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US4164555A Expired / Lapsed US ⏱️ 0.0 years remaining

Pollution control system and method for the removal of sulfur oxides

Assignee: Foster Wheeler Energy Corp
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Filing: 1977-09-12
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Granted: 1979-08-14
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Expires: 1997-09-12
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Abstract

Abstract A pollution control system and method in which sulfur oxides in flue gases are adsorbed by activated char in a gas-solid contacting device. The saturated char is regenerated in an integrated desorption-reduction vessel, to which crushed coal and combustion-supporting air are supplied. A portion of the crushed coal is burned to provide the heat for the regeneration of the char, resulting in the formation of sulfur dioxide and carbon dioxide gases, and the chemical consumption of a portion of the char. The remaining crushed coal reduces the sulfur dioxide to gaseous sulfur, and results in a material having a porous system suitable for use in the adsorption of sulfur oxides. The remaining regenerated char and the oxidized coal are cycled back to the gas-solid contacting device, and the gaseous sulfur is condensed to liquid in a condenser.

Inventors

  • 👤 Peter Steiner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:32
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/0473; C01B17/0482; B; B01; B01D; B01D53/00; B01D53/02

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 99 words
A method for treating a sulfur oxides-saturated carbonaceous adsorbent char comprising the steps of: passing said char to a vessel; introducing combustion-supporting air into said vessel; introducing a quantity of coal into said vessel; and simultaneously burning a portion of said quantity of coal as a fuel to provide heat to desorb said char of said sulfur oxides and reacting said sulfur oxides with the remaining portion of said coal to produce gaseous elemental sulfur, the adsorbent characteristics of said remaining coal portion being enhanced such that said remaining coal portion constitutes a carbonaceous adsorbent material after said reacting.
Claim 2
Independent Claim 99 words
A method for treating a sulfur oxides-saturated carbonaceous adsorbent char comprising the steps of: passing said char to a vessel; introducing combustion-supporting air into said vessel; introducing a quantity of coal into said vessel; and simultaneously burning a portion of said quantity of coal as a fuel to provide heat to desorb said char of said sulfur oxides and reacting said sulfur oxides with the remaining portion of said coal to produce gaseous elemental sulfur, the adsorbent characteristics of said remaining coal portion being enhanced such that said remaining coal portion constitutes a carbonaceous adsorbent material after said reacting.
Claim 3
Dependent Claim 38 words
The method of claim 1, further comprising the steps of: condensing said gaseous elemental sulfur to liquid sulfur; and conveying said desorbed char and said reacted portion of coal to an adsorption means for use as adsorbent material.
Claim 4
Dependent Claim 20 words
The method of claim 1, wherein the step of introducing combustion-supporting air includes heating said air to a predetermined temperature.
Claim 5
Dependent Claim 22 words
The method claimed in claim 1 wherein: said remaining coal portion undergoes an increase in porosity as a consequence of said reacting.
Claim 6
Dependent Claim 22 words
The method claimed in claim 1 wherein: said char and said remaining coal portion pass through said vessel in continuous mass flow.
Claim 7
Dependent Claim 30 words
The method claimed in claim 1, further comprising the step of: conveying said desorbed char and said reacted portion of coal to an adsorption means for use as adsorbent material.
Claim 8
Independent Claim 158 words
A method for the removal of sulfur oxides from flue gases and the production of elemental sulfur comprising: contacting the flue gases with an adsorbent char in a first vessel and adsorbing the sulfur oxides onto said char; passing the sulfur oxides saturated char to a second vessel; introducing a quantity of coal into said second vessel; simultaneously burning a portion of said quantity of coal as a fuel in the presence of said sulfur oxides-saturated char to provide heat to desorb said char of said sulfur oxides and reacting said sulfur oxides with the remaining portion of coal to produce gaseous elemental sulfur, the adsorbent characteristics of said remaining coal portion being enhanced such that the remaining coal portion constitutes a carbonaceous adsorbent material after said reacting; condensing said gaseous elemental sulfur to liquid sulfur; and conveying said desorbed char and said reacted portion of said coal to said first vessel for use as an adsorbent material.
Claim 9
Independent Claim 158 words
A method for the removal of sulfur oxides from flue gases and the production of elemental sulfur comprising: contacting the flue gases with an adsorbent char in a first vessel and adsorbing the sulfur oxides onto said char; passing the sulfur oxides saturated char to a second vessel; introducing a quantity of coal into said second vessel; simultaneously burning a portion of said quantity of coal as a fuel in the presence of said sulfur oxides-saturated char to provide heat to desorb said char of said sulfur oxides and reacting said sulfur oxides with the remaining portion of coal to produce gaseous elemental sulfur, the adsorbent characteristics of said remaining coal portion being enhanced such that the remaining coal portion constitutes a carbonaceous adsorbent material after said reacting; condensing said gaseous elemental sulfur to liquid sulfur; and conveying said desorbed char and said reacted portion of said coal to said first vessel for use as an adsorbent material.
Claim 10
Dependent Claim 20 words
The method of claim 7, wherein the step of introducing combustion-supporting air includes heating said air to a predetermined temperature.
Claim 11
Dependent Claim 22 words
The method claimed in claim 7 wherein: said remaining coal portion undergoes an increase in porosity as a consequence of said reacting.
Claim 12
Dependent Claim 23 words
The method claimed in claim 7 wherein said char and said remaining coal portion pass through said second vessel in continuous mass flow.
Claim 13
Dependent Claim 31 words
The method claimed in claim 7 wherein said char and said reacted portion of said coal are cyclicly conveyed in continuous mass flow through said first vessel and said second vessel.
Claim 14
Dependent Claim 28 words
The method claimed in claim 10 wherein: said char portion of said flow of char and said reacted portion of said coal is diminished with each successive cycle.
Claim 15
Dependent Claim 22 words
The method claimed in claim 11 wherein: said char portion is diminished by between one and five percent on each successive cycle.

References Cited (Backward Citations)

US1908873A Cited
DE2155320A1 Cited
US3810972A Cited
US4041141A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-08-13 1983-02-12 1983-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-08-13 1987-02-12 1987-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-08-13 1991-02-12 1991-08-14 $7700.00 Window Closed / Lapsed

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