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US4167542A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester resin compositions containing dicyclopentadiene alkenoate

Assignee: Dow Chemical Co
•
Filing: 1978-10-23
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Granted: 1979-09-11
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Expires: 1998-10-23
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Abstract

Abstract Thermosetting resin compositions containing unsaturated polyester resins which have been modified with a dicyclopentadiene. The polyester resins are blended with a mixture of vinyl aromatic monomers and dicyclopentadiene alkenoate. The resin compositions are useful to make fibrous reinforcement laminates. The use of the dicyclopentadiene alkenoate accelerates the rate at which hardness develops during room temperature cure.

Inventors

  • 👤 Donald L. Nelson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 05:19
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/54; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0478; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31616; Y10T428/3162; Y10T442/00; Y10T442/20; Y10T442/2926; Y10T442/2992

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 82 words
A thermosetting resin composition which comprises (A) about 80 to about 30% by weight of a linear unsaturated polyester containing 10 to 100 mole percent of a dicyclopentadiene concentrate based on the moles of dicarboxylic acid or anhydride contained in said polyester, (B) about 20 to about 70% by weight of an unsaturated monomer mixture of a vinyl aromatic monomer and a dicyclopentadiene alkenoate wherein the range of dicyclopentadiene alkenoate in said mixture ranges from about 5 to about 90 weight percent.
Claim 2
Dependent Claim 82 words
A thermosetting resin composition which comprises (A) about 80 to about 30% by weight of a linear unsaturated polyester containing 10 to 100 mole percent of a dicyclopentadiene concentrate based on the moles of dicarboxylic acid or anhydride contained in said polyester, (B) about 20 to about 70% by weight of an unsaturated monomer mixture of a vinyl aromatic monomer and a dicyclopentadiene alkenoate wherein the range of dicyclopentadiene alkenoate in said mixture ranges from about 5 to about 90 weight percent.
Claim 3
Dependent Claim 56 words
The resin composition of claim 1 wherein the unsaturated polyester is prepared by the reaction under resin forming conditions of: (A) a glycol, (B) an olefinically unsaturated dicarboxylic acid or the anhydride thereof or mixtures thereof, and (C) 10 to 100 mole percent of a dicyclopentadiene concentrate based on the moles of dicarboxylic acid or anhydride.
Claim 4
Dependent Claim 70 words
The resin composition of claim 1 wherein the unsaturated polyester is prepared by the reaction of (A) a glycol, (B) an olefinically unsaturated dicarboxylic acid or the anhydride thereof or mixtures thereof, (C) a saturated dicarboxylic acid or the anhydride thereof or mixtures thereof or mixtures of (B) and (C), and (D) 10 to 100 mole percent of a dicyclopentadiene concentrate based on the moles of dicarboxylic acid or anhydride.
Claim 5
Dependent Claim 13 words
The resin composition of claim 1 wherein the dicyclopentadiene alkenoate is dicyclopentadiene acrylate.
Claim 6
Dependent Claim 11 words
A cured fibrous laminate made with the composition of claim 1.
Claim 7
Dependent Claim 11 words
A cured fibrous laminate made with the composition of claim 2.
Claim 8
Dependent Claim 11 words
A cured fibrous laminate made with the composition of claim 3.
Claim 9
Dependent Claim 11 words
A cured fibrous laminate made with the composition of claim 4.

References Cited (Backward Citations)

US3347806A Cited
US3553294A Cited
US3883612A Cited
US3933757A Cited
US4029848A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-10 1983-03-12 1983-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-10 1987-03-12 1987-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-10 1991-03-12 1991-09-11 $7700.00 Window Closed / Lapsed

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