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US4157282A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for maintaining stoichiometric air/fuel mixtures

Assignee: Motors Liquidation Co
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Filing: 1977-08-18
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Granted: 1979-06-05
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Expires: 1997-08-18
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Abstract

Abstract A durable and relatively inexpensive air/fuel ratio sensor for detecting oxygen concentration in exhaust gases of internal combustion engines, that does not require a separate reference atmosphere. A body of stabilized zirconium dioxide with two opposite major faces serves as a solid oxygen ion electrolyte. A catalytic electrode is on one of the faces, while a noncatalytic electrode is on the other face. The body is mounted in an exhaust pipe so that both of the electrodes are exposed to the exhaust gases.

Inventors

  • 👤 John W. Riddel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:04
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/406; G01N27/407; G01N27/4075; F; F02; F02B; F02B77/00; F02B77/08; F02B77/085; F02B77/086

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 164 words
A method for maintaining internal combustion engine air/fuel mixtures at stoichiometry by electrochemical analysis of engine exhaust gases, using non-equilibrium oxygen content of exhaust gases from both rich and lean air/fuel ratios as a reference, comprising: forming a single stream of exhaust gases from an internal combustion engine intended to combust stoichiometric air/fuel mixtures, said single stream being from fuel-rich, fuel-lean and stoichiometric air/fuel mixtures and always non-equilibrated; directing said single stream simultaneously across two opposite major faces of a zirconium dioxide solid electrolyte body to establish an output voltage between catalytic and non-catalytic gas pervious electrodes respectively on said faces, based on non-equilibrium oxygen content in said exhaust gases as a reference atmosphere regardless as to the air/fuel ratio from which produced; generating an electrical control signal in response to said output voltage that is representative of a substantially stoichiometric air/fuel mixture to be introduced into said engine; and regulating air/fuel mixtures introduced into said engine in response to said electrical control signal.
Claim 2
Independent Claim 164 words
A method for maintaining internal combustion engine air/fuel mixtures at stoichiometry by electrochemical analysis of engine exhaust gases, using non-equilibrium oxygen content of exhaust gases from both rich and lean air/fuel ratios as a reference, comprising: forming a single stream of exhaust gases from an internal combustion engine intended to combust stoichiometric air/fuel mixtures, said single stream being from fuel-rich, fuel-lean and stoichiometric air/fuel mixtures and always non-equilibrated; directing said single stream simultaneously across two opposite major faces of a zirconium dioxide solid electrolyte body to establish an output voltage between catalytic and non-catalytic gas pervious electrodes respectively on said faces, based on non-equilibrium oxygen content in said exhaust gases as a reference atmosphere regardless as to the air/fuel ratio from which produced; generating an electrical control signal in response to said output voltage that is representative of a substantially stoichiometric air/fuel mixture to be introduced into said engine; and regulating air/fuel mixtures introduced into said engine in response to said electrical control signal.
Claim 3
Independent Claim 205 words
A method for maintaining internal combustion engine air/fuel mixtures at stoichiometry by electrochemical analysis of engine exhaust gases, using non-equilibrium oxygen content of exhaust gases resulting from both rich and lean air/fuel mixtures as a reference, comprising: forming a single stream of exhaust gases from an internal combustion engine intended to combust stoichiometric air/fuel mixtures, said single stream being from fuel-rich, fuel-lean, and stoichiometric air/fuel mixtures and always non-equilibrated; directing said single stream simultaneously across two opposite major faces of a zirconium dioxide solid electrolyte body to produce an output voltage between gas pervious electrodes on said faces based on non-equilibrium oxygen content in said exhaust gas stream as a reference, the electrode on one of said faces catalyzing chemical oxidation substantially to equilibrium of unreacted exhaust gas combustibles and producing an electrode potential varying with the air/fuel mixture combusted, the electrode on the other face not catalyzing such chemical oxidation and producing an electrode potential not significantly varying with the air/fuel mixture combusted; generating an electrical control signal in response to said output voltage that is representative of a substantially stoichiometric air/fuel mixture to be introduced into said engine; and regulating air/fuel mixtures introduced into said engine in response to said electrical control signal.
Claim 4
Independent Claim 205 words
A method for maintaining internal combustion engine air/fuel mixtures at stoichiometry by electrochemical analysis of engine exhaust gases, using non-equilibrium oxygen content of exhaust gases resulting from both rich and lean air/fuel mixtures as a reference, comprising: forming a single stream of exhaust gases from an internal combustion engine intended to combust stoichiometric air/fuel mixtures, said single stream being from fuel-rich, fuel-lean, and stoichiometric air/fuel mixtures and always non-equilibrated; directing said single stream simultaneously across two opposite major faces of a zirconium dioxide solid electrolyte body to produce an output voltage between gas pervious electrodes on said faces based on non-equilibrium oxygen content in said exhaust gas stream as a reference, the electrode on one of said faces catalyzing chemical oxidation substantially to equilibrium of unreacted exhaust gas combustibles and producing an electrode potential varying with the air/fuel mixture combusted, the electrode on the other face not catalyzing such chemical oxidation and producing an electrode potential not significantly varying with the air/fuel mixture combusted; generating an electrical control signal in response to said output voltage that is representative of a substantially stoichiometric air/fuel mixture to be introduced into said engine; and regulating air/fuel mixtures introduced into said engine in response to said electrical control signal.

References Cited (Backward Citations)

USB843038I5 Cited
US3768259A Cited
DE2304464A1 Cited
US4005001A Cited
US3941673A Cited
US3844920A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-04 1982-12-04 1983-06-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-04 1986-12-04 1987-06-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-04 1990-12-04 1991-06-05 $7700.00 Window Closed / Lapsed

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