Metal complexes

Claim 2

A metal complex prepared by reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, with the remaining active sites on the metal complex being occupied by groups derived from a polyhydric alcohol.

Claim 3

A metal complex according to claim 1, wherein the molar proportion of the alkanolamine to the metal alkoxides is within the range 0.25:1 to 0.9:1.

Claim 4

A metal complex according to claim 1 wherein the metal alkoxides are derived from an aliphatic alcohol containing up to 4 carbon atoms.

Claim 5

A metal complex according to claim 1 wherein the polyhydric alcohol is diethylene glycol.

Claim 6

The process for the preparation of a metal complex according to claim 1 which comprises reacting a mixture of aluminum and titanium alkoxides with (i) an excess of a polyhydric alcohol and (ii) with an alkanolamine.

Claim 7

The process for the preparation of a metal complex according to claim 1, which comprises reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, and subsequently adding an excess of a polyhydric alcohol and removing the monohydric alcohol by-product by distillation.

Claim 8

The process for the preparation of a metal complex according to claim 1, which comprises adding to a mixture of aluminum and titanium alkoxides an excess of a polyhydric alcohol, heating the resulting mixture to remove by distillation the liberated alcohol and subsequently adding an alkanolamine.

Claim 9

The process according to claim 7 wherein the alkanolamine is added after completion of the reaction between the polyhydric alcohol and the metal alkoxides as the product is cooling at a temperature below 100° C.

Claim 10

A thixotropic composition containing a film-forming polymer and organic colloid gelled with a metal complex prepared by reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, with the remaining active sites on the metal complex being occupied by groups derived from a polyhydric alcohol, wherein the molar ratio of said aluminum to titanium in said metal complex is up to 0.25 Al/0.75 Ti, said composition also containing sodium hexametaphosphate and/or calcium ions.

Claim 11

A thixotropic composition containing a film-forming polymer and organic colloid gelled with a metal complex prepared by reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, with the remaining active sites on the metal complex being occupied by groups derived from a polyhydric alcohol, wherein the molar ratio of said aluminum to titanium in said metal complex is up to 0.25 Al/0.75 Ti, said composition also containing sodium hexametaphosphate and/or calcium ions.

Claim 12

A thixotropic composition according to claim 9, comprising from 0.25 to 5% by weight of the metal complex based on the film-forming polymer.

Claim 13

A thixotropic composition which is free from sodium hexametaphosphate, containing a film-forming polymer and organic colloid gelled with a metal complex prepared by reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, with the remaining active sites on the metal complex being occupied by groups derived from a polyhydric alcohol, wherein the aluminum/titanium molar ratio is 0.95-0.7 Al/0.05-0.30 Ti.

Claim 14

A thixotropic composition which is free from sodium hexametaphosphate, containing a film-forming polymer and organic colloid gelled with a metal complex prepared by reacting less than 1 mole of an alkanolamine with at least 1 mole of a mixture of aluminum and titanium alkoxides, with the remaining active sites on the metal complex being occupied by groups derived from a polyhydric alcohol, wherein the aluminum/titanium molar ratio is 0.95-0.7 Al/0.05-0.30 Ti.

Claim 15

A thixotropic composition according to claim 9 which is an emulsion paint.

Claim 16

A metal complex according to claim 1 containing aluminum in a molar ratio of up to 0.25 Al/0.75 Ti.

Claim 17

A metal complex according to claim 1 comprising aluminum and titanium in molar ratios of 0.95-0.7 Al/0.05-0.30 Ti.

Claim 18

A metal complex according to claim 1 or 5 in which said alkanolamine is derived from a lower primary alcohol having up to about six carbon atoms.

Claim 19

A thixotropic composition according to claim 11, comprising from 0.25 to 5% by weight of the metal complex based on the film-forming polymer.