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US4155752A Expired / Lapsed US ⏱️ 0.0 years remaining

Corrosion-resistant ferritic chrome-molybdenum-nickel steel

Assignee: Thyssen Stahl AG
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Filing: 1978-01-10
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Granted: 1979-05-22
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Expires: 1998-01-10
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Abstract

Abstract Described herein is a ferritic chrome-molybdenum-nickel steel, containing specified amounts of niobium, zirconium and aluminum, of high chemical resistance against general and intercrystalline corrosion attack, as well as against pitting, crevice and stress corrosion in chloride-containing solutions. The described steel is useful for the fabrication of articles which must exhibit a 0.2-limit of at least 520 N/mm 2 at room temperature; a notched bar impact strength of at least 40 J at 0° C. and at least 70 J at 20° C. in 3-mm U-notch impact specimens; and guaranteed for flat stock such as sheet or strip material up to at least 10 mm thickness and for bar material of at least 60 mm diameter, round of square.

Inventors

  • 👤 Rudolf Oppenheim
  • 👤 Heinrich Kiesheyer
  • 👤 Helmut Brandis
  • 👤 Gustav Lennartz
  • 👤 Rainer Thielmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:52
CPC Classifications
C; C22; C22C; C22C38/00; C22C38/18; C22C38/40; C22C38/50

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 163 words
A ferritic chrome-molybdenum-nickel steel of high chemical resistance against general and intercrystalline corrosion attack as well as against pitting, crevice and stress corrosion in chloride-containing solutions consisting essentially of: ______________________________________ 18 to 32 % chromium 0.1 to 6 % molybdenum 0.5 to 5 % nickel 0.01 to 0.05 % carbon 0.02 to 0.08 % nitrogen 0.10 to 0.60 % niobium 0.005 to 0.50 % zirconium 0.01 to 0.25 % aluminum up to 0.25 % titanium up to 3 % copper up to 3 % silicon up to 1 % manganese up to 0.01 % each calcium, magnesium, cerium or cerium mixed metal, boron remainder iron and impurities due to the melting process. ______________________________________ wherein the niobium content is at least 12-times that of the carbon and at most 12-times + 0.20%, and the total content of zirconium plus 3.5-times the aluminum content at least 10-times that of the free, non-niobium-bound nitrogen content and at most 10-times + 10% according to the formula: ##EQU2##
Claim 2
Dependent Claim 163 words
A ferritic chrome-molybdenum-nickel steel of high chemical resistance against general and intercrystalline corrosion attack as well as against pitting, crevice and stress corrosion in chloride-containing solutions consisting essentially of: ______________________________________ 18 to 32 % chromium 0.1 to 6 % molybdenum 0.5 to 5 % nickel 0.01 to 0.05 % carbon 0.02 to 0.08 % nitrogen 0.10 to 0.60 % niobium 0.005 to 0.50 % zirconium 0.01 to 0.25 % aluminum up to 0.25 % titanium up to 3 % copper up to 3 % silicon up to 1 % manganese up to 0.01 % each calcium, magnesium, cerium or cerium mixed metal, boron remainder iron and impurities due to the melting process. ______________________________________ wherein the niobium content is at least 12-times that of the carbon and at most 12-times + 0.20%, and the total content of zirconium plus 3.5-times the aluminum content at least 10-times that of the free, non-niobium-bound nitrogen content and at most 10-times + 10% according to the formula: ##EQU2##
Claim 3
Dependent Claim 21 words
A steel according to claim 1 containing about 27.5 to 29% chromium, 1.8 to 2.5% molybdenum, and 3.3 to 4.0% nickel.
Claim 4
Dependent Claim 21 words
A steel according to claim 1 containing about 19.5 to 21% chromium, 4.0 to 5.0% molybdenum, and 1.5 to 2.5% nickel.
Claim 5
Dependent Claim 18 words
A steel according to claim 1 in which the total carbon and nitrogen contents are at most 0.080%.
Claim 6
Dependent Claim 13 words
A steel according to claim 1 containing from about 0.15 to 0.45% niobium.
Claim 7
Dependent Claim 13 words
A steel according to claim 5 containing no greater than about 0.30% niobium.
Claim 8
Dependent Claim 13 words
A steel according to claim 1 containing no greater than about 0.10% aluminum.
Claim 9
Dependent Claim 18 words
A steel according to claim 1 containing no greater than about 0.80% combined content of niobium and zirconium.
Claim 10
Dependent Claim 25 words
A steel according to claim 1 wherein said aluminum is partially replaced by about twice the amount of titanium, but only up to 0.25% titanium.
Claim 11
Dependent Claim 14 words
A steel according to claim 1 containing from about 0.5 to about 2.0% copper.
Claim 12
Dependent Claim 14 words
A steel according to claim 1 containing from about 0.5 to about 2.0% silicon.
Claim 13
Dependent Claim 77 words
A process for the manufacture of articles which must exhibit a 0.2-limit at room temperature of at least 520 N/mm 2 , a notched bar impact strength of at least 40 J at 0° C. and at least 70 J at 20° C. on DVM specimens, and guaranteed for flat stock such as sheet or strip up to at least 60 mm diameter, round or square, comprising fabricating said articles from a steel according to claim 1.
Claim 14
Dependent Claim 7 words
Articles manufactured in accordance with claim 12.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-21 1982-11-20 1983-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-21 1986-11-20 1987-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-21 1990-11-20 1991-05-22 $7700.00 Window Closed / Lapsed

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