Patent US4153648A successfully refreshed from Google Patents.
US4153648A
Expired / Lapsed
US
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Thermoplastic nitrile resin blends
Assignee: Standard Oil Co
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Filing: 1977-10-28
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Granted: 1979-05-08
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Expires: 1997-10-28
Abstract
Abstract Blends of high-acrylonitrile thermoplastic copolymers with acrylonitrile-indene copolymers have improved softening temperatures, improved gas barrier properties and other improved physical properties.
Inventors
- 👤 George S. Li
- 👤 John F. Jones
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 07:43
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/18; C08L33/20
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
248 words
The blend composed of 100 parts by weight of (I) a polymer prepared by the polymerization of 100 parts by weight of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 to 50% by weight based on the combined weight of (A) and (B) of at least one member selected from the group consisting of (1) styrene, (2) an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, (3) an alpha-olefin having the structure ##STR10## wherein R' and R" are alkyl groups having from 1 to 7 carbon atoms, (4) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, and (5) vinyl acetate, and from 5 to 15 parts by weight of (II) a polymer resulting from the copolymerization of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR11## wherein R has the foregoing designation, (B) from 10 to 50% by weight of indene, and (C) from 0 to 40% by weight of an ester having the structure ##STR12## wherein R 1 and R 2 have the foregoing designations.
Claim 2
Dependent Claim
248 words
The blend composed of 100 parts by weight of (I) a polymer prepared by the polymerization of 100 parts by weight of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 to 50% by weight based on the combined weight of (A) and (B) of at least one member selected from the group consisting of (1) styrene, (2) an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, (3) an alpha-olefin having the structure ##STR10## wherein R' and R" are alkyl groups having from 1 to 7 carbon atoms, (4) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, and (5) vinyl acetate, and from 5 to 15 parts by weight of (II) a polymer resulting from the copolymerization of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR11## wherein R has the foregoing designation, (B) from 10 to 50% by weight of indene, and (C) from 0 to 40% by weight of an ester having the structure ##STR12## wherein R 1 and R 2 have the foregoing designations.
Claim 3
Dependent Claim
10 words
The blend of claim 1 wherein (I) (A) is acrylonitrile.
Claim 4
Dependent Claim
11 words
The blend of claim 2 wherein (I) (B) (1) is styrene.
Claim 5
Dependent Claim
12 words
The blend of claim 2 wherein (I) (B) (2) is methyl acrylate.
Claim 6
Dependent Claim
10 words
The blend of claim 1 wherein (II) (A) is acrylonitrile.
Claim 7
Dependent Claim
11 words
The blend of claim 1 wherein (II) (C) is methyl acrylate.
Claim 8
Dependent Claim
16 words
The blend of claim 3 wherein (II) (A) is acrylonitrile and (II) (C) is methyl acrylate.
Claim 9
Dependent Claim
16 words
The blend of claim 4 wherein (II) (A) is acrylonitrile and (II) (C) is methyl acrylate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-05-07 | 1982-11-06 | 1983-05-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-05-07 | 1986-11-06 | 1987-05-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-05-07 | 1990-11-06 | 1991-05-08 | $7700.00 | Window Closed / Lapsed |