Patent US4165344A successfully refreshed from Google Patents.
US4165344A
Expired / Lapsed
US
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Cyclopentadiene resin and isocyanate cured epoxy resin compositions
Assignee: Zeon Corp
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Filing: 1977-05-09
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Granted: 1979-08-21
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Expires: 1997-05-09
Abstract
Abstract An epoxy resin composition comprising (a) a cyclopentadiene-type hydrocarbon resin having a hydroxyl value of 100 to 300 obtained by copolymerizing a cyclopentadiene-type monomer and a hydroxyl-containing monolefinic monomer at elevated temperatures, (b) a polyol selected from the group consisting of epoxy resins containing at least two hydroxyl groups in the molecule and epoxy resin derivatives containing at least two hydroxyl groups in the molecule and obtained by the reaction of epoxy resins with alkanolamines, and (c) an isocyanate-type curing agent. The compositions have improved low temperature curability, acid resistance and water resistance while retaining the various desirable properties of epoxy resins such as chemical resistance and oil resistance, and which when used as paints, exhibit improved adhesion to an adherend and improved re-coating adhesion to the film formed thereon.
Inventors
- 👤 Takao Okuda
- 👤 Akira Wada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 09:50
CPC Classifications
C; C08; C08L; C08L63/00; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/58; C08G18/584; C08G18/62; C08G18/6204; C08G18/67; C08G18/6705; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4028; C08G59/62; C08G59/64; C09; C09D; C09D163/00
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
127 words
An epoxy resin composition comprising (a) a cyclopentadiene or cyclopentadiene skeleton-containing hydrocarbon resin having a hydroxyl value of 100 to 300 obtained by copolymerizing cyclopentadiene or a cyclopentadiene skeleton-containing monomer and a hydroxyl-containing monolefinic monomer at elevated temperatures, (b) a polyol selected from the group consisting of epoxy resins containing at least two hydroxyl groups in the molecule and epoxy resin derivatives containing at least two hydroxyl groups in the molecule and obtained by the reaction of epoxy resins with alkanolamines, and (c) an isocyanate group containing polyol curing agent wherein the amounts of the cyclopentadiene hydrocarbon resin (a) and the polyol (b) are 90 to 5% by weight, and 10 to 95% by weight, respectively based on the total weight of the components (a) and (b).
Claim 2
Dependent Claim
127 words
An epoxy resin composition comprising (a) a cyclopentadiene or cyclopentadiene skeleton-containing hydrocarbon resin having a hydroxyl value of 100 to 300 obtained by copolymerizing cyclopentadiene or a cyclopentadiene skeleton-containing monomer and a hydroxyl-containing monolefinic monomer at elevated temperatures, (b) a polyol selected from the group consisting of epoxy resins containing at least two hydroxyl groups in the molecule and epoxy resin derivatives containing at least two hydroxyl groups in the molecule and obtained by the reaction of epoxy resins with alkanolamines, and (c) an isocyanate group containing polyol curing agent wherein the amounts of the cyclopentadiene hydrocarbon resin (a) and the polyol (b) are 90 to 5% by weight, and 10 to 95% by weight, respectively based on the total weight of the components (a) and (b).
Claim 3
Dependent Claim
38 words
The composition of claim 1 wherein the isocyanate curing agent (c) is contained in an amount such that there are 0.3 to 1.5 equivalents of isocyanate groups per equivalent of the hydroxyl groups based on the polyol (b).
Claim 4
Dependent Claim
30 words
The composition of claim 1 wherein the cyclopentadiene hydrocarbon resin (a) has a softening point of 50° to 170° C., and a Gardner color number of not more than 10.
Claim 5
Dependent Claim
23 words
The composition of claim 3 wherein the cyclopentadiene monomer is cyclopentadiene, methyl cyclopentadiene, or a dimer, trimer or codimer of any of these.
Claim 6
Dependent Claim
21 words
The composition of claim 3 wherein the hydroxyl-containing monolefinic monomer is allyl alcohol, crotyl alcohol, cis-2-butene-1,4-diol, hydroxyethyl acrylate, or hydroxyethyl methacrylate.
Claim 7
Dependent Claim
16 words
The composition of claim 1 wherein the polyol (b) is an ether group containing epoxy resin.
Claim 8
Dependent Claim
30 words
The composition of claim 1 wherein the polyol (b) is synthesized by the reaction of an ether group containing glycidyl ester group containing or alicyclic epoxy resin with an alkanolamine.
Claim 9
Dependent Claim
20 words
The composition of claim 1 wherein the isocyanate groups containing curing agent (c) is an aliphatic, alicyclic or aromatic polyisocyanate.
Claim 10
Dependent Claim
13 words
The composition of claim 1 wherein the hydroxyl-containing monolefinic monomer is allyl alcohol.
Claim 11
Dependent Claim
18 words
The composition of claim 1 wherein the polyol (b) is the condensation product of bisphenol A and epichlorohydrin.
Claim 12
Dependent Claim
40 words
The composition of claim 5 wherein the polyol (b) is a glycidyl ether group-containing epoxy resin or an epoxy resin which is the reaction product of a glycidyl ether group-containing, glycidyl ester group-containing or alicyclic epoxy resin with an alkanolamine.
Claim 13
Dependent Claim
51 words
The composition of claim 11 wherein the isocyanate group-containing curing agent (c) is an aliphatic, alicyclic or aromatic polyisocyanate wherein the isocyanate curing agent is contained in an amount such that there are 0.3 to 1.5 equivalents of isocyanate groups per equivalent of the hydroxyl groups based on the polyol (b).
Claim 14
Dependent Claim
24 words
The composition of claim 12 wherein the hydroxyl-containing monolefinic monomer is allyl alcohol and the polyol (b) is a glycidyl ether group-containing epoxy resin.
Claim 15
Dependent Claim
41 words
The composition of claim 12 wherein the amount of the cyclopentadiene hydrocarbon resin (a) and the polyol (b) are 60 to 30% by weight, and 40 to 70% by weight, respectively, based on the total weight of components (a) and (b).
References Cited (Backward Citations)
US3317471A
Cited
US4012458A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-08-20 | 1983-02-19 | 1983-08-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-08-20 | 1987-02-19 | 1987-08-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-08-20 | 1991-02-19 | 1991-08-21 | $7700.00 | Window Closed / Lapsed |