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US4167626A Expired / Lapsed US ⏱️ 0.0 years remaining

Triazolyl stilbene triazoles

Assignee: Sandoz AG
•
Filing: 1977-07-22
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Granted: 1979-09-11
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Expires: 1997-07-22
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Abstract

Abstract Disclosed are compounds of formula I, <IMAGE> I in which X signifies hydrogen, C1-4alkyl, cyano, -COOM, -COOR1, -CONR2R3, -SO2NR2R3, -SO2R1, -SOR1, -SO3R1 or -SO3M, Y signifies hydrogen, C1-4alkyl, cyano, -COOM, -COOR1, -CONR2R3, -SO2NR2R3, -SO2R1, -SOR1, -SO3R1 or -SO3M, with the proviso that X and Y do not simultaneously have a significance selected from hydrogen and C1-4alkyl, R signifies an aryl radical, unsubstituted or substituted by up to two substituents selected from C1-4 alkyl, C1-4 alkoxy, chlorine, cyano, -COOM, -COOR1, -CONR4R5, -SO2NR4R5, -SO2R1 and -SO3M, R1 signifies C1-4alkyl or phenyl, R2 and R3, independently, signify hydrogen or C1-4alkyl, either R4 and R5, independently, signify hydrogen or C1-4alkyl, OR R4 and R5, together with the nitrogen atom to which they are attached, signify a five or six membered heterocyclic radical, and THE M's, independently, signify hydrogen or a non-chromophoric cation, their production and use as anionic optical brightening agents, particularly for cellulosic and polyamide substrates.

Inventors

  • 👤 Fritz Fleck
  • 👤 Alec V. Mercer
  • 👤 Roger Paver

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:48
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/02; C07D249/04; C07D249/06; D; D06; D06L; D06L4/00; D06L4/60; D06L4/614; D06L4/621

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 73 words
A compound of formula I", ##STR53## in which Y" signifies --COOM, --COOR 1 ", --CONH 2 , or --SO 3 M, R" signifies phenyl, unsubstituted or mono- or di-substituted by methyl, C 1-2 alkoxy, chlorine, cyano, --CONH 2 , --COOM, --COOR 1 ", --SO 2 CH 3 , SO 2 NH 2 or --SO 3 M, R 1 " signifies C 1-2 alkyl, and the M's are, independently, hydrogen or a non-chromophoric cation.
Claim 2
Dependent Claim 73 words
A compound of formula I", ##STR53## in which Y" signifies --COOM, --COOR 1 ", --CONH 2 , or --SO 3 M, R" signifies phenyl, unsubstituted or mono- or di-substituted by methyl, C 1-2 alkoxy, chlorine, cyano, --CONH 2 , --COOM, --COOR 1 ", --SO 2 CH 3 , SO 2 NH 2 or --SO 3 M, R 1 " signifies C 1-2 alkyl, and the M's are, independently, hydrogen or a non-chromophoric cation.
Claim 3
Dependent Claim 25 words
A compound of claim 1, in which Y" is other than --CONH 2 , and in which any phenyl as R" is unsubstituted or mono-substituted.
Claim 4
Dependent Claim 32 words
A compound of claim 1, in which Y" is --COOM, --COOR 1 " or --CONH 2 , and R" is phenyl, unsubstituted or mono-substituted by methyl, methoxy, chlorine or --SO 3 M.
Claim 5
Dependent Claim 34 words
A compound of claim 1, wherein Y" is --SO 3 M and R" is phenyl, mono-substituted by --SO 3 M, or di-substituted, once by --SO 3 M and once by methyl, methoxy or chlorine.
Claim 6
Dependent Claim 8 words
A compound of claim 3, of formula ##STR54##
Claim 7
Dependent Claim 8 words
A compound of claim 3, of formula ##STR55##
Claim 8
Dependent Claim 8 words
A compound of claim 3, of formula ##STR56##
Claim 9
Dependent Claim 8 words
A compound of claim 4, of formula ##STR57##
Claim 10
Dependent Claim 26 words
A compound according to claim 1 wherein R", when disubstituted, is substituted once by --SO 3 M and once by methyl, C 1-2 alkoxy or chlorine.
Claim 11
Dependent Claim 22 words
A compound according to claim 1 wherein R" is unsubstituted phenyl or phenyl monosubstituted by cyano, methoxy, chlorine or --SO 3 M.
Claim 12
Dependent Claim 74 words
A compound according to claim 1 of the formula ##STR58## in which Y" signifies --COOM, --COOR 1 " or --CONH 2 , R" signifies phenyl, unsubstituted or mono- or di-substituted by methyl, C 1-2 alkoxy, chlorine, cyano, --CONH 2 , --COOM, --COOR 1 ", --SO 2 CH 3 , SO 2 NH 2 or --SO 3 M, R 1 " signifies C 1-2 alkyl, and the M's are, independently, hydrogen or a non-chromophoric cation.

References Cited (Backward Citations)

GB1320836A Cited
US3928329A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-10 1983-03-12 1983-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-10 1987-03-12 1987-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-10 1991-03-12 1991-09-11 $7700.00 Window Closed / Lapsed

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