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US4167491A Expired / Lapsed US ⏱️ 0.0 years remaining

Radioactive waste disposal

Assignee: Nuclear Engineering Co Inc
•
Filing: 1976-06-07
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Granted: 1979-09-11
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Expires: 1996-06-07
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Abstract

Abstract A method of disposing of wet radioactive waste materials such as those generated in the water used to cool atomic reactors, comprising combining the waste material with a hydrophilic resin in proportions sufficient to provide a solid mass of the resin with the radioactive waste component distributed within. In its preferred form, the waste material is concentrated by separating water from the radioactive portions thereof by methods such as evaporation, taking up the waste components with an ion exchange resin and separating the resin from the bulk of the water, or by the addition of flocculating agents or the like and filtering. The preferred hydrophilic resinous material is a conventional urea-formaldehyde dispersion, which is partially polymerized and capable of taking up water and fully polymerizing upon the addition of an acidic curing agent. The method also contemplates adding a substantially waterproof resinous material to the surface of the solid block, or enclosing it in a waterproof container, or both.

Inventors

  • 👤 Kenneth A. Gablin
  • 👤 Larry J. Hansen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:06
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/04; G21F9/06; G21F9/16; G21F9/167; G21F9/10; G21F9/12

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 47 words
An article for safe transportation and storage of radioactive waste material containing free water, comprising a solid body of polymerized urea-formaldehyde resin having water and the radioactive components of such waste material distributed therein in controlled proportions providing a desired low hazard radiation classification of said body.
Claim 2
Dependent Claim 47 words
An article for safe transportation and storage of radioactive waste material containing free water, comprising a solid body of polymerized urea-formaldehyde resin having water and the radioactive components of such waste material distributed therein in controlled proportions providing a desired low hazard radiation classification of said body.
Claim 3
Dependent Claim 22 words
An article as described in claim 1 and wherein said radioactive waste material includes an insoluble ion exchange resin in particulate form.
Claim 4
Dependent Claim 39 words
An article as described in claim 1 and wherein said body further comprises a non-radioactive filler material distributed therein for further increasing the volume of said body so as to act as a shield and attenuate radiation levels therefrom.
Claim 5
Dependent Claim 18 words
An article as described in claim 1 and wherein said body is encased in a disposable protective container.
Claim 6
Dependent Claim 87 words
A composition of matter, comprising an aqueous dispersion of urea-formaldehyde in a partially polymerized state and in an amount sufficient to solidify substantially all of the water present, said aqueous dispersion further including a measured quantity of radioactive waste material and water in a controlled amount to meet a desired low hazard radiation classification of said dispersion, and a curing agent capable of promoting polymerization of said urea-formaldehyde in an amount sufficient to solidify said dispersion, said radioactive waste material being distributed substantially evenly throughout said dispersion.
Claim 7
Dependent Claim 87 words
A composition of matter, comprising an aqueous dispersion of urea-formaldehyde in a partially polymerized state and in an amount sufficient to solidify substantially all of the water present, said aqueous dispersion further including a measured quantity of radioactive waste material and water in a controlled amount to meet a desired low hazard radiation classification of said dispersion, and a curing agent capable of promoting polymerization of said urea-formaldehyde in an amount sufficient to solidify said dispersion, said radioactive waste material being distributed substantially evenly throughout said dispersion.
Claim 8
Dependent Claim 24 words
A composition as described in claim 5 and further comprising a measured quantity of particles of ion-exchange resin having radioactive metallic cations adsorbed thereon.
Claim 9
Dependent Claim 26 words
A composition as described in claim 6 and wherein said ion-exchange resin comprises a styrene-divinylbenzene matrix suitably sulfonated to provide a strongly acidic cation exchange resin.
Claim 10
Dependent Claim 23 words
A composition as described in claim 5 and further comprising a measured quantity of particulate insoluble material having radioactive metallic cations absorbed therein.
Claim 11
Dependent Claim 18 words
A composition as described in claim 5 and wherein said radioactive waste material comprises nuclear reactor evaporator bottoms.
Claim 12
Dependent Claim 30 words
A composition as described in claim 5 and wherein said urea-formaldehyde comprises about 20% to about 40% by weight of the combined weight of said urea-formaldehyde and said water present.
Claim 13
Dependent Claim 28 words
A composition as described in claim 10 and wherein said curing agent is an acidic material having a dissociation constant between about 10 0 and 10 -5 .
Claim 14
Dependent Claim 46 words
A composition of matter, comprising a solid plastic matrix of cured urea-formaldehyde, a measured quantity of radioactive waste material substantially evenly distributed throughout said matrix, and a controlled quantity of water incorporated in said matrix in an amount to meet a desired low hazard radiation classification.
Claim 15
Dependent Claim 46 words
A composition of matter, comprising a solid plastic matrix of cured urea-formaldehyde, a measured quantity of radioactive waste material substantially evenly distributed throughout said matrix, and a controlled quantity of water incorporated in said matrix in an amount to meet a desired low hazard radiation classification.
Claim 16
Dependent Claim 23 words
A composition as described in claim 12 and wherein said radioactive waste material is derived from recirculating cooling water in a nuclear reactor.

References Cited (Backward Citations)

US3012385A Cited
GB962582A Cited
US3330088A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-10 1983-03-12 1983-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-10 1987-03-12 1987-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-10 1991-03-12 1991-09-11 $7700.00 Window Closed / Lapsed

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