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US4168171A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive thermal developable diazotype sheets with imidazoles

Assignee: 3M Co
•
Filing: 1977-08-05
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Granted: 1979-09-18
•
Expires: 1997-08-05
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Abstract

Abstract A heat-developable diazotype sheet containing an acid-stabilized diazonium salt in one layer thereof and an acid-neutralizing component in another layer thereof is shown wherein at least 25% by weight of the acid-neutralizer component comprises imidazole derivatives of a specific formula.

Inventors

  • 👤 John M. Winslow
  • 👤 Gary E. LaBelle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:11
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/52; G03C1/60

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 158 words
A heat reactive diazotype sheet having a supporting substrate having at least two layers thereon, one of said layers comprising a heat-softenable binder material and an acid-stabilized light sensitive diazonium salt capable of reacting with an azo-coupler compound to form a dye, and the other of said layers comprising a heat-softenable binder material and an acid-neutralizer component capable of providing basic equivalents in an amount at least sufficient to neutralize said acid stabilization of said diazonium salt so as to provide a weakly basic environment for the diazonium salt in the sheet and to render said acid-stabilized diazonium salt reactive with said azo-coupler compound, and at least one of said layers containing an azo-coupler, said diazotype sheet being characterized by said acid-neutralizer component being comprised of at least 25% by weight imidazole acid-neutralizer compound is selected from the group consisting of 2-isopropyl imidazole, 2-phenyl imidazole, 2-benzyl imidazole, 4-phenyl imidazole, 4-methyl imidazole, 2,4-dimethyl imidazole, 2-phenyl-4-methyl imidazole, and 2,4,5-trimethyl imidazole.
Claim 2
Dependent Claim 158 words
A heat reactive diazotype sheet having a supporting substrate having at least two layers thereon, one of said layers comprising a heat-softenable binder material and an acid-stabilized light sensitive diazonium salt capable of reacting with an azo-coupler compound to form a dye, and the other of said layers comprising a heat-softenable binder material and an acid-neutralizer component capable of providing basic equivalents in an amount at least sufficient to neutralize said acid stabilization of said diazonium salt so as to provide a weakly basic environment for the diazonium salt in the sheet and to render said acid-stabilized diazonium salt reactive with said azo-coupler compound, and at least one of said layers containing an azo-coupler, said diazotype sheet being characterized by said acid-neutralizer component being comprised of at least 25% by weight imidazole acid-neutralizer compound is selected from the group consisting of 2-isopropyl imidazole, 2-phenyl imidazole, 2-benzyl imidazole, 4-phenyl imidazole, 4-methyl imidazole, 2,4-dimethyl imidazole, 2-phenyl-4-methyl imidazole, and 2,4,5-trimethyl imidazole.
Claim 3
Dependent Claim 24 words
The heat reactive diazotype sheet of claim 1 wherein at least 50% by weight of said acid neutralizer component is an imidazole acid-neutralizer compound.
Claim 4
Dependent Claim 24 words
The heat reactive diazotype sheet of claim 1 wherein at least 75% by weight of said acid neutralizer component is an imidazole acid-neutralizer compound.
Claim 5
Dependent Claim 27 words
The heat reactive diazotype sheet of claim 1 wherein said imidazole acid-neutralizer component is selected from the group consisting of 2-isopropyl imidazole, 2-phenyl imidazole, and 2-benzyl imidazole.

References Cited (Backward Citations)

US3022716A Cited
US3140645A Cited
US3211073A Cited
US3199982A Cited
US3294534A Cited
US3520691A Cited
US3754916A Cited
US3910794A Cited
JPS5173431A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-17 1983-03-19 1983-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-17 1987-03-19 1987-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-17 1991-03-19 1991-09-18 $7700.00 Window Closed / Lapsed

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