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US4157357A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable two-part silicone rubber compositions with improved adhesion properties

Assignee: DuPont Toray Specialty Materials KK
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Filing: 1977-03-14
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Granted: 1979-06-05
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Expires: 1997-03-14
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Abstract

Abstract Two-part curable silicone rubber compositions are described, in which the crosslinker for the curable silicone rubber composition also serves as the adhesion promoter. Such crosslinkers contain at least one epoxy group.

Inventors

  • 👤 Katsutoshi Mine
  • 👤 Masuo Yokoyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:30
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08G77/18; C08G77/20

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 208 words
A curable composition of matter which consists essentially of a mixture of (a) an organopolysiloxane containing at least two hydrogen atoms bonded to silicon atoms and having the general formula R.sub.a SiO.sub.4-a/2 wherein a has an average value of 1-3 and R is hydrogen, hydroxy radicals or unsubstituted or substituted monovalent hydrocarbon radicals which do not contain aliphatic unsaturation, (b) an organopolysiloxane containing at least one A(R'O) 2 Si- group and at least two lower alkenyl radicals bonded to silicon atoms, in each molecule, wherein A is a monovalent hydrocarbon radical containing a ##STR15## radical, R' is a lower alkyl radical containing 1-6 carbon atoms, the sum of the number of hydrogen atoms bonded to silicon atoms in component (a) and the number of lower alkenyl radicals bonded to silicon atoms in component (b) is five or greater wherein there is present 0.1-10 mols of lower alkenyl groups bonded to silicon in (b) for every mol of hydrogen atoms bonded to silicon atoms in (a), and (c) 0.1-40 parts by weight per one million parts by weight of components (a) and (b) of an addition reaction catalyst for the addition reaction of the hydrogen atoms bonded to silicon atoms with the lower alkenyl groups bonded to silicon atoms.
Claim 2
Dependent Claim 208 words
A curable composition of matter which consists essentially of a mixture of (a) an organopolysiloxane containing at least two hydrogen atoms bonded to silicon atoms and having the general formula R.sub.a SiO.sub.4-a/2 wherein a has an average value of 1-3 and R is hydrogen, hydroxy radicals or unsubstituted or substituted monovalent hydrocarbon radicals which do not contain aliphatic unsaturation, (b) an organopolysiloxane containing at least one A(R'O) 2 Si- group and at least two lower alkenyl radicals bonded to silicon atoms, in each molecule, wherein A is a monovalent hydrocarbon radical containing a ##STR15## radical, R' is a lower alkyl radical containing 1-6 carbon atoms, the sum of the number of hydrogen atoms bonded to silicon atoms in component (a) and the number of lower alkenyl radicals bonded to silicon atoms in component (b) is five or greater wherein there is present 0.1-10 mols of lower alkenyl groups bonded to silicon in (b) for every mol of hydrogen atoms bonded to silicon atoms in (a), and (c) 0.1-40 parts by weight per one million parts by weight of components (a) and (b) of an addition reaction catalyst for the addition reaction of the hydrogen atoms bonded to silicon atoms with the lower alkenyl groups bonded to silicon atoms.
Claim 3
Dependent Claim 15 words
A composition of matter as in claim 1 wherein component (c) is a platinum catalyst.
Claim 4
Dependent Claim 27 words
A composition of matter as in claim 1 wherein component (a) contains methyl and phenyl groups bonded to silicon atoms in addition to the hydrogen atoms present.
Claim 5
Dependent Claim 19 words
A composition of matter as in claim 1 wherein component (b) contains vinyl radicals as the lower alkenyl radicals.
Claim 6
Dependent Claim 22 words
A composition of matter as in claim 1 wherein component (b) contains methyl, ethyl or methoxyethyl as the lower alkyl radicals, R'.
Claim 7
Dependent Claim 33 words
A composition of matter as in claim 1 wherein in the formula A(R'O) 2 Si-A is selected from the group consisting of (i) β-epoxyethyl, (ii) α-chloro-β-epoxyethyl, (iii) γ-glycidylpropyl, (iv) β-(3,4-epoxycyclohexyl)ethyl and (v) γ-(3,4-epoxycyclohexyl)propyl.
Claim 8
Dependent Claim 9 words
A product comprising the cured composition of claim 1.

References Cited (Backward Citations)

US2915497A Cited
GB938701A Cited
US3691206A Cited
US3631220A Cited
JPS4736255U Cited
US3996195A Cited
US4082719A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-04 1982-12-04 1983-06-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-04 1986-12-04 1987-06-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-04 1990-12-04 1991-06-05 $7700.00 Window Closed / Lapsed

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