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US3933757A Expired / Lapsed US ⏱️ 0.0 years remaining

Dicyclopentadiene thermosetting polyester

Assignee: SCM Corp
•
Filing: 1974-10-21
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Granted: 1976-01-20
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Expires: 1994-10-21
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Abstract

Abstract The invention pertains to a dicyclopentadiene modified thermosetting polyester polymer wherein dicyclopentadiene is preferentially esterified in the polymer chain. The dicyclopentadiene polyester polymer is mixed with an ethylenically unsaturated monomer to provide thermosetting polyester resin.

Inventors

  • 👤 Ivor Pratt
  • 👤 Ulrich Boschert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 21:05
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/54; C08G63/553; C08L; C08L67/00; C08L67/06

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 87 words
A method of synthesizing a thermosetting dicyclopentadiene terminated polyester from glycol, dicarboxylic acid, and dicyclopentadiene, said polyester suitable for mixing with sytrene to provide a thermosettable polyester resin, the improvement comprising: reacting an excess molar equivalent of dicarboxylic acid with glycol to produce an acid terminated partial polymer having carboxyl groups; reacting about 0.1-0.4 mols of dicyclopentadiene per mol of unsaturated dicarboxylic acid with said acid terminated partial polymer at temperatures between about 290°- 310°F. until substantially all of said dicyclopentadiene is esterified with said carboxyl groups.
Claim 2
Independent Claim 87 words
A method of synthesizing a thermosetting dicyclopentadiene terminated polyester from glycol, dicarboxylic acid, and dicyclopentadiene, said polyester suitable for mixing with sytrene to provide a thermosettable polyester resin, the improvement comprising: reacting an excess molar equivalent of dicarboxylic acid with glycol to produce an acid terminated partial polymer having carboxyl groups; reacting about 0.1-0.4 mols of dicyclopentadiene per mol of unsaturated dicarboxylic acid with said acid terminated partial polymer at temperatures between about 290°- 310°F. until substantially all of said dicyclopentadiene is esterified with said carboxyl groups.
Claim 3
Dependent Claim 35 words
The process of claim 1 wherein the dicyclopentadiene reacts with said acid terminated partial polymer to form an acid terminated prepolymer, and additional glycol is reacted with said prepolymer to further esterify unreacted carboxyl groups.
Claim 4
Dependent Claim 43 words
The process of claim 2 wherein about one-half the glycol requirements is first reacted with excess molar dicarboxylic acid, and the other one-half of the glycol requirements is reacted after the intermediate step of esterifying said dicyclopentadiene with said acid terminated partial polymer.
Claim 5
Dependent Claim 29 words
A dicyclopentadiene terminated, thermosetting polyester wherein dicyclopentadiene is substantially esterified with carboxyl groups of the acid terminated partial polymer in accordance with the process set forth in claim 1.

References Cited (Backward Citations)

US3347806A Cited
US3340327A Cited
US3166434A Cited
US3333022A Cited
US3448066A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-19 1979-07-21 1980-01-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-19 1983-07-21 1984-01-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-19 1987-07-21 1988-01-20 $7700.00 Window Closed / Lapsed

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