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US4154301A Expired / Lapsed US ⏱️ 0.0 years remaining

Surfactant oil recovery process usable in a formation having high salinity connate water

Assignee: Texaco Inc
•
Filing: 1978-06-29
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Granted: 1979-05-15
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Expires: 1998-06-29
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Abstract

Abstract In the recovery of oil from an oil-bearing formation having a high salinity connate water wherein an aqueous surfactant slug containing a commercially available petroleum sulfonate is injected followed by the injection of an aqueous drive agent, improved recovery is obtained, if a cosurfactant and a mono-unsaturated secondary alcohol are added to the surfactant slug.

Inventors

  • 👤 Joseph T. Carlin
  • 👤 John A. Wells
  • 👤 Timothy N. Tyler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 06:23
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 103 words
In the method of recovering oil from an oil-bearing formation having a high salinity connate water said formation being traversed by at least two spaced wells and said method comprising the injection via one of said wells of an aqueous slug containing a commercially available petroleum sulfonate followed by the injection of an aqueous drive agent to displace said slug and said formation oil toward the second of said spaced wells and recovering said oil from said second spaced well, the improvement comprising: the addition to said aqueous slug containing said commercially available petroleum sulfonate of a cosurfactant and a mono-unsaturated secondary alcohol.
Claim 2
Dependent Claim 103 words
In the method of recovering oil from an oil-bearing formation having a high salinity connate water said formation being traversed by at least two spaced wells and said method comprising the injection via one of said wells of an aqueous slug containing a commercially available petroleum sulfonate followed by the injection of an aqueous drive agent to displace said slug and said formation oil toward the second of said spaced wells and recovering said oil from said second spaced well, the improvement comprising: the addition to said aqueous slug containing said commercially available petroleum sulfonate of a cosurfactant and a mono-unsaturated secondary alcohol.
Claim 3
Dependent Claim 24 words
The method of claim 1 wherein said aqueous slug is injected in amounts from about 5% to about 50% of the reservoir pore volume.
Claim 4
Dependent Claim 25 words
The method of claim 1 wherein said cosurfactant is contained in said aqueous slug in amounts of from about 0.3% to about 3.0% by weight.
Claim 5
Dependent Claim 39 words
The method of claim 1 wherein said cosurfactant is selected from the group consisting of ethoxylated phenols, ethoxylated alkyl phenols, ethoxylated alcohols, sulfated derivatives of said phenols and alcohols, sulfonated derivatives of said phenols and alcohols, and mixtures thereof.
Claim 6
Dependent Claim 28 words
The method of claim 1 wherein said mono-unsaturated secondary alcohol is present in said aqueous slug in a concentration of from about 0.001% to about 1.0% by weight.
Claim 7
Dependent Claim 28 words
The method of claim 5 wherein said mono-unsaturated secondary alcohol is present in said aqueous slug in a concentration of from about 0.002% to about 0.006% by weight.
Claim 8
Dependent Claim 38 words
The method of claim 1 wherein said mono-unsaturated secondary alcohol is selected from the group consisting of a cyclic secondary alcohol, alkyl derivatives of said cyclic secondary alcohols, terpene alcohols and derivatives thereof, polyalicyclic alcohols and derivatives thereof.
Claim 9
Dependent Claim 18 words
The method of claim 7 wherein said mono-unsaturated secondary alcohol is cholesterol, derivatives of cholesterol and mixtures thereof.
Claim 10
Dependent Claim 16 words
The method of claim 1 wherein said aqueous slug contains brine, connate water or fresh water.
Claim 11
Dependent Claim 18 words
The method of claim 1 wherein said aqueous slug contains a water-soluble inorganic salt of an alkali metal.
Claim 12
Dependent Claim 12 words
The method of claim 10 wherein said water-soluble salt is sodium chloride.
Claim 13
Dependent Claim 37 words
The method of claim 1 wherein the injection of said aqueous slug of petroleum sulfonate is followed by the injection of an aqueous slug containing a polymeric material prior to the injection of said aqueous drive agent.

References Cited (Backward Citations)

US3500919A Cited
US3508612A Cited
US3477511A Cited
US3811505A Cited
US3811507A Cited
US3920073A Cited
US3865187A Cited
US4066124A Cited
US4077471A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-14 1982-11-13 1983-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-14 1986-11-13 1987-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-14 1990-11-13 1991-05-15 $7700.00 Window Closed / Lapsed

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