by one sulphonic acid group in the 2- and one methyl in the 4-positions or by one sulphonic acid group in the 5- and one chloro in the 2-positions; X is OH or NH 2 ; each of the residues C 1 and C 3 having at least one and at most two sulphonic acid groups; C 1 is a residue of a coupling component C 1 H and C 3 is a residue of a diazotisable amine C 3 NH 2 .
Claim 2
Dependent Claim
175 words
Dyestuff of the formula: ##STR7## wherein C 1 is selected from the group consisting of ethyl-acetylacetate-2 yl; 1-phenyl-3-methyl-4-yl-5-pyrazolone, in which the benzene nucleus is substituted by a sulphonic acid group in the 3' or 4' position or by two sulphonic acid groups in the 2', 5' positions and by from 0 to 2 chlorine atoms; 1-(4'-sulphophenyl)-4-yl-3-carboxy-5-pyrazolone; acetoacetanilide-2-yl; phenol-yl; 1,3-dihydroxybenzene-yl; 1,3-diaminobenzene-yl; 2,4-diaminotoluene-yl; and 1-aminonaphthalene-yl-6- or 7-sulpho; C 3 is a phenyl substituted by one sulphonic acid group in the 3 or 4 position or by two sulphonic acid groups in the 2,5-positions or by one sulphonic acid group in the 2- and one methyl in the 4-positions or by one sulphonic acid group in the 5- and one chloro in the 2-positions; X is OH or NH 2 ; each of the residues C 1 and C 3 having at least one and at most two sulphonic acid groups; C 1 is a residue of a coupling component C 1 H and C 3 is a residue of a diazotisable amine C 3 NH 2 .
Claim 3
Dependent Claim
18 words
Dyestuff according to claim 1 wherein the diazotisable amine C 3 NH 2 is aniline, toluidine or monochloroaniline.
Claim 4
Dependent Claim
23 words
Dyestuff according to claim 1 wherein C 1 H is 1-(4'-sulphophenyl)-3-methyl-5-pyrazolone, C 3 NH 2 is aniline-2,5 disulphonic acid and X is hydroxyl.
Claim 5
Dependent Claim
23 words
Dyestuff according to claim 1 wherein C 1 H is 1-(4'-sulphophenyl)-5-pyrazolone-3-carboxylic acid, C 3 NH 2 is aniline-2,5-disulphonic acid and X is hydroxyl.
References Cited (Backward Citations)
GB265553A
Cited
US2018764A
Cited
US2027206A
Cited
US2106876A
Cited
US2116206A
Cited
US2259735A
Cited
US3634390A
Cited
US3917887A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-10-01 | 1983-04-02 | 1983-10-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-10-01 | 1987-04-02 | 1987-10-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-10-01 | 1991-04-02 | 1991-10-02 | $7700.00 | Window Closed / Lapsed |