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US4153765A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable composition containing EPM or EPDM interpolymers

Assignee: DSM Copolymer Inc
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Filing: 1978-03-27
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Granted: 1979-05-08
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Expires: 1998-03-27
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Abstract

Abstract Room temperature curable composition containing EPM or EPDM interpolymers having bound ethylene organosilane monomers in which residual hydrolyzable groups of the bound organosilicon components are in the form of lower alkoxy groups, an organotin carboxylate for controlling cure, and which may include an organic amine, an aminosilane, organic hydroxyl compounds and fillers, and in which the EPM or EPDM is of lower molecular weight fluid consistency.

Inventors

  • 👤 Thomas C. H. Tsai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 18:56
CPC Classifications
C; C08; C08F; C08F8/00

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 157 words
A composition having controlled room temperature cure containing an interpolymer selected from the group consisting of an EPM interpolymer formed by copolymerization in the presence of a Ziegler catalyst of ethylene, a monoolefin containing 3 to 12 carbon atoms, and an unsaturated organo-silane having at least one unsaturated organic group and from 1 to 3 highly hydrolyzable groups other than oxygen containing groups thereby to avoid poisoning the catalyst and maintaining the stability of the polymerization reaction attached to the silicon atom and an EPDM interpolymer of ethylene, a monolefin containing 3 to 12 carbon atoms, a polyene and an unsaturated organosilane of the type described with hydrolyzable groups remaining on the organosilanes bound in the interpolymer replacing the hydrolyzable groups with short chained alkoxy groups at a time when they can no longer interfere with the polymerization reaction, and an organotin carboxylate for controlling room temperature cure of the interpolymer containing the short chained alkoxy groups.
Claim 2
Dependent Claim 157 words
A composition having controlled room temperature cure containing an interpolymer selected from the group consisting of an EPM interpolymer formed by copolymerization in the presence of a Ziegler catalyst of ethylene, a monoolefin containing 3 to 12 carbon atoms, and an unsaturated organo-silane having at least one unsaturated organic group and from 1 to 3 highly hydrolyzable groups other than oxygen containing groups thereby to avoid poisoning the catalyst and maintaining the stability of the polymerization reaction attached to the silicon atom and an EPDM interpolymer of ethylene, a monolefin containing 3 to 12 carbon atoms, a polyene and an unsaturated organosilane of the type described with hydrolyzable groups remaining on the organosilanes bound in the interpolymer replacing the hydrolyzable groups with short chained alkoxy groups at a time when they can no longer interfere with the polymerization reaction, and an organotin carboxylate for controlling room temperature cure of the interpolymer containing the short chained alkoxy groups.
Claim 3
Dependent Claim 35 words
A composition as claimed in claim 1 in which the organotin carboxylate is present in an amount within the range of 2 to 10 parts by weight per 100 parts by weight of the interpolymer.
Claim 4
Dependent Claim 35 words
A composition as claimed in claim 1 in which the organotin carboxylate is present in an amount within the range of 2 to 5 parts by weight per 100 parts by weight of the interpolymer.
Claim 5
Dependent Claim 24 words
A composition as claimed in claim 1 in which the organotin carboxylate is a C 1 to C 5 dialkyl tin aliphatic acid ester.
Claim 6
Dependent Claim 31 words
A composition as claimed in claim 1 in which the organotin carboxylate is selected from the group consisting of dibutyl tin diacetate, dibutyl tin dilaurate, dibutyl tin caproate, and stannous octoate.
Claim 7
Dependent Claim 18 words
A composition as claimed in claim 1 which includes an accelerator in the form of an organic amine.
Claim 8
Dependent Claim 16 words
A composition as claimed in claim 6 in which the organic amine is an aliphatic amine.
Claim 9
Dependent Claim 16 words
A composition as claimed in claim 6 in which the organic amine is a secondary amine.
Claim 10
Dependent Claim 14 words
A composition as claimed in claim 6 in which the organic amine is morpholine.
Claim 11
Dependent Claim 34 words
A composition as claimed in claim 6 in which the organic amine is present in an amount within the range of 1 to 10 parts by weight per 100 parts by weight of interpolymer.
Claim 12
Dependent Claim 34 words
A composition as claimed in claim 6 in which the organic amine is present in an amount within the range of 2 to 5 parts by weight per 100 parts by weight of interpolymer.
Claim 13
Dependent Claim 30 words
A composition as claimed in claim 1 which includes an organic alcohol selected from the group consisting of an aliphatic alcohol, diol and polyol having at least two carbon atoms.
Claim 14
Dependent Claim 19 words
A composition as claimed in claim 12 in which the organic alcohol has from 2 to 12 carbon atoms.
Claim 15
Dependent Claim 34 words
A composition as claimed in claim 12 in which the organic alcohol is present in an amount within the range of 1 to 20 parts by weight per 100 parts by weight of interpolymer.
Claim 16
Dependent Claim 34 words
A composition as claimed in claim 12 in which the organic alcohol is present in an amount within the range of 2 to 5 parts by weight per 100 parts by weight of interpolymer.
Claim 17
Dependent Claim 40 words
A composition as claimed in claim 1 which includes an accelerator in the form of an organic amine, and an organic alcohol selected from the group consisting of an aliphatic monoalcohol, diol and polyol having at least 2 carbon atoms.
Claim 18
Dependent Claim 10 words
A composition as claimed in claim 1 which includes fillers.
Claim 19
Dependent Claim 10 words
A composition as claimed in claim 6 which includes fillers.
Claim 20
Dependent Claim 10 words
A composition as claimed in claim 12 which includes fillers.

References Cited (Backward Citations)

US3240768A Cited
US3644306A Cited
US4022961A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-07 1982-11-06 1983-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-07 1986-11-06 1987-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-07 1990-11-06 1991-05-08 $7700.00 Window Closed / Lapsed

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