Hardenable compositions comprising an unsaturated epoxy ester and an ethylenically unsaturated monomer

Claim 2

A hardenable composition which provides a hardened composition of improved impact resistance comprising an unsaturated epoxy ester resin and an ethylenically unsaturated monomer copolymerizable with the latter, said monomer being present in the composition in an amount of from 0.4 to 2 parts by weight for each part by weight of said resin, and said resin being the reaction product of an unsaturated monocarboxylic acid or a monoester of an unsaturated bicarboxylic acid with the epoxidation product of epichlorohydrin and a novolak phenolic resin of the structural formula: ##STR4## wherein n has an average value of 0.2 or 0.6, said reaction product being obtained in a reaction system which comprises water, the water content of the reaction system being maintained at a value of from 0.5 to 2.5% by weight and the pH of the reaction system being maintained at a value of from 7 to 8.

Claim 3

A hardenable composition of claim 1, wherein said unsaturated monocarboxylic acid is selected from the group consisting of acrylic, methacrylic, crotonic and itaconic acids.

Claim 4

The hardenable composition of claim 1, wherein said monoester is selected from the group consisting of methyl monomaleate and methyl monofumarate.

Claim 5

The hardenable composition of claim 1, wherein said monomer is selected from the group consisting of styrene, vinyltoluene, alpha-methylstyrene, methyl methacrylate and vinylcyclohexene.

Claim 6

The hardenable composition of claim 1, wherein said monomer is present in an amount of from 0.6 to 1.5 parts by weight for each part by weight of said epoxy ester resin.

Claim 7

The hardenable composition of claim 1, wherein said monomer is styrene.

Claim 8

A process for producing a hardened product of improved impact resistance, which comprises adding a catalytic amount of an organic peroxide or hydroperoxide to a hardenable composition comprising an unsaturated epoxy ester resin and an ethylenically unsaturated monomer copolymerizable with the latter, said monomer being present in the composition in an amount of from 0.4 to 2 parts by weight for each part by weight of said resin, and said resin being the reaction product of an unsaturated monocarboxylic acid or a monoester of an unsaturated bicarboxylic acid with the epoxidation product of epichlorohydric and a novolak phenolic resin of the structural formula: ##STR5## wherein n has an average value of 0.2 or 0.6, said reaction product being obtained in a reaction system which comprises water, the water content of the reaction system being maintained at a value of from 0.5 to 2.5% by weight and the pH of the reaction system being maintained at a value of from 7 to 8, and hardening the resulting mixture.

Claim 9

A process for producing a hardened product of improved impact resistance, which comprises adding a catalytic amount of an organic peroxide or hydroperoxide to a hardenable composition comprising an unsaturated epoxy ester resin and an ethylenically unsaturated monomer copolymerizable with the latter, said monomer being present in the composition in an amount of from 0.4 to 2 parts by weight for each part by weight of said resin, and said resin being the reaction product of an unsaturated monocarboxylic acid or a monoester of an unsaturated bicarboxylic acid with the epoxidation product of epichlorohydric and a novolak phenolic resin of the structural formula: ##STR5## wherein n has an average value of 0.2 or 0.6, said reaction product being obtained in a reaction system which comprises water, the water content of the reaction system being maintained at a value of from 0.5 to 2.5% by weight and the pH of the reaction system being maintained at a value of from 7 to 8, and hardening the resulting mixture.

Claim 10

The process of claim 7, wherein said organic peroxide or hydroperoxide is selected from the group consisting of methyl ethyl ketone peroxide, cyclohexanone peroxide, benzoyl peroxide and cumene hydroperoxide.

Claim 11

The process of claim 7, wherein said peroxide or hydroperoxide is added in an amount if from 0.2 to 4 parts by weight for each 100 parts by weight of the sum of said epoxy ester resin and said monomer.

Claim 12

The process of claim 7, wherein a hardening accelerator selected from the group consisting of dimethylaniline and trimethylbenzylammonium chloride is added to the composition in an amount of from 0.1 to 2 parts by weight for each 100 parts by weight of the sum of said epoxy ester resin and said monomer.

Claim 13

The process of claim 7, wherein a hardening accelerator selected from the group consisting of naphthenates and octoates of cobalt, vanadium and vanadyl is added to the composition in an amount of from 0.02 to 2 parts by weight (as metal) for each 100 parts by weight of the sum of said epoxy resin and said monomer.

Claim 14

The hardenable composition of claim 1, wherein n has an average value of 0.2.

Claim 15

The process of claim 7, wherein n has an average value of 0.2.