Patent US4157409A successfully refreshed from Google Patents.
US4157409A
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Method of making metal impregnated graphite fibers
Assignee: United States Department of the Army
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Filing: 1978-08-28
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Granted: 1979-06-05
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Expires: 1998-08-28
Abstract
Abstract A method is disclosed for pretreating graphite fibers and woven graphite preforms so that they may be wetted and infiltrated by molten metals such as aluminum and alloys thereof. Pretreatment includes immersing graphite fibers or preforms in a bath of liquid NaK alloy at room temperature. The pretreatment allows a lower temperature and shorter immersion time than prior art processes and permits improved wetting and infiltration by the molten metal constituting the matrix of a graphite fiber reinforced metal composite.
Inventors
- 👤 Albert P. Levitt
- 👤 Hans E. Band
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 11:07
CPC Classifications
C; C22; C22C; C22C47/00; C22C47/02; C22C47/04; C22C49/00; C22C49/14; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12444; Y10T428/29; Y10T428/2913; Y10T428/2918; Y10T428/2933; Y10T428/294; Y10T428/2958; Y10T428/30; Y10T442/00; Y10T442/30; Y10T442/3382
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
126 words
A process for fabricating graphite fiber reinforced metal comprising in sequence the steps of: immersing a graphite fiber in a bath of liquid NaK alloy in an inert atmosphere for a period of time sufficient to enhance the wettability and infiltration of the graphite fiber, wherein the composition of the NaK alloy is such that the alloy is a liquid at room temperature, transferring the fiber to, and immersing the fiber in, a molten bath of metal selected from the group consisting of aluminum, magnesium, copper, tin, lead, zinc and alloys thereof whereby the metal wets, infiltrates and coats the graphite fiber, and removing the metal-coated fiber from the molten metal bath whereby upon cooling the metal hardens and a graphite fiber reinforced metal is fabricated.
Claim 2
Dependent Claim
126 words
A process for fabricating graphite fiber reinforced metal comprising in sequence the steps of: immersing a graphite fiber in a bath of liquid NaK alloy in an inert atmosphere for a period of time sufficient to enhance the wettability and infiltration of the graphite fiber, wherein the composition of the NaK alloy is such that the alloy is a liquid at room temperature, transferring the fiber to, and immersing the fiber in, a molten bath of metal selected from the group consisting of aluminum, magnesium, copper, tin, lead, zinc and alloys thereof whereby the metal wets, infiltrates and coats the graphite fiber, and removing the metal-coated fiber from the molten metal bath whereby upon cooling the metal hardens and a graphite fiber reinforced metal is fabricated.
Claim 3
Dependent Claim
40 words
A process according to claim 1 wherein, following the NaK immersion step and preceding the metal immersion step, the fiber is treated by immersing the fiber in a molten bath of tin or an alloy of the containing 1%-2% magnesium.
Claim 4
Dependent Claim
29 words
A process according to claim 1 wherein the NaK alloy consists of from 13% to 57% by weight of Na and from 43% to 87% by weight of K.
Claim 5
Dependent Claim
37 words
A process according to claim 3 wherein the composition of the NaK alloy is 44%±1% Na and 56%±1% K by weight and wherein the temperature of the NaK alloy bath is from 5° C. to 200° C.
Claim 6
Dependent Claim
16 words
A process according to claim 3 wherein the NaK alloy bath is maintained at room temperature.
Claim 7
Dependent Claim
19 words
A process according to claim 5 wherein the time of immersion in the NaK bath is about 10 seconds.
Claim 8
Dependent Claim
20 words
A process according to claim 6 wherein the time of immersion in the molten metal bath is about 5 minutes.
Claim 9
Independent Claim
136 words
A method of making a graphite fiber reinforced metal article comprising in sequence the steps of: fabricating a graphite fiber preform of the article, immersing the preform in a bath of liquid NaK alloy in an inert atmosphere for a period of time sufficient to enhance the wettability and infiltration of the graphite fiber preform, wherein the composition of the NaK alloy is such that the alloy is a liquid at room temperature transferring the preform to and immersing the preform in, a molten bath of metal selected from the group consisting of aluminum, magnesium, copper, tin, lead, zinc and alloys thereof, whereby the metal wets, infiltrates and coats the preform, and removing the metal-coated preform from the molten metal bath whereby upon cooling the metal hardens and a graphite fiber reinforced metal article is made.
Claim 10
Independent Claim
136 words
A method of making a graphite fiber reinforced metal article comprising in sequence the steps of: fabricating a graphite fiber preform of the article, immersing the preform in a bath of liquid NaK alloy in an inert atmosphere for a period of time sufficient to enhance the wettability and infiltration of the graphite fiber preform, wherein the composition of the NaK alloy is such that the alloy is a liquid at room temperature transferring the preform to and immersing the preform in, a molten bath of metal selected from the group consisting of aluminum, magnesium, copper, tin, lead, zinc and alloys thereof, whereby the metal wets, infiltrates and coats the preform, and removing the metal-coated preform from the molten metal bath whereby upon cooling the metal hardens and a graphite fiber reinforced metal article is made.
Claim 11
Dependent Claim
40 words
A method according to claim 8 wherein, following the NaK immersion step and preceding the metal immersion step, the article is treated by immersing the article in a molten bath of tin or an alloy of tin containing 1%-2% magnesium.
Claim 12
Dependent Claim
29 words
A process according to claim 8 wherein the NaK alloy consists of from 13% to 57% by weight of Na and from 43% to 87% by weight of K.
Claim 13
Dependent Claim
37 words
A method according to claim 10 wherein the composition of the NaK alloy is 44%±1% Na and 56%±1% K. by weight and wherein the temperature of the NaK alloy bath is from 5° C. to 200° C.
Claim 14
Dependent Claim
15 words
A method according to claim 10 wherein the NaK alloy is maintained at room temperature.
Claim 15
Dependent Claim
19 words
A method according to claim 12 wherein the time of immersion in the NaK bath is about 10 seconds.
Claim 16
Dependent Claim
20 words
A method according to claim 13 wherein the time of immersion in the molten metal bath is about 5 minutes.
References Cited (Backward Citations)
US3770488A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-06-04 | 1982-12-04 | 1983-06-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-06-04 | 1986-12-04 | 1987-06-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-06-04 | 1990-12-04 | 1991-06-05 | $7700.00 | Window Closed / Lapsed |