Patent US4168226A successfully refreshed from Google Patents.
US4168226A
Expired / Lapsed
US
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Thermal stabilization of N-methyl-2-pyrrolidone
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1978-10-16
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Granted: 1979-09-18
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Expires: 1998-10-16
Abstract
Abstract The thermal decomposition of N-methyl-2-pyrrolidone is minimized by the addition of minor amounts of water thereto prior to its being heated to temperatures in excess of 500 DEG F. This is of particular importance in processes using N-methyl-2-pyrrolidone as an extraction solvent to remove aromatics from mixtures of aromatic and non-aromatic hydrocarbons and wherein the N-methyl-2-pyrrolidone is recovered from the extracted fractions by thermal means such as flash evaporation and distillation.
Inventors
- 👤 Anthony M. White
- 👤 Bruce M. Sankey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 20:41
CPC Classifications
C; C10; C10G; C10G21/00; C10G21/28
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
43 words
A method for minimizing the thermal decomposition of N-methyl-2-pyrrolidone solvent heated to temperatures above 600° F., which comprises adding water to said solvent so that the water content thereof is at least about 0.5 LV% when said solvent is heated to said temperatures.
Claim 2
Independent Claim
43 words
A method for minimizing the thermal decomposition of N-methyl-2-pyrrolidone solvent heated to temperatures above 600° F., which comprises adding water to said solvent so that the water content thereof is at least about 0.5 LV% when said solvent is heated to said temperatures.
Claim 3
Dependent Claim
27 words
The method of claim 1 wherein the NMP solvent is mixed with a hydrocarbon and wherein the 0.5 LV% water is based on the NMP content thereof.
Claim 4
Dependent Claim
15 words
The method of claim 1 wherein said temperatures range from about 600°to about 900° F.
Claim 5
Dependent Claim
20 words
The method of claim 3 wherein the water content of the NMP ranges from about 0.5 to about 10 LV%.
Claim 6
Dependent Claim
25 words
The method of claim 4 wherein the water content of the NMP is at least about 1 LV% and wherein said temperatures exceed 700° F.
Claim 7
Dependent Claim
97 words
In a hydrocarbon extraction process wherein a hydrocarbon feed is contacted with an extraction solvent comprising NMP to form a raffinate and extract phase with both phases containing NMP and wherein said NMP is recovered from at least one of said phases by employing thermal recovery means and wherein at least one of said NMP containing phases is heated to temperatures above 600° F., the improvement comprising adding water to said phase to that it contains at least 0.5 LV% water based on the NMP content thereof before said phase is heated to temperatures above 600° F.
Claim 8
Dependent Claim
97 words
In a hydrocarbon extraction process wherein a hydrocarbon feed is contacted with an extraction solvent comprising NMP to form a raffinate and extract phase with both phases containing NMP and wherein said NMP is recovered from at least one of said phases by employing thermal recovery means and wherein at least one of said NMP containing phases is heated to temperatures above 600° F., the improvement comprising adding water to said phase to that it contains at least 0.5 LV% water based on the NMP content thereof before said phase is heated to temperatures above 600° F.
Claim 9
Dependent Claim
16 words
The process of claim 6 wherein said high temperatures range from about 600°to about 900° F.
Claim 10
Dependent Claim
18 words
The process of claim 7 wherein said water comprises from about 0.5 to 10 LV% of the NMP.
Claim 11
Dependent Claim
23 words
The process of claim 6 wherein said water comprises at least about 1 LV% of the NMP and said temperature exceeds 700° F.
Claim 12
Dependent Claim
119 words
In a lube oil extraction process wherein a lube oil feed stock is extracted with a solvent comprising NMP and minor amounts of water to form a raffinate phase containing a desired lube oil and an extract phase containing aromatic and other undesirable lube oil components and wherein a substantial amount of the extraction solvent is recovered by thermal means and wherein at least a portion of at least one of said phase is heated to temperatures above 600° F. in the recovery process, the improvement comprising adding water to said phase so that the water content thereof is at least 0.5 LV% of the NMP content thereof when said phase is heated to said temperatures above 600° F.
Claim 13
Dependent Claim
119 words
In a lube oil extraction process wherein a lube oil feed stock is extracted with a solvent comprising NMP and minor amounts of water to form a raffinate phase containing a desired lube oil and an extract phase containing aromatic and other undesirable lube oil components and wherein a substantial amount of the extraction solvent is recovered by thermal means and wherein at least a portion of at least one of said phase is heated to temperatures above 600° F. in the recovery process, the improvement comprising adding water to said phase so that the water content thereof is at least 0.5 LV% of the NMP content thereof when said phase is heated to said temperatures above 600° F.
Claim 14
Dependent Claim
35 words
The process of claim 10 wherein the water content of said phase ranges from about 0.5 to about 10 LV% based on the NMP content thereof while said phase is exposed to said high temperatures.
Claim 15
Dependent Claim
16 words
The process of claim 11 wherein said high temperatures range from about 600°to about 900° F.
Claim 16
Dependent Claim
38 words
The process of claim 11 wherein the water content of said phase is at least 1 LV% of the NMP content thereof when said phase is heated to said temperatures and wherein said high temperatures exceed 700° F.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-09-17 | 1983-03-19 | 1983-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-09-17 | 1987-03-19 | 1987-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-09-17 | 1991-03-19 | 1991-09-18 | $7700.00 | Window Closed / Lapsed |